• Particle and aerosol research
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• v.10 no.1
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• pp.27-31
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• 2014

A simple bimodal model has been developed to analyze charged particle coagulation by modifying previously suggested bimdal model for evolution of particle generation and growth. In the present model, two monodisperse modes are used and 40 charge nodes are assigned to each mode to account both change of the particle size and charge distribution. In addition, we also implemented the effect of electrostatic dispersion loss in the present model. Based on the developed model, we analyzed coagulation of asymmetric bipolar charged particles by computing evolutions of particle number concentration, geometric mean diameter of particles, charge asymmetric ratio and geometric standard deviation of particle size distribution for various initial charge asymmetric ratios. The number concentration of asymmetric bipolar charged particles decreases faster than that of neutral particles but that does not give faster growth of particles since the electrostatic dispersion loss overwhelms particle growth by coagulation.

• Toxicological Research
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• v.29 no.2
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• pp.121-127
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• 2013

Nanotoxicological research has shown toxicity of nanomaterials to be inversely related to particle size. However, the contribution of agglomeration to the toxicity of nanomaterials has not been sufficiently studied, although it is known that agglomeration is associated with increased nanomaterial size. In this study, we prepared aerosols of nano-sized carbon black by 2 different ways to verify the effects of agglomeration on the toxicity and deposition of nano-sized carbon black. The 2 methods of preparation included the carbon black dispersion method that facilitated clustering without sonication and the carbon black dispersion method involving sonication to achieve scattering and deagglomeration. Male Sprague-Dawley rats were exposed to carbon black aerosols 6 hr a day for 3 days or for 2 weeks. The median mass aerodynamic diameter of carbon black aerosols averaged $2.08{\mu}m$ (for aerosol prepared without sonication; group N) and $1.79{\mu}m$ (for aerosol prepared without sonication; group S). The average concentration of carbon black during the exposure period for group N and group S was $13.08{\pm}3.18mg/m^3$ and $13.67{\pm}3.54mg/m^3$, respectively, in the 3-day experiment. The average concentration during the 2-week experiment was $9.83{\pm}3.42mg/m^3$ and $9.08{\pm}4.49mg/m^3$ for group N and group S, respectively. The amount of carbon black deposition in the lungs was significantly higher in group S than in group N in both 3-day and 2-week experiments. The number of total cells, macrophages and polymorphonuclear leukocytes in the bronchoalveolar lavage (BAL) fluid, and the number of total white blood cells and neutrophils in the blood in the 2-week experiment were significantly higher in group S than in normal control. However, differences were not found in the inflammatory cytokine levels (IL-$1{\beta}$, TNF-${\alpha}$, IL-6, etc.) and protein indicators of cell damage (albumin and lactate dehydrogenase) in the BAL fluid of both group N and group S as compared to the normal control. In conclusion, carbon black aerosol generated by sonication possesses smaller nanoparticles that are deposited to a greater extent in the lungs than is aerosol formulated without sonication. Additionally, rats were narrowly more affected when exposed to carbon black aerosol generated by sonication as compared to that produced without sonication.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.3
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• pp.237-246
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• 1994

Experimental data are reported for charging and collection of NaCl aerosols in the 0.03- to $0.2{\mu}m$-geometric-mean-diameter range in 2-stage parallel-plate electrostatic precipitators. The NaCl aerosols are generated with geometric standard deviation of about 1.74 and particle generation rate of about 10^9 particles/see by the constant output atomizer and injected into the air flow in the clean wind-tunnel. The 2-stage parallel-plate electrostatic precipitator installed in the test section of the wind-tunnel is operated with a positive corona discharge. The NaCl aerosols in the channel flow are sampled and transported to the aerosol particle number concentration measurement system by using the isoaxial sampling and transport system constructed based on the Okazaki and Willeke design. The aerosol particle number concentration measurement system measures the size distribution of submicrometer aerosols by an electrical mobility detection technique. It is confirmed from comparing the measured collection efficiencies in this study and the predicted ones by our previous theoretical analysis that the predicted collection efficiencies agree well with the experimental ones. It is also found from the comparison that below about $0.02{\mu}m$ all particles are not charged and the uncharged particles are not collected, and consequently 2-stage parallel-plate electrostatic precipitators are not suitable for that particle size range.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.1
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• pp.17-24
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• 2014

We measured black carbon concentration in rural area to understand the characteristic of atmospheric aerosol by comparing the black carbon concentration and meteorological factors such as PM10 concentration, relative humidity, temperature and wind velocity. A MAAP (Multi Angle Absorption Photometer) which is one of filter based equipments was used to measure black carbon concentration. Black carbon concentration was measured to be high from April to May and low from June to September. Black carbon concentration was proportional to PM10 concentration. Black carbon concentration was correlated to relative humidity. Black carbon concentration was inversely proportional to wind velocity and temperature. Finally, we suggest that the volume fraction of black carbon in the atmosphere can be estimated from the size, number concentration and absorption coefficient measured using the MAAP.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.423-423
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• 2003

The radiative properties of atmospheric aerosol are determined by the mass and chemical characteristics, and optical properties such as aerosol optical depth (AOD), ngstr m parameter ( $\alpha$) and single scattering albedo (SSA). In particular these aerosol optical properties also determine surface temperature perturbation that may give some information in understanding the regional atmospheric radiative forcing. For understanding the radiative forcing and regional surce of aerosol, this paper summarizes and compares the aerosol optical properties results from and compares the atmospheric aerosol optical properties results from two different experiments: Anmyeon 2000 and Jeju 2001. Korea Global Atmosphere Watch Observatory (KGAWO) at Anmyeon island and ACE-Asia super-site at Gosan Jeju island have measured the radiations and aerosols since the year of 2000. The sites are located in the mid-west and south of Korea peninsula where it is strongly affected by the Asian dust coming from China region in every spring. Aerosol optical properties over both sites were measured through the ground-based sun and sky radiometers were analyzed for understanding the radiation and climate properties. Number concentration and chemical components of aerosol were additionally analyzed for the source estimation in the transportation. The frequency distributions of aerosol optical depth are rather narrow with a modal vaiue of 0.38 at both sites. However, the distributions of show one peak (1.13) at Jeju but two peaks (0.63 and 1.13) at Anmyeon. In the cases of Anmyeon, one peak around 0.63 corresponds to relatively dust-free cases, and the second peak around 1.13 characterizes the situation when Asian dust is presented. The correlation between AOD and resulted high correlation on the wide range with high values of optical depth at Anmyeon, otherwise a narrow range of with moderate to low AOD at Jeju. In dust free condition SSA decrease with waveleneth while in the presence of Asian dust SSA either stays neutral or increases slightly with wavelength. The change of surface temperature shows the stronger positive correlations with aerosol optical depth increase at Anmyeon than Jeju. In the chemical properties the aerosol are related to high concentrations in inorganic matters, SO$^4$, NO$_3$, CA2+ in fine and coarse.

• KEPCO Journal on Electric Power and Energy
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• v.8 no.2
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• pp.103-110
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• 2022

Ultrafine Particle number and size distributions were simultaneously measured at rural area around the power plant in Dangjin, South Korea. New Particle formation and growth events were frequently observed during January, 2021 and classified based on their strength and persistence as well as the variation in geometric mean diameter(GMD) on January 12, 21 and 17. In this study, we investigated mechanisms of new particle growth based on measurements using a high resolution time of flight aerosol mass spectrometer(HR-ToF-AMS) and a scanning mobility particle sizer(SMPS). On Event days(Jan 12 and 21), the total average growth rate was found to be 8.46 nm/h~24.76 nm/hr. These growth rate are comparable to those reported for other urban and rural sites in South Korea using different method. Comparing to the Non-Event day(Jan 17), New Particle Growth mostly occurred when solar radiation is peaked and relative humidity is low in daytime, moreover enhanced under the condition of higher precusors, NO₂ (39.9 vs 6.2ppb), VOCs(129.5 vs 84.6ppb), NH₃(11 vs 4.7ppb). The HR-ToF-AMS PM_1.0 composition shows Organic and Ammoniated nitrate were dominant species effected by emission source in domestic. On the other hand, The Fraction of Ammoniated sulfate was calculated to be approximately 16% and 31% when air quality is inflow from China. Longer term studies are needed to help resolve the relative contributions of each precusor species on new particle growth characteristics.

• Particle and aerosol research
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• v.10 no.4
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• pp.163-167
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• 2014

Particle number portable emission measurement system (PN-PEMS) is an instrument for measuring number concentration of automobile exhaust. The principle of some pre-existing commercial PN-PEMS is to charge particles and display the number of particles by measuring current. However, this method has some problems for measuring exhaust. In this study, to solve these issues, we have developed a single particle counting PN-PEMS based condensation particle counter (CPC). The PN-PEMS based CPC does not affect driving conditions and it is convenient for mobile because the instrument is small and light in structure. We evaluated counting efficiency of PN-PEMS based CPC by using electrostatic method (electrometer and Faraday cup).

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.1
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• pp.65-73
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• 2014

Objectives: The purposes of this study are to investigate workers' exposures to respirable particles generated in taconite mines and to compare two metric methods for mass concentrations using direct-reading instruments. Methods: Air monitorings were conducted at six mines where subjects have been exposed primarily to particulate matters in crushing, concentrating, and pelletizing processes. Air samples were collected during 4 hours of the entire work shift for similarly exposure groups(SEGs) of nine jobs(N=37). Following instruments were employed to evaluate the workplace: a nanoparticle aerosol monitor(particle size range; 10-1000 nm, unit: ${\mu}m^2/cc$, Model 9000, TSI Inc.); DustTrak air monitors($PM_{10}$, $PM_{2.5}$, unit: $mg/m^3$, Model 8520, TSI Inc.); a condensation particle counter(size range; 20-1000 nm, unit: #/cc, P-Trak 8525, TSI Inc.); and an optical particle counter(particle number by size range $0.3-25{\mu}m$, unit: #/cc, Aerotrak 9306, TSI Inc.). Results: The highest airborne concentration among SEGs was for furnace operator followed by pelletizing maintenance workers in number of particle and surface area, but not in mass concentrations. The geometric means of $PM_{2.5}$ by the DustTrak and the Ptrak/Aerotrak were $0.04{\mu}m$(GSD 2.52) and $0.07{\mu}m$(GSD 2.60), respectively. Also, the geometric means of RPM by the DustTrak and the Ptrak/Aerotrak were $0.16{\mu}m$(GSD 2.24) and $0.32{\mu}m$(GSD 3.24), respectively. The Pearson correlation coefficient for DustTrak $PM_{2.5}$ and Ptrak/Aerotrak $PM_{2.5}$ was 0.56, and that of DustTrak RPM and Ptrak/Aerotrak RPM was 0.65, indicating a moderate positive association between the two sampling methods. Surface area and number concentration were highly correlated($R^2$ = 0.80), while $PM_{2.5}$ and RPM were also statistically correlated each other($R^2$ = 0.79). Conclusions: The results suggest that it is possible to measure airborne particulates by mass concentrations or particle number concentrations using real-time instruments instead of using the DustTrak Aerosol monitor that monitor mass concentrations only.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.5
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• pp.345-353
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• 2002

A study of polydispersed aerosol dynamics by Electrostatic Precipitator (ESP) was carried out. The log-normal particle size distribution was assumed and moment method was considered. In order to apply moment method in Deutsch-Anderson equation, Cunningham slip correction factor and Cochet's charge equation were simplified for certain range of particle size. The three parameters, which explain the particle size distribution, such as total number concentration, geometric mean diameter, and geometric standard deviation were considered to derive the analytic solution. The obtained solution was compared with available numerical results (Bai et al., 1995). The comparison of the numerical and analytic results showed a good agreement.

• Particle and aerosol research
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• v.10 no.3
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• pp.93-97
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• 2014

Condensation particle counter (CPC) has been one of the most important basic instrument for measuring number concentration of submicron aerosols. The principle of the CPC is to expose aerosols to a supersaturated vapor and cool down which causes adiabatic expansion. The particles grow by heterogenous nucleation to a sufficient size for easy detection by optical method. However, for growth by condensation, CPC essentially needs both saturater and condensor causing a heavy system. Therefore, it is hard to install commercial CPC to tethered balloon package system. In this study, we developed customized CPC for tethered balloon package system called Hy-CPC which is lighter and smaller in structure than commercial CPCs, and evaluated activation efficiency and detection efficiency by Hy-CPC using electrostatic method (electrometer and Faraday cup).