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Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 수화 특성에 관한 연구)

  • Sim, Jun-Soo;Lee, Ki-Gang;Kim, Yu-Taek;Kang, Seung-Ku
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.185-190
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    • 2012
  • The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.

A Study on Photo-Luminescence Spectrum Properties of ZnS:Mn QD Prepared by Wet-Process (습식공정을 이용한 ZnS:Mn2+계 QD의 합성 조건에 따른 광 특성 변화 연구)

  • Cha, Ji Min;Lee, Yoon Ji;Moon, Seong Cheol;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.42-47
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    • 2017
  • In this study, the physical and optical properties of $ZnS:Mn^{2+}$ Quantum Dot prepared by wet-process condition with Mn/Zn ratio was valuated. The powder characteristics and optical behavior were investigated through XRD, TEM and Photo spectrometer exicted by various UV light source. We found the main peak of ZnS (111) was shifted by 0.8 degree to low angle position with increasing stirring energy from 200 RPM to 600 RPM, which is thought to be the increase of lattice defects during wet process. The photo luminescence at 600 RPM shows also higher blue intensity which is well correlated with XRD results. With increasing Mn/Zn ratio, the PL intensity become higher and shifed by 8.5nm to right side, by the increment of substitutional $Mn^{2+}$ ions.

The Study of fabrication and characteristics of Inorganic EL Device with combination of high dielectric constant layer (고유전 유전막을 적용한 Inorganic EL Device 제작 및 특성 연구)

  • Lee, Gun-Sub;Ryu, Ji-Ho;An, Sung-Il;Lee, Seong-Eui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.392-393
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    • 2007
  • In this paper, we report the characteristics inorganic EL device with high dielectric constant materials of PMN, PZT. Fabricated EL device shows stable light emission even at 20kHz -400Volt without any break down failure. Brightness voltage curve of EL device is same with typical EL. As increasing applied voltage, the brightness increased linearly. From the results of Frequency and duty ratio variation, over 50% of brightness increment was seen. Luminous efficiency was increased upto 200V range and saturated over 200V by slow increasement of light emission. We got e bright stable emission of 1733 cd/m2 at the condition of Frequency 35 KHz, Duty 10%, 400V.

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Synthesis and Electrochemical Performance of Li2MnSiO4 for Lithium Ion Battery Prepared by Amorphous Silica Precusor (비정질 실리콘 산화물을 이용한 리튬망간실리콘산화물의 합성 및 전기화학적 특성 평가)

  • Jin, Yun-Ho;Lee, Kun-Jae;Kang, Lee-Seung;Jung, Hang-Chul;Hong, Hyun-Seon
    • Journal of Powder Materials
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    • v.19 no.3
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    • pp.210-214
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    • 2012
  • Mass production-capable $Li_2MnSiO_4$ powder was synthesized for use as cathode material in state-of-the-art lithium-ion batteries. These batteries are main powder sources for high tech-end digital electronic equipments and electric vehicles in the near future and they must possess high specific capacity and durable charge-discharge characteristics. Amorphous silicone was quite superior to crystalline one as starting material to fabricate silicone oxide with high reactivity between precursors of sol-gel type reaction intermediates. The amorphous silicone starting material also has beneficial effect of efficiently controlling secondary phases, most notably $Li_xSiO_x$. Lastly, carbon was coated on $Li_2MnSiO_4$ powders by using sucrose to afford some improved electrical conductivity. The carbon-coated $Li_2MnSiO_4$ cathode material was further characterized using SEM, XRD, and galvanostatic charge/discharge test method for morphological and electrochemical examinations. Coin cell was subject to 1.5-4.8 V at C/20, where 74 mAh/g was observed during primary discharge cycle.

Aqueous-Base-Developable Benzocyclobutene (BCB)-Based Material for Display Applications

  • So, Ying-Hung;Stark, Edmund;Li, Yongfu;Achen, Albert;Scheck, Dan;Kisting, Scott;Baranek, Kayla;Wood, Charilie
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1510-1515
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    • 2006
  • A self-priming and photosensitive aqueous-basedevelopable benzocyclobutene (BCB)-based dielectric material curable in air is described. Patterned films have high resolution. Whether cured in nitrogen or in air, the formulation produces a film with optical, electrical, thermal, and mechanical properties desired for many microelectronic applications, such as a planarization layer or insulation layer in display applications. A self-priming, air-curable nonphoto- sensitive BCB material is also described.

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Fabrication and Microstructure/Properties of Bulk-type Tantalum Material by a Kinetic Spray Process (Kinetic Spray 공정을 이용한 벌크형 탄탈륨 소재의 제조 및 미세조직/물성)

  • Lee, Ji-Hye;Kim, Ji-Won;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.23 no.1
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    • pp.8-14
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    • 2016
  • A bulk-type Ta material is fabricated using the kinetic spray process and its microstructure and physical properties are investigated. Ta powder with an angular size in the range $9-37{\mu}m$ (purity 99.95%) is sprayed on a Cu plate to form a coating layer. As a result, ~7 mm-sized bulk-type high-density material capable of being used as a sputter material is fabricated. In order to assess the physical properties of the thick coating layer at different locations, the coating material is observed at three different locations (surface, center, and interface). Furthermore, a vacuum heat treatment is applied to the coating material to reduce the variation of physical properties at different locations of the coating material and improve the density. OM, Vickers hardness test, SEM, XRD, and EBSD are implemented for analyzing the microstructure and physical properties. The fabricated Ta coating material produces porosity of 0.11~0.12%, hardness of 311~327 Hv, and minor variations at different locations. In addition, a decrease in the porosity and hardness is observed at different locations upon heat treatment.

Effect of Humidity on Friction Characteristics of Automotive Friction Materials

  • Kim, Seong-Jin;Lee, Jae-Young;Jang, Ho
    • KSTLE International Journal
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    • v.2 no.2
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    • pp.150-153
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    • 2001
  • The effects of humidity on friction performance of automotive brake materials were studied using a pad-on-disk type friction tester. Three different friction materials based on a simple formulation were investigated by changing the solid lubricant graphite, MoS$_2$, and Sb$_2$S$_3$. Friction materials without solid lubricants were also examined to study the effect of other ingredients in the matrix on humidity. The friction material containing graphite was strongly affected by the humidity showing lower friction coefficient at high humidity level than other conditions. On the other hand, the friction material containing MoS$_2$exhibited higher friction coefficient at initial stage under high humidity level. The friction material without solid lubricant or with Sb$_2$S$_3$ was not affected by humidity conditions. However, the friction material containing barite showed strong speed dependence.

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Physicochemical characterization of porcine bone-derived grafting material and comparison with bovine xenografts for dental applications

  • Lee, Jung Heon;Yi, Gyu Sung;Lee, Jin Woong;Kim, Deug Joong
    • Journal of Periodontal and Implant Science
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    • v.47 no.6
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    • pp.388-401
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    • 2017
  • Purpose: The physicochemical properties of a xenograft are very important because they strongly influence the bone regeneration capabilities of the graft material. Even though porcine xenografts have many advantages, only a few porcine xenografts are commercially available, and most of their physicochemical characteristics have yet to be reported. Thus, in this work we aimed to investigate the physicochemical characteristics of a porcine bone grafting material and compare them with those of 2 commercially available bovine xenografts to assess the potential of xenogenic porcine bone graft materials for dental applications. Methods: We used various characterization techniques, such as scanning electron microscopy, the Brunauer-Emmett-Teller adsorption method, atomic force microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, and others, to compare the physicochemical properties of xenografts of different origins. Results: The porcine bone grafting material had relatively high porosity (78.4%) and a large average specific surface area (SSA; $69.9m^2/g$), with high surface roughness (10-point average roughness, $4.47{\mu}m$) and sub-100-nm hydroxyapatite crystals on the surface. Moreover, this material presented a significant fraction of sub-100-nm pores, with negligible amounts of residual organic substances. Apart from some minor differences, the overall characteristics of the porcine bone grafting material were very similar to those of one of the bovine bone grafting material. However, many of these morphostructural properties were significantly different from the other bovine bone grafting material, which exhibited relatively smooth surface morphology with a porosity of 62.0% and an average SSA of $0.5m^2/g$. Conclusions: Considering that both bovine bone grafting materials have been successfully used in oral surgery applications in the last few decades, this work shows that the porcinederived grafting material possesses most of the key physiochemical characteristics required for its application as a highly efficient xenograft material for bone replacement.