• Title/Summary/Keyword: Advanced Chemistry

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The Effects of Face-to-face and Non-face-to-face Classes on the Academic Achievement of Chemistry II and Advanced Chemistry in Science High School Students (대면 및 비대면 수업 형태가 과학고 학생들의 화학II 및 고급화학의 학업성취도에 미치는 영향)

  • Dong-Seon Shin;Jong Keun Park
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.2
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    • pp.237-244
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    • 2024
  • We studied the effects on their academic achievement of chemistry II and advanced chemistry subjects of science high school students according to the type of class (face-to-face and non-face-to-face). The subjects of this study were 195 first-year students of G Science High School located in Gyeongnam. The average scores of Chemistry II and Advanced Chemistry in non-face-to-face classes in 2020 and face-to-face classes in 2021 were compared and analyzed. As a result of comparing and analyzing the academic achievement according to the class type, students' grades in Chemistry II and Advanced Chemistry were higher in non-face-to-face classes. In the comparison of academic achievement by level according to class type, Chemistry II showed higher average grades in non-face-to-face classes as the lower level were, and in advanced chemistry, the higher the upper grades in non-face-to-face classes. In addition, in terms of the effect of changes in class form on the upper and lower 10% levels of academic achievement of Chemistry II, the upper 10% showed high grades in face-to-face classes and the lower 10% in non-face-to-face classes. On the other hand, in advanced chemistry, the average grade of non-face-to-face classes was higher than that of face-to-face classes in the top 10%, and the average grade of face-to-face classes was higher than that of non-face-to-face classes in the bottom 10%. Through these results, it was found that in the teaching-learning of science high school students, instructors need to design and treat teaching-learning appropriate to the level of academic achievement.

Solid State NMR Study of PAZO-6 and Related Materials

  • Han, Oc Hee;Jin, Jung-Il;Kim, Jong-Sung;Yoon, Yong-Kook;Huh, Sung-Mu
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.493-498
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    • 1995
  • PAZO-6 is a new combined type liquid crystalline polymers (LCP) which has two types of mesogens combined non linearly. Ordering of branch mesogen azo group, in PAZO-6 is an important parameter to observe as well as the substitution effect on the backbone. The related small molecules sllch as monomers as well as the polymer itself are studied by solid state NMR techniques. Preliminary $^{13}C$ CP/MAS (cross polarization/ magic angle spinning) spectral results suggest that the azo groups in the monomers are not aligned with themselves. Azo groups in the monomers seem to be poorly ordered between well ordered p-phenylene terephthalate moeities. Similar disordering tendency of the azo group in PAZO-6 is deduced from the overall aromatic carbon peak positions which are not much different from those of the monomer.

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Implementation of magnetic Fe3O4@ZIF-8 nanocomposite to activate sodium percarbonate for highly effective degradation of organic compound in aqueous solution

  • Sajjadi, Saeed;Khataee, Alireza;Soltani, Reza Darvishi Cheshmeh;Bagheri, Nafiseh;Karimi, Afzal;Azar, Amirali Ebadi Fard
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.406-415
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    • 2018
  • Here, as-synthesized $Fe_3O_4$ nanoparticles were incorporated into the zeolitic imidazolate framework (ZIF-8) lattice to activate sodium percarbonate (SPC) for degradation of methylene blue (MB). The reaction rate constant of $Fe_3O_4@ZIF-8/SPC$ process ($0.0632min^{-1}$) at acidic conditions (pH = 3) was more than six times that of the $Fe_3O_4/SPC$ system ($0.009min^{-1}$). Decreasing the solute concentration, along with increasing SPC concentration and $Fe_3O_4@ZIF-8$ nanocomposite (NC) dosage, favored the catalytic degradation of MB. The $Fe_3O_4@ZIF-8$ NC after fifteen consecutive treatment processes showed the excellent stability with a negligible drop in the efficiency of the system (<10%). The reaction pathway was obtained via GC-MS analysis.

5' Processing of RNA I in an Escherichia coli Strain Carrying the rnpA49 Mutation

  • Jung, Young-Hwan;Park, Jung-Won;Kim, Se-Mi;Cho, Bong-Rae;Lee, Young-Hoon
    • BMB Reports
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    • v.30 no.2
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    • pp.162-165
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    • 1997
  • RNA I. a negative controller of ColE1-type plasmid replication, is metabolized by several RNases in Escherichia coli. Two small derivatives of RNA I are accumulated at nonpermissive temperatures in an E. coli strain carrying the rnpA49 mutation, a thermosensitive mutation in the rnpA gene encoding the protein component of RNase P. A primer extension analysis was carried out to compare 5' processing of RNA I in the E. coli rnpA49 cells at both permissive and nonpermissive temperatures. Derivatives of RNA I having different 5' ends were observed in the cells grown at permissive and nonpermissive temperatures. Some of the derivatives may be generated by the cleavage of RNase P.

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Pretreatment Effect on CO Oxidation over Highly Ordered Mesoporous Silver Catalyst

  • Shon, Jeong-Kuk;Park, Jung-Nam;Hwang, Seong-Hee;Jin, Mingshi;Moon, Ki-Young;Boo, Jin-Hyo;Han, Tae-Hee;Kim, Ji-Man
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.415-418
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    • 2010
  • Highly ordered mesoporous silver material was successfully synthesized from a mesoporous silica template (KIT-6) with 3-D channel structure using the nano-replication method. The effects of $H_2$ or $O_2$ pretreatments on the catalytic performance of the mesoporous silver were investigated using a temperature programmed CO oxidation technique in a fixed bed reactor. The mesoporous silver material that was pretreated with $H_2$ exhibited an excellent catalytic activity compared to the as-prepared and $O_2$-pretreated catalysts. Moreover, this present mesoporous silver material showed good catalytic stability. For the CO oxidation, the apparent activation energy of the $H_2$-pretreated mesoporous silver catalyst was $61{\pm}0.5\;kJ\;mol^{-1}$, which was also much lower than the as-prepared ($132{\pm}1.5\;kJ\;mol^{-1}$) and $O_2$-pretreated ($124{\pm}1.4\;kJ\;mol^{-1}$) catalysts.

Syntheses and light-emitting properties of new PPV derivatives containing polyhedral oligomeric silsequioxane

  • Kang, Jong-Min;Lee, Jong-Hee;Jo, Hoon-Hae;Shim, Hong-Ku;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1421-1423
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    • 2005
  • A new light-emitting poly(p-phenylenevinylene) (PPV) derivative containing a polyhedral oligomeric silsequioxane (POSS-PPV) and its MEH-PPV copolymers, [Poly(POSSPV-co-MEHPV)]s, have been synthesized through the Gilch polymerization, and their light-emitting properties were investigated. The synthesized polymers were characterized by NMR, GPC, thermogravimetric and elemental analysis. The POSS-PPV and copolymers showed almost the same optical properties as the MEH-PPV, regardless of copolymer composition. The POSS-PPV and MEHPPV all showed their peak absorption at 505 and 496nm, and PL emission maxima at 578 and 581nm. POSSPPV showed higher PL quantum efficiency than the MEH-PPV. Synthesis, characterization and electroluminescent properties of the polymers will be presented.

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