• 공업화학
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• 제33권6호
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• pp.636-645
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• 2022

이 연구에서는 은행껍질기반 활성탄으로 음이온성 염료인 메틸오렌지(MO)의 흡착 특성을 조사하였다. 이를 위해 은행껍질과 대표적인 화학활성화제인 수산화칼륨(KOH)을 이용하여 서로 다른 기공 특성을 지닌 다공성 활성탄(GS-1, GS-2, GS-4)을 제조하였다. 제조한 활성탄의 구조적 특성값과 KOH 혼합비율과의 상관관계는 질소 흡/탈착등온선으로 조사하였다. 활성탄에 대한 MO 흡착 평형 실험은 서로 다른 pH (pH 3~11) 및 온도(298~318 K) 조건에서 실시하였으며 그 결과를 Langmuir, Freundlich, Sips 및 온도 의존 Sips식으로 살펴보았다. 그리고 Langmuir 무차원 분리계수값으로 제조한 활성탄의 MO 흡착처리공정의 타당성을 조사하였다. 흡착에너지분포함수(AED)로 비교 분석한 활성탄에 대한 MO의 불균일 흡착 특성은 온도와 활성탄의 구조적 특성과 밀접한 관련이 있었다. 서로 다른 온도에서 수행한 회분식 흡착 속도 실험 결과는 외부물질전달, 입자 내 확산 및 활성사이트의 흡착을 고려한 균일표면확산모델(HSDM)로 만족스럽게 설명할 수 있었다. 또한 표면확산계수값을 Arrhenius 플롯으로 나타내어 구한 활성화에너지와 흡착에너지분포 함수값과의 상관관계를 살펴보았다. 그리고 Biot 수를 이용하여 제조한 활성탄에 대한 MO의 흡착 공정 메커니즘을 평가하였다.

• 상하수도학회지
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• 제14권1호
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• pp.54-61
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• 2000

Recently, our circumstances are threatened by an accident that leakage of under ground storage tank and illegal dumping of synthetic organic compounds at chemical plants and many treatment methods, Activated carbon adsorption, Ozonization, Membrane filtration and Photocatalystic oxidation, are developed to remove such a synthetic organic compounds. And it has reported that Activated carbon adsorption have a great removal efficiency to nondegradable matters and organic compounds which have a high molecular weight. Comparing with other adsorbents, Activated carbon adsorption have a worse efficiency when ad desorption speed is low. Thus improved type of adsorbents was invented and one of those is Activated Carbon Filter. The purpose of this study was getting information about adsorption characteristic phenol which can be applied Activated Carbon Fiber and Granular Activated Carbon. In detail, With comparing removal characteristics of phenol in the presence Humic Acid using Activated Carbon Fiber(ACF) and Granular Activated. Carbon(GAC), it is to certify an effective application of Activated Carbon Fiber. At the range of this study, Batch test, Isotherm adsorption test and Factorial analysis, following conclusion were obtained from the results of this study. Batch test was carried to know time of adsorption equilibrium. In this study about time of adsorption equilibrium by ACF was faster than GAC's, for developed micropore of ACF. From the result of phenol adsorption test, High removal rate of adsorption is shown at pH 5. The result of lsotherm adsorption test, it has represented that the Freundlich's isotherm is most suitable one in others, that a ACF's adsorption capacity is more excellent than GAC's. Adsorption of phenol exiting humic acid is decreased getting raised humic acid concentration. Since ACF's micropore is developed at this time, an effect of high molecular humic acid is lower. Factorial analysis was carried to know about Main effect which was injection dosage of adsorbent in the range of this study.

• 한국산학기술학회논문지
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• 제15권7호
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• pp.4675-4681
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• 2014

본 연구는 흡착제 Zeolite 3A와 DETOX에 대하여 $H_2S$의 유입농도와 흡착온도를 공정변수로 하여 포화시간, 흡착량, 흡착속도 등의 $H_2S$ 흡착 제거특성을 평가하기 위하여 수행되었다. $H_2S$의 유입질량유속이 증가함에 따라 Zeolite 3A의 흡착용량은 증가되었으나 포화시간은 감소되었다. 한편 DETOX의 흡착용량과 포화시간은 $H_2S$의 유입질량유속의 증가에 따라 감소되었다. 흡착온도가 상승함에 따라 Zeolite 3A의 흡착용량과 포화시간은 감소한 반면에, DETOX에 대한 이들 값은 증가하였다. DETOX의 $H_2S$흡착용량은 Zeolite 3A의 2.5~16.4배 정도 높게 나타났다. 이는 흡착에서 활성화에너지장벽을 넘어설 충돌빈도는 흡착온도가 증가함에 따라 증가한 것에 기인한 것으로 해석된다. Zeolite 3A와 DETOX에 대하여 $H_2S$의 흡착속도는 $H_2S$의 유입질량유속과 흡착온도가 증가함에 따라 증가하였다. $H_2S$의 흡착속도는 Zeolite 3A가 DETOX의 4배로 나타났다. DETOX는 Zeolite 3A에 비하여 온도 308~318K에서 포화시간은 더욱 길어지고 흡착용량은 더욱 커진다. 바이오가스 중의 $H_2S$제거에 있어서 DETOX는 Zeolite 3A에 비하여 유리한 것으로 나타났다.

• 한국환경과학회지
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• 제23권9호
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• pp.1609-1618
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• 2014

In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.

• 한국물환경학회지
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• 제28권2호
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• pp.197-201
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• 2012

The objective of this study was to evaluate the removal efficiency of arsenite and arsenate using composite adsorbents with various mixing ratio of recycled aluminum oxides and $TiO_2$. From batch adsorption experiments, while the removal of As(III) was almost same with 4 different composite samples in the entire pH range, the removal of As(V) was substantially increased as the weight ratio of $TiO_2$ in composite samples reduced and showed anionic adsorption characteristics. Both adsorption of As (III) and As(V) on composite samples followed pseudo-second-order adsorption equation and C-3 showed faster reaction rate for the removal of arsenic. From the adsorption isotherm experiments, Langmuir isotherm explained well and the maximum adsorption capacities of arsenic were obtained with C-1.

• 한국환경과학회지
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• 제26권3호
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• pp.363-371
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• 2017

This study evaluates the adsorption properties of Sr ions in an aqueous solution of the synthetic zeolite (Z-Y1) prepared using coal fly ash generated from a thermal power plant. In order to investigate the adsorption characteristics, the effects of various parameters such as the initial concentrations of Sr ion, contact time, and solution pH were investigated in a batch mode. The Langmuir and Redlich-Peterson model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacity of Sr ions, as determined the Langmuir model, was 181.68 mg/g. It was found that by varying the Sr ion concentration, pH, and temperature, the pseudo-second-order kinetic model describes the adsorption kinetics of the Sr ion better than the pseudo-first-order kinetic model. The calculated thermodynamic parameters of ${\Delta}H^0$ and ${\Delta}G^0$ showed that the adsorption of Sr ions on Z-Y1 was occurred through a spontaneous and an endothermic reaction. We found that the adsorption of Sr ions by Z-Y1 was more affected by pH than by temperature and Sr ion concentration.

• 상하수도학회지
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• 제25권3호
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• pp.359-366
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• 2011

The feasibility of using volcanic ash for lead ion removal from wastewater was evaluated. The adsorption experiments were carried out in batch tests using volcanic ash that was treated with either NaOH or HCl prior to the use. Volcanic ash dose, temperature and initial Pb(II) concentration were chosen as 3 operational variables for a $2^3$ factorial design. Ash dose and concentration were found to be significant factors affecting Pb(II) adsorption. The removal of Pb(II) was enhanced with increasing volcanic ash dose and with decreasing the initial Pb(II) concentration. Pb(II) adsorption on the volcanic ash surface was spontaneous reaction and favored at high temperatures. Calculation of Gibb's free energy indicated that the adsorption was endothermic reaction. The equilibrium parameters were determined by fitting the Langmuir and Freundlich isotherms, and Langmuir model better fitted to the data than Freundlich model. BTV(base-treated volcanic ash) showed the maximum adsorption capacity($Q_{max}$) of 47.39mg/g. A pseudo second-order kinetic model was fitted to the data and the calculated $q_e$ values from the kinetic model were found close to the values obtained from the equilibrium experiments. The results of this study provided useful information about the adsorption characteristics of volcanic ash for Pb(II) removal from aqueous solution.

• 한국환경과학회지
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• 제27권3호
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• pp.167-177
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• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.

• 한국환경과학회지
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• 제11권3호
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• pp.227-234
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• 2002

Laboratory experiments were conducted to examine the behavior of metalaxyl in environment which was used as pesticide in green soil of golf course and as functions of the characteristics of adsorption, desorption and degradation in soil texture and organic matter contents. Acid water containing metalaxyl was conducted to evaluate the effects on adsorption, desorption and degradation. The adsorption of metalaxyl played more significant role in organic contents than clay contents, and pH Increases more pH 2.5 than pH 5.6. The desorption of metalaxyl from contaminants soil decreased higher organic contents LS-soil than S-soil, but the desorption amount of metalaxyl increased more pH 5.6 than pH 2.5. The rate of degradation of metalaxyl in green soil environmental increased higher organic contents LS-soil than S-soil and decreased more pH 2.5 than pH 5.6. These results indicated that the behavior of metalaxyl of the green soil was affected the soil texture of the golf course. Increasing of organic contents, the adsorption amount of metalaxyl on soil increased. Moreover the decrease of the pH of solution increased adsorption amounts and decreased desorption amounts. As the results, the transportation of metalaxyl in soil decreased the acidic rates. The acidification of soil by the acid rain increased the adsorption amount of metalaxyl, but the degradation of metalaxyl decreased. Therefore, it is possible to sustain contamination in run-off the stream and ground water by residuals in soil.

• 상하수도학회지
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• 제34권1호
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• pp.1-8
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• 2020

In this study, the physicochemical characteristics and fluoride adsorption capacity of the bone char pyrolyzed at different temperatures; 200℃, 300℃, 350℃, 400℃, 500℃, 600℃, and 700℃ were investigated. Analytical studies of the synthesized bone char including; SEM-EDS, XRD, BET and FT-IR, showed the presence of hydroxyapatite(HAP), which is the main substance that adsorbs fluoride from aqueous solutions containing high fluoride concentrations. Bone char pyrolyzed from 350~700℃ specifically revealed that, the lower the temperature, the higher the fluoride adsorption capacity and vice versa. The loss of the fluoride adsorption function of HAP (OH^- band in the FTIR analysis) was interpreted as the main reason behind this inverse correlation between temperature and fluoride adsorption. Bone char produced at 350℃ hence exhibited a fluoride adsorption capacity of 10.56 mgF/g, resulting in significantly higher adsorption compared to previous studies.