• Journal of Korean Society of Water and Wastewater
• /
• v.34 no.6
• /
• pp.393-402
• /
• 2020

In the membrane process, it is important to improve water treatment efficiency to ensure water quality and minimize membrane fouling. In this study, a pilot study of membrane process using reservoir water was conducted for a long time to secure high flux operation technology capable of responding to influent turbidity changes. The raw water and DAF(Dissolved Air Flotation) treated water were used for influent water of membrane to analyze the effect of water quality on the TMP (Trans Membrane Pressure) and to optimize the membrane operation. When the membrane flux were operated at 70 LMH and 80 LMH under stable water quality conditions with an inlet turbidity of 10 NTU or less, the TMP increase rates were 0.28 and 0.24 kPa/d, respectively, with minor difference. When the membrane with high flux of 80 LMH was operated for a long time under inlet turbidity of 10 NTU or more, the TMP increase rate showed the maximum of 43.5 kPa/d. However, when the CEB(Chemically Enhanced Backwash) cycle was changed from 7 to 1 day, it was confirmed that the TMP increase rate was stable to 0.23 kPa/d. As a result of applying pre-treatment process(DAF) on unstability water quality conditions, it was confirmed that the TMP rise rates differed by 0.17 and 0.64 kPa/d according to the optimization of the coagulant injection. When combined with coagulation pretreatment, it was thought that the balance with the membrane process was more important than the emphasis on efficiency of the pretreatment process. It was considered that stable TMP can be maintained by optimizing the cleaning conditions when the stable or unstable water quality even in the high flux operation on membrane process.

• Applied Chemistry for Engineering
• /
• v.33 no.5
• /
• pp.502-522
• /
• 2022

Clay minerals are natural materials that show widespread applications in various branches of science, including environmental sciences, in particular the remediation of water contaminated with various water pollutants. Modified clays and minerals have attracted the attention of researchers in the recent past since the modified materials are seemingly more useful and efficient for removing emerging water contaminants. Therefore, modified engineered materials having multi-functionalities have received greater interest from researchers. The advanced clay-based materials are highly effective in the remediation of water contaminated with organic and inorganic contaminants, and these materials show enhanced selectivity towards the specific pollutants. The review inherently discusses various methods employed in the modification of clays and addresses the challenges in synthesizing the advanced engineered materials precursor to natural clay minerals. The changes in physical and chemical properties, as investigated by various characterization techniques before and after the modifications, are broadly explained. Further, the implications of these materials for the decontamination of waterbodies as contaminated with potential water pollutants are extensively discussed. Additionally, the insights involved in the removal of organic and inorganic pollutants are discussed in the review. Furthermore, the future perspectives and specific challenges in the scaling up of the treatment methods in technology development are included in this communication.

• Journal of Powder Materials
• /
• v.29 no.5
• /
• pp.411-417
• /
• 2022

Environmental issues such as global warming due to fossil fuel use are now major worldwide concerns, and interest in renewable and clean energy is growing. Of the various types of renewable energy, green hydrogen energy has recently attracted attention because of its eco-friendly and high-energy density. Electrochemical water splitting is considered a pollution-free means of producing clean hydrogen and oxygen and in large quantities. The development of non-noble electrocatalysts with low cost and high performance in water splitting has also attracted considerable attention. In this study, we successfully synthesized a NiCo₂O₄/NF electrode for an oxygen evolution reaction in alkaline water splitting using a hydrothermal method, which was followed by post-heat treatment. The effects of heat treatment on the electrochemical performance of the electrodes were evaluated under different heat-treatment conditions. The optimized NCO/NF-300 electrode showed an overpotential of 416 mV at a high current density of 50 mA/cm² and a low Tafel slope (49.06 mV dec^-1). It also showed excellent stability (due to the large surface area) and the lowest charge transfer resistance (12.59 Ω). The results suggested that our noble-metal free electrodes have great potential for use in developing alkaline electrolysis systems.

• Journal of Korean Society on Water Environment
• /
• v.24 no.2
• /
• pp.164-168
• /
• 2008

Perchlorate, which is still unregulated, is found in tap water, posing a threat to public health. In and out of Korea, there is no clear standard for drinking water quality or discharge. To make matters worse, Perchlorate study is in its infancy in Korea. This research tracked fresh water and purified water of water purification facility A and B located at the city of D, where Nak-dong River is being utilized as the purified water. And it was found that purified water shows no particular pattern in Perchlorate concentrations but represented a higher level of concentration compared to fresh water. With utilizing the research results, the study sought the impact of activated-carbon treatment process on Perchlorate elimination and found out that Perchlorate concentrations increased 38% after the process. The result proves that conventional water purification process can't eliminate Perchlorate. Therefore, it is reasonable that Perchlorate discharge from sources should be minimized.

• Journal of environmental and Sanitary engineering
• /
• v.5 no.2
• /
• pp.15-21
• /
• 1990

Current analyses of tap water in Seoul metropolitan area prove the water is still safe, despite the Pollution of raw water source. However, it also significantly suggests that a feasibility study of apply, additional advanced technology to existing water treatment processes is needed in order to cope with future pollution. Also, the monitoring of water quality within private, multi-household buildings is important as the monitoring of public water distribution system.

• International Journal of Highway Engineering
• /
• v.16 no.2
• /
• pp.35-41
• /
• 2014

PURPOSES : Surface treatment is a favorable method in the pavement preventive maintenance. This study (Part I) aimed to develop the low viscosity filling material for waterproof characteristics and high penetrable and weather resistance, and a series of companion study (Part II) presents the coating characteristics and performance analysis using field and lab tests. METHODS : Hydrophobic characteristics of the advanced surface treatment material are observed and measured the filling depth and the permeability for sand and asphalt pavement specimen using the water absorption test and permeability test, X-RAY CT test. Color difference for the weather resistance using ultraviolet ray accelerated weathering test is compared with asphalt pavement specimens. RESULTS : The developed material shows the decreased water absorption and increased impermeable effect because of the hydrophobic characteristics. It is found that the filling depth is about 6mm and weather resistance is better than asphalt pavement specimen. CONCLUSIONS : The advanced hydrophobic - low viscosity filling treatment material is developed in this study (Part I) to improve the waterproof characteristics and high filling capacity and weather resistance for the pavement preventive maintenance.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 1998.10a
• /
• pp.1-1
• /
• 1998

Advanced (Chemical) oxidation processes (AOP) differ from most conventional ones in that hydroxyl radical(OH.) is considered to be the primary oxidant. Hydroxyl radicalcan react non-selectively with a great number of organic and inorganic chemicals. The typical rate constants of true hydroxyl radical reactions are in the range of between 109 to 1012 sec-1. Many processes are possible to generate hydroxyl radical. These include physical and chemical methods and their combinations. Physical means involves the use of high energy radiation such as gamma ray, electron beam, and acoustic wave. Under an applied high energy radiation, water molecules can be decomposed to yield hydroxyl radicals or aqueous electrons. Chemical means include the use of conventional oxidants such as hydrogen peroxide and ozone, two of the most efficient oxidants in the presence of promoter or catalyst. Hydrogen peroxide in the presence of a catalyst such as divalent iron ions can readily produce hydroxyl radicals. Ozone in the presence of specific chemical species such as OH- or hydrogen peroxide, can also generate hydroxyl radicals. Finally the combination of chemical and physical means can also yield hydroxyl radicals. Hydrogen peroxide in the presence of acoustic wave or ultra violet beam can generate hydroxyl radicals. The principles for hydroxyl radical generation will be discussed. Recent case studied of AOP for water treatment and other environmental of applications will be presented. These include the treatment of contaminated soils using electro-Fenton, lechate treatment with conventional Ponton, treatment of coal for sulfur removal using sonochemical and the treatment of groundwater with enhanced sonochemical processes.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.3
• /
• pp.143-148
• /
• 2021

Alkaline oxygen evolution reaction (OER) electrocatalysts have been widely studied for improving the efficiency and green hydrogen production through electrochemical water splitting. Transition metal-based electrocatalysts have emerged as promising materials that can significantly reduce the hydrogen production costs. Among the available electrocatalysts, transition metal-based layered double hydroxides (LDHs) have demonstrated outstanding OER performance owing to the abundant active sites and favorable adsorption-desorption energies for OER intermediates. Currently, cobalt doped nickel LDHs (NiCo LDHs) are regarded as the benchmark electrocatalyst for alkaline OER, primarily owing to the physicochemical synergetic effects between Ni and Co. We report effects of heat-treatment of the as-grown NiCo LDH on electrocatalytic activities in a temperature range from 250 to 400℃. Electrocatalytic OER properties were analysed by linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The heat-treatment temperature was found to play a crucial role in catalytic activity. The optimum heat-treatment temperature was discussed with respect to their OER performance.

• Korean Journal of Materials Research
• /
• v.26 no.5
• /
• pp.287-291
• /
• 2016

The effect of heat treatment on the microstructure and mechanical properties of cast Ti-6%Al-4%V alloy was investigated. Heat treatment of cast Ti-6Al-4V alloy was conducted by solution treatment at $950^{\circ}C$ for 30 min; this was followed by water quenching and then aging at $550^{\circ}C$ for 1 to 1440 min. The highest hardness of the heat-treated specimens was obtained by solution treatment and subsequent aging for 5 min due to precipitates of fine ${\alpha}$ that formed from retained ${\beta}$ phase. The tensile strength of this alloy increased without dramatic decrease of the ductility due to microstructural refinement resulting from the decomposition of ${\alpha}^{\prime}$ martensite into fine ${\alpha}$ and ${\beta}$ phases, and also due to the fine ${\alpha}$ phase formed from the retained ${\beta}$ phase by aging treatment for 5 min. In addition, this strengthening might be caused by the transformation induced plasticity (TRIP) effect, which is a strain-induced martensite transformation from the retained ${\beta}$ phase during deformation, and which occurs even after aging treatment at $550^{\circ}C$ for 5 min.

• Advances in environmental research
• /
• v.1 no.2
• /
• pp.125-142
• /
• 2012

Clean development mechanism (CDM) validity study was conducted to suggest better and more adaptable CDM scenario on water treatment plant (WTP). Potential four scenarios for CDM project; improvement of intake pumping efficiency, hydro power plant construction, solar panel construction and system optimization of mechanical mixing process were evaluated on S-WTP in Korea. Net present value (NPV) of each scenario was estimated based on sensitivity analysis with the variable factors to investigate the CDM validity percentile. Hydro power plant construction was the best option for CDM business with 97.76% validity and $1,127,069 mean profit by 9,813 $tonsCO_2e$/yr reduction. CDM validity on improvement of intake pumping efficiency was 90.2% with $124,305 mean profit by huge amount of $CO_2$ mitigation (10,347 $tonsCO_2e$/yr). System optimization of mechanical mixing process reduced 15% of energy consumption (3,184 $tonsCO_2e$/yr) and its CDM validity and mean profit was 77.25% and $23,942, respectively. Solar panel construction could make the effect of 14,094 $tonsCO_2$ mitigation annually and its CDM validity and mean profit was 64.68% and $228,487, respectively.