• Membrane Journal
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• v.22 no.4
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• pp.243-250
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• 2012

The effect of water back-flushing period (filtration time, FT) was investigated in hybrid process of alumina microfiltration and photocatalyst for advanced drinking water treatment in this study, and compared with the previous studies with carbon microfiltration or alumina ultrafiltration membranes. The FT was changed in the range of 2~10 min with fixed 10 sec of BT. Then, the FT effects on resistance of membrane fouling ($R_f$), permeate flux (J) and total permeate volume ($V_T$) were observed during total filtration time of 180 min. As decreasing FT, $R_f$ decreased and J increased as decreasing FT, which was same with the previous results with carbon microfiltration or alumina ultrafiltration membranes. The treatment efficiency of turbidity was high beyond 98.1%, and the effect of FT was not shown on treatment efficiency of turbidity, which was same with the previous result of carbon microfiltration. The treatment efficiency of organic matters was the highest value of 89.6 % at FT 8 min, which was a little higher than those of the previous results, and the effect of FT was not shown on treatment efficiency of organic matters.

• Membrane Journal
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• v.21 no.4
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• pp.351-359
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• 2011

For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.5
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• pp.461-467
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• 2005

Phthalate esters is recently considered as an environmental pollutant. This study investigated removal methods of phthalate esters in water environment. On tap water treatment condition with batch test, removal efficiency of coagulation precipitation of one oxidation were $26.6{\sim}33.8%$ and $10{\sim}15%$, respectively. Phthalate esters was effectively removed by the activated carbon adsorption process on tap water treatment condition. The operation of raw water with EBCT of 10 minutes on continuous process satisfied the standard of drinking water by the WHO and US EPA when the concentration of phthalate esters was $100\;{\mu}g/L$. On pilot plant test, coagulation precipitation process got $32{\sim}44%$ of removal efficiency, sand filtration process $6{\sim}10%$ and ozone oxidation process $8{\sim}10%$, respectively. DEP, DBP, BBP and DEHP were not detected after the raw water was processed with activated carbon. The actual survey of phthalate esters removal by advanced water treatment showed that $29{\sim}76%$, $3{\sim}29%$ and $17{\sim}22%$ of phthalate esters were removed on coagulation precipitation process, sand filtration and ozone oxidation process, respectively. DEP, DBP, BBP and DEHP were not detected after the raw water was processed with activated carbon.

• Membrane and Water Treatment
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• v.10 no.2
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• pp.155-163
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• 2019

The roles of polypropylene (PP) beads and pH on membrane fouling and treatment efficiency were investigated in a hybrid advanced water treatment process of tubular carbon fiber membranes (ultrafiltration (UF) or microfiltration (MF)) and PP beads. The synthetic feed including humic acid and kaolin flowed inside the membrane, and the permeated contacted the PP beads fluidized in the space between the membrane and the module with UV irradiation and periodic water back-flushing. In the hybrid process of UF ($0.05{\mu}m$) and PP beads, final resistance of membrane fouling ($R_f$) after 180 min increased as PP beads increased. The turbidity treatment efficiency was the maximum at 30 g/L; however, that of dissolved organic matters (DOM) showed the highest at PP beads 50 g/L. The $R_f$ strengthened as pH of feed increased. It means that the membrane fouling could be inhibited at low alkali condition. The treatment efficiency of turbidity was almost constant independent of pH; however, that of DOM showed the maximum at pH 5. For MF ($0.1{\mu}m$), the final $R_f$ was the minimum at PP beads 40 g/L. The treatment efficiencies of turbidity and DOM were the maximum at PP beads 10 g/L.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.1
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• pp.45-53
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• 2008

In this paper, the property of influent water and variations of removal efficiencies in each unit processes were studied based on the experiment data from the advanced water treatment plant in a city of Korea. The microbial species in the biological activated carbon(BAC) after backwashing of activated carbon filtration tank(ACFT) were also identified. The property and the removal efficiencies were evaluated by considering 8-9 items. The variations of 4 items were investigated from the influent and effluent of ACFT. SEM recording were conducted on BAC samples before and after backwashing. And the existence of attached microorganisms were identified through HPC(Heterotrophic Plate Counter) investigation. For the property of influent water, the concentrations of most items were maintained in the constant ranges, some items had seasonal properties. For the removal efficiencies, there were some items showing similar monthly-pattern and increasing with time, other items decreasing at the ozone contactor. Through these investigations, it was possible to distinguish the target items, which were removed by the advanced processes. The existence of microorganisms in ACFT could be predicted based on the variation curve of NH$_3$-N, and this fact were proved by SEM and HPC.

• Journal of Korean Society on Water Environment
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• v.33 no.1
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• pp.63-69
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• 2017

Small size privately owned wastewater treatment plants have been difficult to treat their wasted sludge and maintain steady effluent quality compared with publicly owned wastewater treatment plants. Therefore, this study has focused on treatment efficiency enhancement, specially nitrogen removal efficiency by recycling dewatering filtrate as an alkalinity additive from filter press using $CaCO_3$. As the result, it was found that the optimal mixing ratio between the excess sludge and $CaCO_3$ was 1:2. The major operation parameters such as specific substrate utilization rate, specific nitrification rate, and specific denitrification rate were also improved 64% ($0.048-0.079mg\;BOD_5/mg\;MLVSS{\cdot}day$), 35% ($0.020-0.027mg\;NH_3-N/mg\;MLVSS{\cdot}day$) and 68% ($0.051-0.086mg\;NO_3{^-}-N/mg\;MLVSS{\cdot}day$), respectively, after the adoption of new methods. Therefore, both the problem of sludge treatment at small scale plants and the need for efficiency improvement could be solved.

• Journal of the Korean Society for Heat Treatment
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• v.17 no.4
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• pp.216-222
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• 2004

Study was focused on the quenching embrittlement property of Zircaloy-4 cladding simulated Loss Of Coolant Accident (LOCA) environment in terms of high temperature oxidation and phase transformation. Property in LOCA condition of advanced cladding that contained Nb element was also investigated. Claddings were oxidized at given temperature and given time followed by water quenching. The results showed that ${\beta}$ phase which formed at quenching stage has an influence on cladding property. In case of advanced cladding, Nb retards cladding oxidation, thus enhances quenching resistance.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.6
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• pp.481-490
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• 2017

Water and wastewater treatment has always been a challenging task due to the continuous increase in amount and the change in characteristics of the poorly biodegradable and highly colored organic matters, as well as harmful micro-organisms. Advanced techniques are therefore required to successfully remove these pollutants from water before reuse or discharge to receiving water bodies. Application of ozone, which is a powerful oxidant and disinfectant, alone or as part of advanced oxidation process depends on the complex kinetic reactions and the mass transfer of ozone involved. Micro- and nano bubbling considerably improves gas dissolution compared to conventional bubbles and hence mass transfer. It can also intensify generation of hydroxyl radical due to collapse of the bubbles, which in turn facilitates oxidation reaction under both alkaline as well as acidic conditions. This review gives the overview of application of micro- and nano bubble ozonation for purification of water and wastewater. The drawbacks of previously considered techniques and the application of the hydrodynamic ozonation to synthetic aqueous solutions and various industrial wastewaters are systematically reviewed.

• Journal of Korean Society of Water and Wastewater
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• v.11 no.4
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• pp.126-132
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• 1997

Trihalomethanes (THMs) are formed during the chlorination of waters containing precusors compounds, most commonly humic substances, changes in pH, TOC, temperature, precusor source and concentration chlorine dosage, bromide level and reaction time directly influence trihalomethane formation potential (THMFP) and kinetics. A standard THMFP experiment was conducted for each water under the following conditions ; $20^{\circ}C$, pH 7.4, reaction time of 48hr, TOC 5.7mgC/L. A series of kinetic experiments was conducted for each water to provide THM formation under varying conditions of reaction time, pH, temperature and TOC, chlorine dosage. The resultant mutiple parameter powre function predicts a THM which allows direct calculation of THM, is $[THM]=0.00039(pH-2.81)[TOC][Cl_2]^{0.321}\;t^{0.266}\;T^{0.286}$ Characteristics of raw water in advanced drinking water treatment pilot plant were, TOC levels ran from 4.42~6.84mgC/L, pH 7.2~7.8, temperature $7.0{\sim}18.4^{\circ}C$, UV-254 absorbance $0.057{\sim}0.85cm^{-1}$, THM levels ranged from 0.031~0.049mgC/L.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.3
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• pp.268-276
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• 2005