• Journal of the Optical Society of Korea
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• v.15 no.1
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• pp.90-95
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• 2011

12-year LIDAR observations of tropospheric aerosol vertical distribution using a Mie scattering LIDAR in Hefei ($31.9^{\circ}N$, $117.2^{\circ}E$) from 1998 to 2009 are presented and analyzed in this paper. Characters of temporal variation and vertical distribution of tropospheric aerosol over Hefei are summarized from the LIDAR measurements. The impacts of natural source and human activities on the aerosol vertical distribution over Hefei could be seen clearly. Dust particles from the north in spring could affect the aerosol distributions below about 12 km over Hefei, and aerosol scale height in April reaches $2.29{\pm}0.68\;km$. Both LIDAR measurements and surface visibility imply that aerosols in the lower troposphere have been increasing since about 2005.

• Journal of the Optical Society of Korea
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• v.19 no.6
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• pp.695-699
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• 2015

A high spectral resolution lidar (HSRL) system based on injection-seeded Nd:YAG laser and iodine absorption filter has been developed for the quantitative measurement of aerosol and cloud. The laser frequency is stabilized at 80 MHz by a frequency locking system and the absorption line of iodine cell is selected at the 1111 line with 2 GHz width. The observations show that the HSRL can provide vertical profiles of particle extinction coefficient, backscattering coefficient and lidar ratio for cloud and aerosol up to 12 km altitude, simultaneously. For the measured cases, the lidar ratios are 10~20 sr for cloud, 28~37 sr for dust, and 58~70 sr for urban pollution aerosol. It reveals the potential of HSRL to distinguish the type of aerosol and cloud. Time series measurements are given and demonstrate that the HSRL has ability to continuously observe the aerosol and cloud for day and night.

• Journal of the Optical Society of Korea
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• v.15 no.3
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• pp.209-215
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• 2011

A new iterative algorithm is developed to estimate LIDAR ratio for a thin cirrus cloud over an aerosol layer. First, the thin cirrus cloud is screened out and replaced by a modeled LIDAR signal and the extinction coefficients of the aerosol layer are derived using the Fernald backward method. These aerosol coefficients are referred as the "actual values". Second, the original LIDAR signal which includes the thin cirrus cloud is also inverted by the Fernald backward method down to the aerosol layer but using different LIDAR ratio for the thin cirrus cloud. Depending on the different assumptions about the LIDAR ratio of the thin cirrus cloud, different sets of aerosol extinction can be derived. The "actual values" which are found in the first step can be used to constrain this iterative progress and the correct LIDAR ratio of the thin cirrus cloud can be found. The detailed description of this method and retrieval examples are given in the paper. The cases compared with other methods are presented and the statistical result is also shown and agrees well with other studies.

• Journal of the Optical Society of Korea
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• v.14 no.4
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• pp.444-450
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• 2010

The traditional approach to inverting aerosol extinction makes use of the assumption of a constant LIDAR ratio in the entire Mie-LIDAR signal profile using the Fernald method. For the large uncertainty in the cloud optical depth caused by the assumed constant LIDAR ratio, an not negligible error of the retrieved aerosol extinction below the cloud will be caused in the backward integration of the Fernald method. A new algorithm to determine aerosol extinction below a cirrus cloud from Mie-LIDAR signals, based on a new cloud boundary detection method and a Mie-LIDAR signal modification method, combined with the backward integration of the Fernald method is developed. The result shows that the cloud boundary detection method is reliable, and the aerosol extinction below the cirrus cloud found by inverting from the modified signal is more efficacious than the one from the measured signal including the cloud-layer. The error due to modification is less than 10% taken in our present example.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.4
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• pp.389-398
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• 1996

In order to understand the relative importance of various pathways leading to the production and transformation of aerosols under different atmospheric conditions, the behavior of atmospheric aerosols have been investigated using a high volume tape sample in Seoul for a week period during August 1990. The concentrations of anion $(SO^{2-}_4, NO^-_3, CI^-)$ and cation $(Ca^{2+}, Na^+, NH^+_4)$ species of aerosol samples were analyzed to identify the ionic composition of aerosols and to estimate their relative contributions to aerosol formation. The concentrations of aerosol species were calculated by a multiple regression model. The results of our calculations indicate the existence of various chemical species such as $(NH_4)_2SO_4, Na_2SO_4, CaSO_4, NH_4NO_3, NaNO_3, Ca(NO_3)_2, NH_4Cl$, and NaCl salts. According to our calculations, the most dominant species of aerosol was $(NH_4)_2SO_4$ with the mean concentration of 23.3 $/mu g/m^3$ (66.9%). The proportion of different componts with aerosol (e.g., $NH_4NO_3$ and $NH_4Cl$) was strongly affected by temperature, relative humidity, and partial presure of gases.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.11a
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• pp.277-282
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• 2008

We developed fixed aerosol auto fire-extinguishing systems which are different from fire suppression systems like powder extinguisher or halon extinguishing system, etc. Fixed aerosol auto fire-extinguishing substances which are including solid alkali salts generated by combustion of solid composition. It represents high fire suppression ability due to particle friendly auto fire-extinguishing systems for the reason of excluding toxic substances in it's composition.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.470-482
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• 2008

Seasonal variations of chemical composition and optical properties of aerosols at Seoul and Gosan were investigated using the ground-based aerosol measurements and an optical model calculation. The mass fraction of elemental carbon was $8{\sim}17%$, but its contribution on light absorption was high up to $29{\sim}48%$ in Seoul. In Gosan, the contribution of water soluble aerosols on aerosol extinction was $83{\sim}94%$ due to the high mass fraction of these particles in the range of $56{\sim}88%$. Model calculation showed that the water holding capacity of aerosols was larger in Gosan than in Seoul because of higher relative humidity and temperature along with abundant water soluble aerosols. Difference between measured and calculated aerosol optical depths was the highest in summer. This was because aerosol optical depth calculated from ground-based measurements could not consider aerosol loadings at high altitude in spite of high column-integrated aerosol loadings observed by Sun photometer. Although hygroscopic growth was expected to be dominant in summer, the mass concentration of water soluble aerosols was too low to permit this growth.

• Atmosphere
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• v.26 no.3
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• pp.357-372
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• 2016

Northeast Asian regions have recently become the main source of anthropogenic and natural aerosols. Measurement of aerosols on the sea in these regions have been rarely conducted since the experimental campaigns such as ACE-ASIA (Asian Pacific Regional Aerosol Characterization Experiment) in 2001. Research vessel observations of aerosol mass and chemical composition were performed on the Yellow and south sea around the Korean peninsula. The ship measurements showed six representative cases such as aerosol event and non-event cases during the study periods. On non-event cases, the anthropogenic chemical and natural soil composition on the Yellow sea were greater than those on the south sea. On aerosol event cases such as haze, haze with dust, and dust, the measured mass concentrations of anthropogenic chemical and element compositions were clearly changed by the events. In particular, methanesulfonate ($MSA^-$, $CH_3SO_3^-$), a main component of natural oceanic aerosol important for sulfur circulation on Earth, was first observed by the vessel in Korea, and its concentration on the Yellow sea was three times that on the south sea during the study period. Sea salt concentration important to chemical composition on the sea is related to wind speed. Coefficients of determination ($R^2$) between wind speed and sea salt concentration were 0.68 in $PM_{10}$ and 0.82 in $PM_{2.5}$. Maximum wave height was not found to be correlated to the sea salt concentration. When sea-salt comes into contact with pollutants, the total sea-salt mass is reduced, i.e., a loss of $Cl^-$ concentration from NaCl, the main chemical composing sea salt, is estimated by reaction with $HNO_3$(gas) and $H_2SO_4$(gas). The $Cl^-$ concentration loss by $SO_4^{2-}$ and $NO_3^-$ more easily increased for $PM_{10}$ compared to $PM_{2.5}$. The results of this study will be applied to verifying a dust-haze forecasting model. In addition, continued vessel measurements of aerosol data will become important to research for climate change studies in the future.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.5
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• pp.485-500
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• 2016

We examined acidity state of inorganic aerosol and oxidation state of organic aerosol by High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) at Baengnyeong Super site from Jan 2012 to Dec 2013. Additionally, we carried out the analysis for the aerosol component group of organic matter ($C_xH_y$, $C_xH_yO_1$, $C_xH_yO_z$, $C_xH_yO_zN_p$) and elemental composition to calculate H/C, O/C, N/C, OM/OC and identify the oxidation state. The aerosol chemical composition in this study is dominated by sulfate ($SO_4{^{2-}}$), nitrate ($NO_3{^-}$) plays a smaller role in aerosol acidity. Ammonium ($NH_4{^+}$) was found in a formation of $(NH_4)_3H(SO_4)_2$. However, the binding formations of $NH_4NO_3$ and $NH_4Cl$ increase in the winter. $C_xH_yO_1$ indicating the oxidized state of $PM_{1.0}$ has the highest ratio of 41% while $C_xH_y$ indicating the non-oxidized state has a lower ratio of 36%, meaning that the oxidation level of $PM_{1.0}$ in Baengnyeong Island is high. The ratio between H/C and O/C was 1.33 and 0.78 respectively, showing the characteristic of LV-OOA (Low volatility-Oxygenated Organic Aerosol). Acidic and oxidized aerosols sampled during this field study were largely anthropogenic in origin from Chinese continent and photochemically aged.

• Asian Journal of Atmospheric Environment
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• v.6 no.4
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• pp.304-313
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• 2012

In this study, the ${\AA}$ngstrom exponent for polydispersed aerosol during dynamic processes was investigated. Log-normal aerosol size distribution was assumed, and a sensitivity analysis of the ${\AA}$ngstrom exponent with regards the coagulation and condensation process was performed. The ${\AA}$ngstrom exponent is expected to decrease because of the particle growth due to coagulation and condensation. However, it is difficult to quantify the degree of change. In order to understand quantitatively the change in the ${\AA}$ngstrom exponent during coagulation and condensation, different real and imaginary parts of the refractive index were considered. The results show that the ${\AA}$ngstrom exponent is sensitive to changes in size distribution and refractive index. The total number concentration decreases and the geometric mean diameter of aerosols increase during coagulation. On the while, the geometric standard deviation approaches monodispersed size distribution during the condensation process, and this change in size distribution affects the ${\AA}$ngstrom exponent. The degree of change in the ${\AA}$ngstrom exponent depends on the refractive index and initial size distribution, and the size parameter changes with the ${\AA}$ngstrom exponent for a given refractive index or chemical composition; this indicates that the size distribution plays an important role in determining the ${\AA}$ngstrom exponent as well as the chemical composition. Subsequently, this study shows how the ${\AA}$ngstrom exponent changes quantitatively during the aerosol dynamics processes for a log-normal aerosol size distribution for different refractive indices; the results showed good agreement with the results for simple analytic size distribution solutions.