• Title/Summary/Keyword: Adhesion and Removal

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Microbe Adhesion and Organic Removal from Synthetic Wastewater Treatment using Polypropylene Media Modified by Ion-Assisted Reactions (이온 보조 반응에 의하여 활성화된 폴리프로필렌 담체를 이용만 합성폐수 처리시 미생물 부착 및 유기물의 제거)

  • Seon, Yong-Ho;Han, Sung;Koh, Seok-Keun
    • KSBB Journal
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    • v.17 no.3
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    • pp.235-240
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    • 2002
  • The surface of polypropylene was modified by 1 keV $Ar^+$ ion beam in an $O_2$ environment in order to enhance wettability. Contact angle of deionized water on modified polypropylene was reduced from $78^{\circ}$to $22^{\circ}$. The enhanced wettability is originated from newly formed functional groups such as ether, carbonyl, and carbonyl groups. During immersion in deionized water, the enhanced wettability has remained nearly same. After washing in water, the hydrophilic functional groups on the polymer surface have been very stable. The modified polypropylene was adopted as bio-film media to remove organics in synthetic wastewater. Microbe adhesion on the polypropylene surface was improved due to the newly formed hydrophilic groups.

THE EFFECT OF REMOVAL OF RESIDUAL PEROXIDE ON THE SHEAR BOND STRENGTH AND THE FRACTURE MODE OF COMPOSITE RESIN-ENAMEL AFTER TOOTH BLEACHING (생활치 표백술 후 수종의 자유 산소기 제거제 처리가 복합 레진-법랑질 전단 접착 강도 및 파절 양상에 미치는 영향)

  • 임경란;금기연;김애리;장수미
    • Restorative Dentistry and Endodontics
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    • v.26 no.5
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    • pp.399-408
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    • 2001
  • Tooth bleaching has been prevailing recently for its ability to recover the color and shape of natural teeth without reduction of tooth material. However, it has been reported that bleaching procedure adversely affects the adhesive bond strength of composite resin to tooth. At the same time the bond strength was reported to be regained by application of some chemical agents. The purpose of this in vitro study was to investigate the effect of the removal of residual peroxide on the composite- enamel adhesion and also evaluated fracture mode between resin and enamel after bleaching. Sixty extracted human anterior and premolars teeth were divided into 5 groups and bleached by combined technique using of office bleaching with 35 % hydrogen peroxide and matrix bleaching with 10% carbamide peroxide for 4 weeks. After bleaching, the labial surfaces of each tooth were treated with catalase, 70% ethyl alcohol, distilled water and filled with composite resin. Shear bond strength was tested and the fractured surfaces were also examined with SEM. Analysis revealed significantly higher bond strength values. (p<0.05) for catalase-treated specimens, but water-treated specimens showed reduction of bond strength, alcohol- treated specimens had medium value between the two groups(p<0.05). The fracture mode was shown that the catalase group and the alcohol group had cohesive failure but the water sprayed group had adhesive failure. It was concluded that the peroxide residues in tooth after bleaching seems to be removed by gradual diffusion and the free radical oxygen from peroxide prevents polymerization by combining catalyst in the resin monomer. Therefore it may be possible to eliminate the adverse effect on the adhesion of composite resin to enamel after bleaching by using water displacement solution or dentin bonding agent including it for effective removal of residual peroxide.

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A dynamic analysis on minute particles' detachment mechanism in a cryogenic $CO_2$ cleaning process (극저온 $CO_2$ 세정과정 시 미세오염물의 탈착 메커니즘 연구)

  • Seok, Jong-Won;Lee, Seong-Hoon;Kim, Pil-Kee;Lee, Ju-Hong
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.4
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    • pp.29-33
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    • 2008
  • Rapid increase of integrity for recent semiconductor industry highly demands the development of removal technology of contaminated particles in the scale of a few microns or even smaller. It is known that the surface cleaning technology using $CO_2$ snow has its own merits of high efficiency. However, the detailed removal mechanism of particles using this technology is not yet fully understood due to the lack of sophisticated research endeavors. The detachment mechanism of particles from the substrates is known to be belonged in four types; rebounding, sliding, rolling and lifting. In this study, a modeling effort is performed to explain the detachment mechanism of a contaminant particle due to the rebounding caused by the vertical collision of the $CO_2$ snow. The Hertz and Johnson-Kendall-Roberts(JKR) theories are employed to describe the contact, adhesion and deformation mechanisms of the particles on a substrate. Numerical simulations are followed for several representative cases, which provide the perspective views on the dynamic characteristics of the particles as functions of the material properties and the initial inter-particle collision velocity.

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Arthroscopic Treatment of Post-traumatic Stiff Shoulder by Rotator Interval Bridging Scar Adhesion - Case Report - (회전근 개 간격의 가교 반흔 유착에 의한 외상성 견관절 강직증의 관절경적 치료 - 증례 보고 -)

  • Kim Young-Mo;Rhee Kwang-Jin;Kim Kyung-Cheon;Byun Byung-Nam
    • Clinics in Shoulder and Elbow
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    • v.7 no.1
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    • pp.41-45
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    • 2004
  • In adhesive capsulitis of the shoulder of no response to nonoperative treatment, an arthroscopic capsular release and manipulation improves range of motion and pain relief. We performed an arthroscopic examination in the stiff shoulder, of which she had no response to nonoperative treatment, after the conservative treatment of a clavicular shaft fracture by motorcycle-driver traffic accident. We found the intra-articular 'rotator interval bridging scar adhesion' between subscapularis tendon and antero-superior glenoid fossa under the rotator interval which was no adhesion and contracture itself. We performed the scar adhesion removal and synovectomy, maintaining the rotator interval. We recommended nonsteroidal anti-inflammatory drug for postoperative pain relief and continuous active and passive range of motion (ROM) exercise to gain motions. Preoperatively, active and passive range of motion were 70° for forward elevation, 60° for abduction and especially 0° for external rotation. After postoperative 2 months, active ROM were 150° for forward elevation, 130° for abduction and 80° for external rotation. After postoperative 6 months, passive and active ROM were full. UCLA score improved from preoperative 9 points to postoperative 29 points.

Clinical Results of Anti-adhesion Adjuvants after Endonasal Dacryocystorhinostomy

  • Shin, Hye-Young;Paik, Ji-Sun;Yang, Suk-Woo
    • Korean Journal of Ophthalmology
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    • v.32 no.6
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    • pp.433-437
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    • 2018
  • Purpose: Various absorbable anti-adhesion agents have been used to prevent postoperative synechia formation after endonasal surgery. The purpose of this study was to evaluate the anti-adhesion effects of HyFence and Mediclore after endonasal dacryocystorhinostomy (DCR) compared to a mixed solution of hyaluronic acid and sodium carboxymethylcellulose (Guardix-Sol). Methods: In this retrospective study, endonasal DCR and silicone tube intubation were performed on 198 eyes of 151 patients. Three different anti-adhesion adjuvants were applied to the osteotomy site in the nasal cavity after standard endonasal DCR procedures. The subjects were classified into three respective groups: group A (71 eyes, Guardix-Sol 1.5 g), group B (89 eyes, HyFence 1.5 mL), and group C (38 eyes, Mediclore 1 cc). The three groups were evaluated by asking patients about subjective symptoms and by performing lacrimal irrigation tests and endoscopic examinations. Results: There were no statistically significant differences in age, sex, timing of tube removal, or follow-up period among the three groups. There were no statistically significant differences in success rates among the three groups (p = 0.990, 91.5% [65 / 71], 92.1% [82 / 89], and 92.1% [35 / 38], respectively). Conclusions: HyFence and Mediclore are safe and effective adjunctive modalities following endonasal DCR compared to Guardix-Sol. Therefore, these agents can be considered good alternatives to Guardix-Sol to increase the success rate of endonasal DCR in treating patients with poor prognosis.

Improvement of Interfacial Adhesion for Surface treated Rice Husk Flour-Filled Polypropylene Bio-Composites (표면처리에 의한 왕겨분말-폴리프로필렌 바이오복합재의 계면 접착력 향상)

  • Lee, Byoung-Ho;Kim, Hee-Soo;Choi, Seung-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.38-45
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    • 2006
  • The main objective of this study is the improvement of the interfacial adhesion of RHF-polypropylene (PP) bio-composites through NaOH and acetic acid treated RHF. After manufacturing of untreated and NaOH and acetic acid treated RHF filled PP bio-composites, the effect on interfacial adhesion of bio-composites was investigated. Tensile strength of the bio-composites made from treated RHF with NaOH and acetic acid was higher than that of the untreated bio-composites. The RHF surface before and after NaOH and acetic acid treatment was clearly confirmed by scanning electron microscopy (SEM) micrograph. It was found that both treatments result in a removal of impurity materials of RHF surface by SEM micrographs. The chemical structures of untreated and NaOH and acetic acid treated RHF were confirmed by fourier transform infrared (FTIR). The crystallization structure and crystallinity of non-treated, NaOH and acetic acid treated RHF were investigated by wide-angle X-ray scattering (WAXS).

Study on Anti-biofouling Properties of the Surfaces Treated with Perfluoropolyether (PFPE) (Perfluoropolyether (PFPE)로 처리된 표면의 생물오손 방지 특성 연구)

  • Park, Sooin;Kwon, Sunil;Lee, Yeongmin;Koh, Won-Gun;Ha, Jong Wook;Lee, Sang-Yup
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.71-76
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    • 2012
  • Biofouling by marine organisms such as algae and barnacles causes lots of significant problems in marine systems such as a rise of the maintenance-repair cost for the ship and the marine structures. In this work, a fluoropolymer, perfluoropolyether (PFPE), was applied as an anti-biofouling coating material that prevents the adhesion of marine organisms and facilitates the removal of them. Water contact angles of various surfaces were tested to examine the hydrophobicity of the PFPE-modified surface. The PFPE-modified surface showed the water contact angle of $64.5^{\circ}$ which is a remarkable rise from $46.7^{\circ}$ of amine-treated surface. When the substrate was treated with PFPE, the adhesion on the of the barnacle and other marine organisms were repressed around 15% by the enhanced hydrophobicity. In addition, the removal the of the adhered marine organisms were better comparing to that of the surface prepared by PDMS. Surfaces of the substrate treated by PFPE were characterized through physical and chemical methods to analyze the biofouling results. Degree of biomolecular adhesion to the substrate was quantified by the measurement the fluorescence intensity of marine organisms dyed with green fluorescence. PFPE is expected to be applicable not only to anti-biofouling systems but also to medical devices where the prevention of protein adhesion is required.

ONP 탈묵공정의 계면활성제와 지방산 비교

  • Ryu, Jeong-Yong;Song, Bong-Geun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2010.04a
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    • pp.7-7
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    • 2010
  • Flotation deinking is a common practice for removing ink from recovered paper, and it is becoming a key process in many recycling paper mills. Flotation deinking was successfully introduced to the paper recycling industry in the 1980s, and its applications in wax removal, stickies control, and fiber fractionation have attracted great research interest. A successful flotation process has three major efficient subprocesses: the detachment of the ink particles from the fibers, the effective adhesion of the ink particles onto air bubble surfaces, and the removal of froth and ink particles from flotation cells. Surfactants can affect these subprocesses either positively or negatively. To understand how a surfactant can positively and negatively affect the flotation deinking process, the basic chemistry of surfactant in solution should be discussed.

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Study on Cake Resistance and Microfiltraion Performance of Rotating Membrane Filters (회전막 정밀여과기에서 케이크 저항과 여과성능에 대한 연구)

  • 박원철;최창균;김재진;박진용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.105-109
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    • 1998
  • 1. Introduction : In microfiltration the transport, deposition and removal of particles control cake formation on a filter. In this connection a new model on cake formation, based on the wall shear stress, was tested here in comparison with experiments of fine particle slurry under Taylor-vortex flow. The model expresses the deposition process for particles as two first-order steps in series of mass transfer and adhesion, and their removal process as a linear relation to the wall shear stress. This embraces characteristics of both dead-end and crossflow filtration. The correlation resulting from fitting to experimental data represented the experimental data reasonably well. This study will be helpful in analyzing fouling in heat exchangers.

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The Study on Wafer Cleaning Using Excimer Laser (엑사이머 레이저를 이용한 웨이퍼 크리닝에 관한 고찰)

  • 윤경구;김재구;이성국;최두선;신보성;황경현;정재경
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.743-746
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    • 2000
  • The removal of contaminants of silicon wafers has been investigated by various methods. Laser cleaning is the new dry cleaning technique to replace wafer wet cleaning in the near future. A dry laser cleaning uses inert gas jet to remove contaminant particles lifted off by the action of a KrF excimer laser. A laser cleaning model is developed to simulate the cleaning process and analyze the influence of contaminant particles and experimental parameters on laser cleaning efficiency. The model demonstrates that various types of submicrometer-sized particles from the front sides of silicon wafer can be efficiently removed by laser cleaning. The laser cleaning is explained by a particle adhesion model. including van der Waals forces and hydrogen bonding, and a particle removal model involving rapid thermal expansion of the substrate due to the thermoelastic effect. In addition, the experiment of wafer laser cleaning using KrF excimer laser was conducted to remove various contaminant particles.

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