• Title/Summary/Keyword: Advanced Water treatment

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A study on reactive chlorine species generation enhanced by heterojunction structures on surface of IrO2-based anodes for water treatment (IrO2 기반 수처리용 산화 전극의 표면 이종 접합 구성에 따른 활성 염소종 발생 증진 특성 연구)

  • Hong, Sukhwa;Cho, Kangwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.349-355
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    • 2018
  • This study interrogated multi-layer heterojunction anodes were interrogated for potential applications to water treatment. The multi-layer anodes with outer layers of $SnO_2/Bi_2O_3$ and/or $TiO_2/Bi_2O_3$ onto $IrO_2/Ta_2O_5$ electrodes were prepared by thermal decomposition and characterized in terms of reactive chlorine species (RCS) generation in 50 mM NaCl solutions. The $IrO_2/Ta_2O_5$ layer on Ti substrate (Anode 1) primarily served as an electron shuttle. The current efficiency (CE) and energy efficiency (EE) for RCS generation were significantly enhanced by the further coating of $SnO_2/Bi_2O_3$ (Anode 2) and $TiO_2/Bi_2O_3$ (Anode 3) layers onto the Anode 1, despite moderate losses in electrical conductivity and active surface area. The CE of the Anode 3 was found to show the highest RCS generation rate, whereas the multi-junction architecture (Anode 4, sequential coating of $IrO_2/Ta_2O_5$, $SnO_2/Bi_2O_3$, and $TiO_2/Bi_2O_3$) showed marginal improvement. The microscopic observations indicated that the outer $TiO_2/Bi_2O_3$ could form a crack-free layer by an incorporation of anatase $TiO_2$ particles, potentially increasing the service life of the anode. The results of this study are expected to broaden the usage of dimensionally stable anodes in water treatment with an enhanced RCS generation and lifetime.

Control of Algal Blooms in Eutrophic Water Using Porous Dolomite Granules

  • Huh, Jae-Hoon;Choi, Young-Hoon;Lee, Shin Haeng;Cheong, Sun Hee;Ahn, Ji Whan
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.108-113
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    • 2017
  • The use of aluminum-based coagulants in water pretreatment is being carefully considered because aluminum exposure is a risk factor for the onset of Alzheimer's disease. Lightly burned-dolomite kiln dust (LB-DKD) was evaluated as an alternative coagulant because it contains high levels of the healthful minerals calcium and magnesium. An organic pore forming agent (OPFA) was incorporated to prepare porous granules after OPFA removal through a thermal decomposition process. A spray drying method was used to produce uniform and reproducible spherical granules with low density, since fine dolomite particles have irregular agglomeration behavior in the hydration reaction. The use of fine dolomite powder and different porosity granules led to a visible color change in raw algae (RA) containing water, from dark green to transparent colorlessness. Also, dolomite powders and granules exhibited a mean removal efficiency of 48.3% in total nitrogen (T-N), a gradual increase in the removal efficiency of total phosphorus (T-P) as granule porosity increased. We demonstrate that porous dolomite granules can improve the settling time and water quality in summer seasons for the emergent treatment of excessive algal blooms in eutrophic water.

Hydrophilization of hydrophobic membrane surfaces for the enhancement of water flux via adsorption of water-soluble polymers

  • Kim, Ka Young;Rhim, Ji Won
    • Membrane and Water Treatment
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    • v.7 no.2
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    • pp.101-113
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    • 2016
  • In this study, to improve the water flux of porous hydrophobic membranes, various water-soluble polymers including neutral, cationic and anionic polymers were adsorbed using 'salting-out' method. The adsorbed hydrophobic membrane surfaces were characterized mainly via the measurements of contact angles and scanning electron microscopy (SEM) images. To enhance the durability of the modified membranes, the water-soluble polymers such poly(vinyl alcohol) (PVA) were crosslinked with glutaraldehyde (GA) and found to be resistant for more than 2 months in vigorously stirred water. The water flux was much more increased when the ionic polymers used as the coating materials rather than the neutral polymer and in this case, about 70% of $0.31L/m^2{\cdot}h$ (LMH) to 0.50 LMH was increased when 300 mg/L of polyacrylamide (PAAm) was used as the coating agents. Among the cationic coating polymers such as poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA), poly(acrylic acid-comaleic acid) (PAM) and poly(acrylic acid) (PAA), PSSA_MA was found to be the best in terms of contact angle and water flux. In the case of PSSA_MA, the water flux was enhanced about 80%. The low concentration of the coating solution was better to hydrophilize while the high concentration inclined to block the pores on the membrane surfaces. The best coating condition was found: (1) coating concentration 150 to 300 mg/L, (2) ionic strength 0.15, (3) coating time 20 min.

Water utilities vulnerability assessment and adaption strategies for climate change in Jeju province (제주도 기후변화 관련 상수도시설 취약성 평가 및 적응대책)

  • Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.6
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    • pp.517-526
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    • 2018
  • Climate adaptation strategies for water utilities including 16 water treatment plants(WTPs) in Jeju were investigated. Drought, heat wave, and heavy rain were among the most significant climate factors affecting water utilities in Jeju. Heat wave increases water temperature, which in turn increases the concentration of algae, color, and odor materials. Some adaption strategies for the heat wave can be strengthening water monitoring and introducing advanced water treatments. Heavy rain increases raw water turbidity in surface water. The 7 WTPs that take raw water from streams or springs had a maximum turbidity of less than 50 NTU under heavy rain. However, due to concerns of turbidity spike in treated water, some WTPs discontinued intaking raw water when raw water turbidity increased more than 2 NTU. They instead received treated water from other WTPs which took groundwater for water supply. This happens because of the low skills of employees. Thus, there needs to be an increase in operator competency and upgrade of water facilities for the adaption of heavy rain. To improve adaption for the drought, there should be an increase in the capacity of intake facilities of surface water as well as a decrease in water loss. In addition, water consumption per person should be decreased.

Development of the method for optimal water supply pump operation considering disinfection performance (소독능을 고려한 송수펌프 최적운영기법 개발)

  • Hyung, Jinseok;Kim, Kibum;Seo, Jeewon;Kim, Taehyeon;Koo, Jayong
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.5
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    • pp.421-434
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    • 2018
  • Water supply/intake pumps operation use 70~80% of power costs in water treatment plants. In the water treatment plant, seasonal and hourly differential electricity rates are applied, so proper pump scheduling can yield power cost savings. Accordingly, the purpose of this study was to develop an optimal water supply pump scheduling scheme. An optimal operation method of water supply pumps by using genetic algorithm was developed. Also, a method to minimize power cost for water supply pump operation based on pump performance derived from the thermodynamic pump efficiency measurement method was proposed. Water level constraints to provide sufficient disinfection performance in a clearwell and reservoirs were calibrated. In addition, continuous operation time constraints were calibrated to prevent frequent pump switching. As a result of optimization, savings ratios during 7 days in winter and summer were 4.5% and 5.1%, respectively. In this study, the method for optimal water pump operation was developed to secure disinfection performance in the clearwell and to save power cost. It is expected that it will be used as a more advanced optimal water pump operation method through further studies such as water demand forecasting and efficiency according to pump combination.

Advanced Water Treatment of High Turbidity Source by Hybrid Process of Ceramic Ultrafiltration and Photocatalyst: 1. Effects of Photocatalyst and Water-back-flushing Condition (세라믹 한외여과 및 광촉매 혼성공정에 의한 고탁도 원수의 고도정수처리: 1. 광촉매 및 물역세척 조건의 영향)

  • Cong, Gao-Si;Park, Jin-Yong
    • Membrane Journal
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    • v.21 no.2
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    • pp.127-140
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    • 2011
  • The effects of $TiO_2$ photocatalyst coating bead concentration, water-back-flushing period (FT), and back-flushing time (BT) were investigated in hybrid process of ceramic ultrafiltration and photocatalyst for advanced drinking water treatment in this study. Photocatalyst coating bead concentration was changed in the range of 10~40 g/L, FT in 2~10 min and BT in 6~30 sec. Then, we observed the effects on resistance of membrane fouling $(R_f)$, permeate flux (J) and total permeate volume $(V_{\Upsilon})$ during total filtration time of 180 min. As decreasing photocatalyst coating bead concentration, $R_f$ increased and J decreased. $V_{\Upsilon}$ was the highest value of 8.85 L at 40 g/L of photocatalyst coating bead concentration. At FT change experiment, $R_f$ decreased and J increased as decreasing FT. Then $R_f$ decreased and J increased according to increasing BT at BT change experiment. Because at NBF (no back-flushing) dramatic membrane fouling reduced membrane pore size, turbid and dissolved organic matters ($UV_{254}$ absorbance) could be removed efficiently. Therefore, treatment efficiencies of turbidity and dissolved organic matters were the highest at NBF. Then by cleaning effect of photocatalyst coating bead, the treatment efficiencies of turbidity and dissolved organic matters increased as decreasing FT and increasing BT.

Degradation and Neutralization of Total Residual Oxidant (TRO) in the Treated Ballast Water by Ozonation

  • Park, Sung-Jin;Bin, Jung-In;Lee, Eon-Sung;Kim, In-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.3
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    • pp.399-406
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    • 2010
  • The aims of this study are to provide data on the ozone dosage control system and TRO sensor performance, to assess the performance of the degradation of total residual oxidant (TRO) neutralizer and to provide data on degradation rates of TRO in the ballast tanks, following treatment by the Ozone BWTS. This study includes the results of an evaluation of the TRO neutralizer, which was tested on the test barge. Accordingly, it has undertaken the evaluation of TRO degradation rates following treatment by the Ozone BWTS.

EFFECTS OF H2O2, TURBIDITY AND METALS ON SONOCHEMICAL DECOMPOSITION OF HUMIC SUBSTANCES IN WASTEWATER EFFLUENT

  • Kim, Il-Kyu
    • Journal of Korean Society on Water Environment
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    • v.18 no.3
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    • pp.271-282
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    • 2002
  • The sonochemical process has been applied as a treatment method to investigate its effect on the decomposition of humic substances (HS). The reaction kinetics and mechanisms in the process of sonochemical treatment for humic substances in wastewater have also been discussed. It was observed that the metal ions such Fe(II) and Mn(II) showed catalytic effects, while Al(III), Ca(II), and Mg(II) had inhibitory effects on the decomposition of humic substances in sonochemical reaction with hydrogen peroxide. Experimental results also showed factors such as hydrogen peroxide dose affected the formation of disinfection by-products. Two trihalomethanes, chloroform and dichlorobromomethane were formed as major disinfection by-products during chlorination. The depolymerization and the radical reaction of HS radicals appear to occur simultaneously. The final step of the reaction is the conversion of organic acids to carbon dioxide.

Development and Application of Static Mixer (스태틱 믹서 개발 및 응용)

  • Yang, Hei-Cheon
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.5
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    • pp.506-513
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    • 2007
  • One of the most widely used static mixers is Sulzer type mixer. However the structure of the element is so complicated that the mixing efficiency is better than others, whereas the pressure drop is larger than the others. Therefore new elements are necessary to reduce the pressure drop and to minimize the decrease of the mixing efficiency compared with the Sulzer ones. The objectives of this study are to develop new static mixer and to perform the experimental investigation in order to evaluate the performance of the new one, and to investigate the applicability of the one in an inline coagulant mixing system for water treatment, The pressure drops of the new static mixer elements were about 4-12% lower than that of the Sulzer SMX one, and the mixing efficiency of the Sulzer SMX one was about 2-5% higher than that of the new ones. The inline coagulant mixing system with a new static mixer element performed significantly better than the traditional mechanical mixing system for turbidity removal.

Bio-filters for the Treatment of VOCs and Odors - A Review

  • Vikrant, Kumar;Kim, Ki-Hyun;Szulejko, Jan E.;Pandey, Sudhir Kumar;Singh, R.S.;Giri, B.S.;Brown, Richard J.C.;Lee, S.H.
    • Asian Journal of Atmospheric Environment
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    • v.11 no.3
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    • pp.139-152
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    • 2017
  • Excessive amounts of volatile organic compounds (VOCs) and odorants discharged into the environment are highly dangerous to human health as well as to ecological systems. Biological treatments of waste gas streams, called biofiltration, containing VOCs and odorous compounds has gained much attention because biofilters are more cost effective and environmentally friendly than conventional air pollution control technologies. This review provides an overview of biotrickling filtration, which is a type of biofiltration including continuous trickled-water flow inside filter media, for VOC and odor abatement. The configuration, design, cost effectiveness, removal capacity and environmental impact of this techniques and the future research and development needs in this area are all considered.