• 동력기계공학회지
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• 제2권3호
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• pp.41-48
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• 1998

This study was aimed at development of fabrication process of functionally graded materials(FGM), consisting of metal and ceramic by thermal spraying method. NiCrAIY/$Al_2O_3$ FGM were made by using plasma spraying onto the SS400 carbon steel substrate. And mechanical properties such as microhardness, thermal shock resistance and adhesive strength of the coating layer were investigated. Adhesive strength was evaluated by acoustic emission method. It was resulted that NiCrAIY/$Al_2O_3$ FGM made by thermal spraying method showed excellent thermal shock resistance and adhesive strength compared to the other lamellar structures of sprayed coatings and that AE is useful tool to evaluate the defect of thermal sprayed coating layer.

• 한국염색가공학회지
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• 제30권2호
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• pp.90-97
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• 2018

Hydrophilic reactive hot-melt polyurethane adhesive(HRHA) using a hydrophilic polyol having different molecular weight and NCO index was synthesized. This HRHA was synthesized using Polyethylene glycol(PEG) as a hydrophilic polyol, Polypropylene glycol(PPG) and Polycaprolactone diol(PCL) as hydrophobic polyols, and Methylene diphenyl diisocyanate(MDI) as an isocyanate. The changes in IR spectrum, viscosity and thermal properties of HRHA with different PEG molecular weights and NCO index were investigated, and the tensile strength and elongation of the HRHA casting film and the peel strength, moisture permeability and water pressure of the HRHA coated fabric were confirmed. In this experiment, as the molecular weight of PEG and NCO index increased, the adhesive strength, tensile strength, elongation and moisture permeability was increased but viscosity and Tg was decreased.

• Human Ecology Research
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• 제59권1호
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• pp.13-21
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• 2021

In order to examine the changes in the appearance properties and the post-adhesion appearance properties of Hanji yarn blended fabrics : 100% Hanji yarn fabric, two kinds of cotton / Hanji yarn blended fabrics and 100% cotton fabric, were selected and fused with three kinds of interlinings. After fusing, changes of standardized KES values were examined. 1. W/T, B/W of Hanji yarn blended fabrics was higher than that cotton fabric. WC/W, 2HB/W, 2HB/B, and 2HG/G values of Hanji yarn blended fabrics are lower than cotton fabric. This means that the Hanji yarn was mixed, shape retention, wrinkle recovery was improved, and the drape property was lowered. 2. After fusing, W/T, shape retention, wrinkle recovery of Hanji yarn blended fabrics increased, and WC/W values of Hanji yarn blended fabrics decreased. The wrinkle recovery property of Hanji yarn blended fabrics were improved; however, the 2HG/G value of Hanji yarn fabric increased due to fusing, and the wrinkle recovery property of Hanji yarn fabric decreased. 3. In the selection of adhesive core, I1 adhesive core is excellent in terms of shape stability and wrinkle recovery; however, an I3 adhesive core is recommended for drape and silhouette formation. When the fabric of the adhesive core was PET, it was found to penetrate better between the fabrics during adhesion than the case of cotton fabrics.

• Structural Engineering and Mechanics
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• 제91권2호
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• pp.135-147
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• 2024

The objective of this study is to analyze, using the finite element method, the durability of damaged and repaired structures under the effect of mechanical loading coupled with environmental conditions (water absorption and/or temperature). The study is based on the hybrid patch repair technique, considering several parameters based on the J integral to observe the behavior of the adhesive in transferring load from a damaged plate to the repair patch. The results clearly show that water absorption and increased temperature cause degradation of the mechanical properties of the adhesive, leading to an increase in its plasticization, which is beneficial for the assembly's strength. However, the degradation of the adhesive's properties due to aging in the repair results in poor load transfer from the damaged area to the patch. The findings of this study allowed the authors to conclude that the [0°]8 sequence consistently offers the best performance, with the lowest J integral values and superior crack resistance. The lowest the J integral for the [0°]8 stacking sequence is typically 3-7% lower than that of the [0/-45/45/90]S and [0/-45/90/45]S sequences at elevated temperatures. At 60℃, the J integral increases by approximately 3-6% compared to 40℃ and 20, depending on the aging duration and stacking sequences.

• Journal of the Korean Wood Science and Technology
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• 제48권3호
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• pp.303-314
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• 2020

Gambir is a non-wood forest product with a potential of being used as wood adhesive, due to about 33% catechin in it. Meanwhile, catechins and sucrose have not been studied as adhesives. Therefore, basic characteristics of gambir-sucrose adhesives were investigated. In this research, adhesives were prepared by dissolving gambir and sucrose in distilled water, at different blending ratios of the gambir/sucrose such as 100/0, 75/25, 50/50, and 25/75 wt%. Furthermore, gas chromatography-mass spectrometry (GC-MS) was employed to determine the gambir chemical compositions, and Fourier transform-infrared (FTIR) spectroscopy was carried out to identify chemical bonds. Particleboards with a target density of 0.8 g/㎤ were then manufactured by hot-pressing for 10 min at 200℃. The internal bond (IB) strength of particleboard was subsequently measured. Based on the GC-MS analysis, 31.11% of catechin was identified. In addition, the viscosity, density, solid content, and gelation time of the adhesives, and insoluble matter content (IMC) in boiling water were 7.30~33.24 mPa.s, 1.2~1.3 g/㎤, 25.56~28.44%, 73~420 min, and 29.75~62.10%, respectively. Adding sucrose to the adhesive was observed to raise the IMC from 49.05 to 62.10%, at 180℃ and 200℃. FT-IR analysis showed that the gambir absorption peaks occurred at approximately 1620 cm^-1, assigned to the C=O stretching of 5-hydroxymethylfurfural, which tended to increase with the addition of sucrose. The reaction between gambir and sucrose was observed in the form of the dimethylene ether bridge. The 25/75 wt% gambir-sucrose adhesives and 200℃ hot-pressed temperature resulted in the highest IB strength (0.89 MPa), and met the requirement of JIS A5908-2003 type 18. Consequently, the gambir-sucrose adhesive could be used as a particleboard adhesive.

• Composites Research
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• 제30권6호
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• pp.416-421
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• 2017

CFRP와 금속간의 접합공정이 개선된 구조용 접착제가 제조되었다. 구조용 접착제에 대한 경화시간, 기지재료의 표면상태 그리고 접착제의 양에 따른 최적의 접합공정 조건을 랩쉐어 실험을 통하여 파악하였다. 적합한 접합조건을 확인하기 위해 이종재료간의 접합 파단면 상태를 반사현미경을 이용하여 평가하였다. 이종재료간 접합력 향상을 위해 접착제의 개선뿐만 아니라 CFRP의 표면처리 또한 중요하였다. 구조용 접착제의 경우 180도 조건에 20분의 경화온도 조건이 최적이였으며, CFRP의 표면 처리에 따라 접합특성이 향상됨을 확인하였다. 이종재료 간 접합을 위해 구조용 접착제의 양은 $1.5{\times}10^{-3}g/mm^2$ 조건일 때 최적이었다. 접합공정의 개선 및 최적화를 통해 기존의 접착력 대비 10% 이상의 물성 강화를 나타냄을 확인하였다.

• 접착 및 계면
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• 제17권3호
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• pp.89-95
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• 2016

유연한 식품포장필름에 사용되고 있는 드라이 라미네이션용 유성접착제를 대체하기 위해, 고분자 분산제를 사용하여 유화하는 방법으로 수성 감압점착제를 친환경적으로 설계하였다. 유화중합에서 널리 사용하는 저분자량의 계면활성제는 물성의 변수로 작용해 왔다. 본 연구에서는 먼저 용액중합으로 polymeric nano-dispersant (PND)를 제조하고, 이 PND 입자들의 분산제를 micelle seed로 이용하여 core-shell grafted acrylic 점착제를 합성하였다. 이때 입자의 바깥층(shell)과 입자내층(core)의 $T_g$를 달리하여 얇은 필름의 점착조건인 초기접착력과 유지력의 균형을 이루도록 설계하였다. 최적화된 시험군 합성 점착제의 물성을 국내외 제조사에서 개발된 연구시료들과 비교분석하여, 점착제로서의 물성을 검토하였다. 물성 비교 결과, 본 연구에서 설계 합성한 저분자량의 계면활성제를 대체 사용한 고분자 나노분산제 기반 core-shell 점착제가 연포장에 적합한 점착물성을 나타냄을 확인하였다.

• Journal of the Korean Wood Science and Technology
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• 제31권2호
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• pp.84-91
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• 2003

본 연구에서는 3 수종(이태리 포플러, 소나무, 굴참나무재)을 공차별(0, 0.15, 0.3, 0.45 mm)로 초산비닐 수지와 레소시놀-페놀 공축합 수지를 이용하여 접합 제작하였다. 휨시험에서 핑거공차에 따라서 검출되는 AE와 휨강도성능 특성을 살펴본 결과는 다음과 같았다. 레소시놀재의 AE파 발생시기가 초산재보다 빨랐으며, 레소시놀재의 AE파 사상총수는 하중의 증가와 함께 계속적으로 증가하였으며 총발생 사상총수도 초산재보다 휠씬 많이 나타났다. 또한, 레소시놀재의 AE파 사상총수는 낮은 하중에서도 많은 개수가 발생하였다. 비례한도 내에서도 레소시놀 접착제를 사용한 경우에는 많은 AE파가 검출되었다. 따라서 레소시놀 접착제로 접착한 핑거 접합재의 휨시험으로부터 얻은 AE 신호는 핑거공차에 따른 접합재의 강도 예측이나 보증에 이용 가능할 것으로 판단되었다.

• Restorative Dentistry and Endodontics
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• 제49권2호
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• pp.18.1-18.13
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• 2024

Objectives: This study was conducted to evaluate the mechanical properties of relined and non-relined fiberglass posts when cemented to root canal dentin using a conventional dual-cure resin cement or a self-adhesive resin cement. Materials and Methods: Two types of resin cements were utilized: conventional and self-adhesive. Additionally, 2 cementation protocols were employed, involving relined and non-relined fiberglass posts. In total, 72 bovine incisors were cemented and subjected to push-out bond strength testing (n = 10) followed by failure mode analysis. The cross-sectional microhardness (n = 5) was assessed along the root canal, and interface analyses (n = 3) were conducted using scanning electron microscopy (SEM). Data from the push-out bond strength and cross-sectional microhardness tests were analyzed via 3-way analysis of variance and the Bonferroni post-hoc test (α= 0.05). Results: For non-relined fiberglass posts, conventional resin cement exhibited higher pushout bond strength than self-adhesive cement. Relined fiberglass posts yielded comparable results between the resin cements. Type II failure was the most common failure mode for both resin cements, regardless of cementation protocol. The use of relined fiberglass posts improved the cross-sectional microhardness values for both cements. SEM images revealed voids and bubbles in the incisors with non-relined fiberglass posts. Conclusions: Mechanical properties were impacted by the cementation protocol. Relined fiberglass posts presented the highest push-out bond strength and cross-sectional microhardness values, regardless of the resin cement used (conventional dual-cure or self-adhesive). Conversely, for non-relined fiberglass posts, the conventional dual-cure resin cement yielded superior results to the self-adhesive resin cement.

• 공업화학
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• 제7권1호
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• pp.194-202
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• 1996

기존의 ethylene-vinyl acetate 핫멜트 접착제는 시간에 따른 크리프 특성과 내열성 등의 한계로 사용에 제한이 있으므로 물성의 향상을 위해 폴리아미드계 수지를 이용한 새로운 핫멜트 접착제 개발에 관하여 연구하였다. 폴리아미드 단일중합체의 경우 융점과 용융점도가 매우 높기 때문에 대신 나일론6, 나일론66, 나일론12로 이루어진 삼원공중합체 혹은 블렌딩 수지를 사용하므로써 분자쇄의 규칙성 파괴로 인해 용융점도와 용융점을 강하시킬 수 있었다. 이로써 선택된 수지가 핫멜트 접착제의 베이스 수지로 적절함을 알 수 있었다. 또한 베이스 수지에 테르펜 수지, butyl benzyl phthalate, 파라핀왁스 등을 첨가하여 접착제를 구성함에 따라 유변학적 거동도 쉽게 조절될 수 있었다. 용융점도와 접착제 자체의 인장물성 결과에 따르면 사용된 CM831과 843형 폴리아미드 수지를 약 75/25~50/50의 무게비로 블렌딩함이 최적의 접착력을 나타내리라 평가되었다. 또한 steel간의 접착력 평가 결과 steel 표면의 거칠음 정도가 접착력에 직접 영향을 미치는 결과를 얻었다.