• 한국입자에어로졸학회지
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• 제14권4호
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• pp.135-144
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• 2018

PMF 수용모델을 사용하여 안면도 측정소에서 2년간 측정한 초미세먼지의 유기성분의 주요 영향원을 파악하였다. 5개 또는 6개의 요인이 최적으로 나타났으며, 6개의 요인이 결과를 더 잘 해석하는 것으로 판단되었다. 이들 요인의 계절별 특성과 영향도 변화를 고려하여 결정한 주요 오염원은 이차유기성분(10.3%), 연소(12.0%), 자연적 생물성 기원(24.8%) 장거리이동식생소각(7.3%), 국지적 생체소각(26.4%), 장거리이동 오염원(19.2%)이다. 안면도 측정소는 배경지역의 특성인 자연적 생물성 기원, 이차유기성분과 장거리이동 오염원의 영향도가 크게 나타나면서도, 비도심의 특성인 국지적 식생소각과 연소 영향도 나타나고 있다. 이는 안면도 측정소에서는 인위적인 영향에 의한 유기성분 특성은 제한적임을 보여준다.

• 한국대기환경학회지
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• 제34권3호
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• pp.430-446
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• 2018

To improve understanding of the sources and chemical properties of particulate pollutants on the Korean Peninsula, An Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) measured non-refractory fine particle ($NR-PM_1$) from 2013 to 2015 at Baengnyeong Island and Seoul metropolitan area (SMA), Korea. The chemical composition of $NR-PM_1$ in Baengnyeong island was dominated by organics and sulfate in the range of 36~38% for 3 years, and the organics were the dominant species in the range of 44~55% of $NR-PM_1$ in Seoul metropolitan area. The sulfate was found to be more than 85% of the anthropogenic origin in the both areas of Baengnyeong and SMA. Ratio of gas to particle partition of sulfate and nitrate were observed in both areas as more than 0.6 and 0.8, respectively, representing potential for formation of additional particulate sulfate and nitrate. The high-resolution spectra of organic aerosol (OA) were separated by three factors which were Primary OA(POA), Semi-Volatility Oxygenated Organic Aerosol (SV-OOA), and Low-Volatility OOA(LV-OOA) using positive matrix factorization (PMF) analysis. The fraction of oxygenated OA (SOA, ${\fallingdotseq}OOA$=SV-OOA+LV-OOA) was bigger than the fraction of POA in $NR-PM_1$. The POA fraction of OA in Seoul is higher than it of Baengnyeong Island, because Seoul has a relatively large number of primary pollutants, such as gasoline or diesel vehicle, factories, energy facilities. Potential source contribution function (PSCF) analysis revealed that transport from eastern China, an industrial area with high emissions, was associated with high particulate sulfate and organic concentrations at the Baengnyeong and SMA sites. PSCF also presents that the ship emissions on the Yellow Sea was associated with high particulate sulfate concentrations at the measurement sites.

• 한국입자에어로졸학회지
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• 제16권4호
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• pp.107-117
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• 2020

충청남도 대형사업장에서의 대기오염물질 배출이 미세먼지 농도에 미치는 영향에 대한 논란이 많다. 2019년 봄과 가을에 항공관측을 수행하여 충청남도 대형사업장 상공에서 대기오염물질 농도를 측정하였고, 이를 바탕으로 황산화물(SO2) 배출량을 산정하였다(하향식 배출량). 이를 사업장에서 제시한 배출량 자료(상향식 배출량)와 비교한 결과, 항공관측에 바탕을 둔 배출량이 더 많았다. 항공관측에 바탕을 둔 배출량은 석탄화력발전소는 1502.1 kg/hr, 제철소는 2805.5 kg/hr였다. 이는 사업장에서 밝힌 2019년 연평균 배출량보다 각각 2.5배와 2.0배 큰 값이다. 이와 같은 차이가 나는 원인을 규명하기 위해서는 관측에 바탕을 둔 하향식 배출량과 활동도에 바탕을 둔 기존의 상향식 배출량을 산정함에 있어서 보다 면밀한 검토와 개선이 필요하다. 하향식 배출량의 개선을 위해서는 관측 불확도를 줄이는 것이 중요하다. 불확도를 높이는 요소의 하나는 지상에서 항공기가 운행될 수 있는 최저 고도까지 관측을 하지 않은 것이다. 이러한 불확도를 줄이는 방법은 지상에서 관측을 수행하며, 더 나아가서는 지상과 항공기 관측 최저 고도 사이에서 드론 등의 방법을 통해 관측을 수행하는 것이다. 바람장 역시 관측 및 외삽과 내삽을 이용하여 평면 분포를 구하면 평면에 대한 적분을 이용하여 평면 전체의 플럭스를 구할 수 있어 불확도를 줄일 수 있을 것이다. 상향식 배출량의 정확도 개선을 위해서는 측정이 이루어지고 있는 굴뚝의 배출량 자료 정확도 개선과 함께, 관측이 이루어지고 있지 않은 배출구의 현황 파악이 필요하다.

• 대기
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• 제25권1호
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• pp.185-191
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• 2015

고산기후관측소에서 2008년 8월과 9월의 Cheju ABC Plume Monsoon Experiment (CAPMEX) 기간 동안 3파장 photoacoustic soot spectrometer (PASS)로 측정된 에어로졸 흡수계수(${\sigma}_a$)와 에어로졸 산란계수(${\sigma}_s$)를 기존의 연구에서 널리 사용되고 있는 aethalometer 및 nephelometer의 동시관측 결과와 비교하였다. PASS ${\sigma}_a$의 관측결과는 aethalometer ${\sigma}_a$와 시간 변화 경향성이 매우 잘 일치했으나, 532 nm의 경우 절대값 면에서 PASS ${\sigma}_a$가 약 53% 큰 값을 보여 다소 차이가 있음을 알 수 있었다. PASS ${\sigma}_s$의 관측결과는 nephelometer ${\sigma}_s$와 비교했을 때, 근소한 차이로 매우 잘 일치함을 확인하였다(Bias Difference: $13.6Mm^{-1}$). 대기 중의 상대습도(RH)가 증가함에 따라 ${\sigma}_a$보다는 ${\sigma}_s$에 대한 영향이 큰 것으로 사료된다. Nephelometer ${\sigma}_s$와 PASS ${\sigma}_s$의 비율은 상대습도가 증가할수록 명확히 증가하는 경향성을 보였다. 이는 RH가 증가함에 따라서 PASS의 ${\sigma}_s$가 nephelometer ${\sigma}_s$에 비해서 상대적으로 감소하였음을 의미하며, 이러한 경향성은 RH가 70~80%를 넘어서면서 차이가 더욱 두드러지게 나타났다. Nephelometer와 aethalometer의 ${\sigma}_a$ 및 ${\sigma}_s$ 관측 결과 보다 PASS의 측정 결과로부터 산출한 $A{\AA}E$와 $S{\AA}E$가 더 크게 나타났다.

• Journal of Korean Society for Atmospheric Environment
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• 제22권E2호
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• pp.69-77
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• 2006

Combined gas and aerosol measurements at a downwind area of the volcanic plume would be essential for helping to access the impact of the volcanic eruption on the local ecosystem and residents. An intensive and the fine time resolution measurement of $SO_2$, sulfate and PM2.5 was made to estimate their distribution in the Kanto area of Japan during the Miyakejima volcanic eruption period. In Tokyo, the 1 hr average $SO_2$ concentration observed before the eruption was 23.9 ppbv, while that of after eruption was 140.4 ppbv. In the Saitama Prefecture, the average concentration of $SO_2$ marked in the present study was two times higher than the average before the volcanic eruption. The PM2.5 mass concentrations in Sitama ranged from 3.8 to $136{\mu}g\;m^{-3}$. Sulfate accounts for $4.4{\sim}39.6%$ of PM2.5 in Sitama. The good correlationship between the concentrations of $SO_2$ and sulfate was obtained. The results of the VAFTAD and HYSPLIT models indicate that $SO_2$, sulfate, and PM2.5 measured in the present study would be expected to be significantly affected by the Miyakejima volcanic plume.

• Bulletin of the Korean Chemical Society
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• 제29권8호
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• pp.1525-1532
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• 2008

An instrument was developed for the simultaneous determination of gas- and aerosol-phase nitrous acid (HONO). Gaseous HONO (HONO(g)) was sampled by a diffusion scrubber and particulate nitrite ($NO_2\;^-$(p)) was collected by a particle growth chamber. The collected samples were analyzed in time-sharing manner, based on the peroxynitrite-induced luminol chemiluminescence. The automated system was found to be sensitive with 13 pptv of detection limit, fast with 4 min. of sampling frequency, and simple and affordable to construct and operate. The system was optimized by adjusting the experimental parameters. The system was applied to the field measurement of gas- and particle-phase HONO during the springtime of 2004 in Gwangju, South Korea. HONO(g) concentrations varied diurnally from 200 pptv around 3 P.M. to 800 pptv at 5 A.M. The variation of $NO_2\;^-$(p) was not significant with the maximum of 240 pptv at 11 P.M. and the minimum of 170 pptv at 4 P.M., not displaying distinct characteristics.

• 한국대기환경학회지
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• 제20권1호
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• pp.17-31
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• 2004

The subway play an important part in serious traffic problems. However, because subway system is a closed environment, many serious air pollution problems occurred in subway stations and injured passenger's health. Therefor, it is a necessary to identify sources and to estimate pollutant sources in order to protect passenger's health and to keep clean subway environment. The purpose of this study was to analyze a air quality in the subway stations and to apply a new receptor methodology for quantitatively estimate of PM10 sources. In this study, the size distributions of particulate matters has been measured by using Aerosizer LD (U.S.A., API, Inc.). It's real time measurement capability of time-of-flight technique offers a significant advantage of user convenience and air pollution management. Also, the mass concentrations of PM 10 has been measured by using mini-vol portable sampler (U.S.A., Airmetrics Co.). The sampling performed in Seoul subway stations during the period of February 2000 and April 2000. The number distribution data used in this study consisted of 26 raw data sets in the Jongno-sam-ga station. Correlation Analysis can be used in subway stations for source separation and identification. Then, number contribution from each source is determined by the particle number balance (PNB). The mass concentration data used in this study consisted of 31 raw data in the 8 different stations. The mass contributions of PM10 sources in the concourse by using PMF/CMB model.

• 한국환경과학회지
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• 제11권6호
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• pp.507-517
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• 2002

Cheeka Peak is a unique site for monitoring the background chemistry and aerosol contents of pristine marine air at mid-latitude. During long-range onshore winds that occur frequently throughout the year, it is predicted to have the cleanest air in the northern hemisphere. Measurements of CO and O$_3$were conducted at Cheeka Peak Observatory(CPO) on the northwestern tip of Washington state, USA during March 6 ∼May 29, 2001. The data have been segregated to quantify the mixing ratio of these species in the Pacific marine atmosphere. Also the marine air masses were further classified into four categories based on 10-day backward isentropic trajectories; high, mid, and low latitude and those which had crossed over the Asian industrial region. The diurnal variation of CO and O$_3$at CPO showed a similar to tendency of background measurement site. When marine air mass flowed to CPO, CO concentration was lower and O$_3$was similar or higher than those of total data. The westerly flow from ocean, not easterly from continent occurred the high concentration of CO and O$_3$at CPO. Using the trajectory segregation of marine air mass, the comparison of concentration according to latitude calculated. the CO concentration of Asian trajectory was lower than other latitudes, O$_3$concentration was higher.

• 대한원격탐사학회지
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• 제32권3호
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• pp.245-251
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• 2016

황사의 주요 발원지인 중국 북부 둔황지역에 선포토미터를 설치하여 440, 675, 870 그리고 1020 nm 채널에서 황사의 파장별 입자편광소멸도를 산출하였다. 이와 함께 발원한 황사가 장거리 수송과정에 위치한 제주 고산과 일본 오사카에 설치된 선포토미터를 함께 분석하였다. 황사 발원지에서 1020 nm 파장에서 입자편광소멸도가 0.34로 가장 높은 수치를 보였다. 또한, 초미세먼지농도가 증가하는 경우 입자편광소멸도는 감소하는 경향을 보였다. 우리는 본 연구에서 선포토미터의 입자편광소멸도 산출을 통해 에어로졸에서 황사의 구성 비율이 변화함을 확인하였다.

• Asian Journal of Atmospheric Environment
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• 제5권2호
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• pp.105-112
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• 2011

In order to investigate the effects of local and synoptic meteorological conditions on urban scale particulate air pollutants observed over the Busan coastal area, power spectrum analysis was applied to observed particulate matter with an aerodynamic diameter $\leq10\;{\mu}m$ ($PM_{10}$) for the period from 1 October, 1993 to 31 December, 2004. Fast Fourier Transform (FFT) analysis was used to obtain the hourly mean observed $PM_{10}$ concentrations to identify different periodicity scales of $PM_{10}$ concentrations. The results showed that, aside from the typical and well-known periodicities such as diurnal and annual variations caused by anthropogenic influences, three other significant power spectral density peaks were identified: 7-day, 21-day and 2.25-year periodicities. Cospectrum analysis indicated that the seven-day variations were closely related to the synoptic meteorological conditions such as weak wind speed, which are relevant to the stagnant high pressure system slowly passing through the Korean Peninsula. The intra-seasonal 21-day variation was negatively correlated with wind speed but was consistently positively correlated with relative humidity, which is related to aerosol formation that can be achieved as a result of the hygroscopic characteristics of aerosols. However, the quasibiennial 2.25-year variation was correlated with the frequency of Asian dust occurrence, the periodicities of which have been recorded inter-annually over the Korean Peninsula.