• Journal of Life Science
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• v.29 no.1
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• pp.90-96
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• 2019

The objective of this study was to evaluate the potential of Diospyros malabarica stem extract, a natural materials, in oral health material. With this aim in mind, thin layer chromatography (TLC), TLC-bioautography, high-performance liquid chromatography (HPLC), electrospray ionization-mass spectrometry (ESI-MS), scanning electron microscopy (SEM), and real-time qPCR were performed. The antibacterial activity of D. malabarica stem extract against Streptococcus mutans KCTC3065 was confirmed in an n-hexane fraction with low polarity. The molecular weight of the antibacterial compound was estimated to be 188 by ESI-MS analysis. The inhibitory effects of the extract on biofilm formation and gene expression related to biofilm formation of S. mutans were determined by SEM and real-time PCR analysis. The extract inhibited the formation of S. mutans biofilms at D. malabarica stem extract concentrations of 1 mg/ml, as shown by SEM. The real-time PCR analysis showed that the expression of the gtfC gene, which is associated with biofilm formation, was significantly decreased in a dose-dependent manner. Based on the above results, it can be concluded that D. malabarica stem extracts, a natural materials, can be used in oral health products to suppress the formation of biofilms by inhibiting tooth adhesion of S. mutans, a causative agent of dental caries.

• The Journal of Korean Academy of Prosthodontics
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• v.59 no.3
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• pp.319-332
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• 2021

With the rapid development of aesthetic ceramic materials and resin adhesives, the transition from metal ceramic crown to all-ceramic restoration is being actively carried out. When making porcelain restorations, the advantages can be maximized only when appropriate forms and techniques are used. Recently, an esthetic partial-coverage restoration method with supra-gingival margins was introduced by applying a minimally invasive tooth removal method that preserves enamel as much as possible and enhances adhesion efficiency. Through this, various advantages such as minimization of tooth structure removal and ease of excess cement removal can be obtained. In addition, since this manufacturing method does not require cord packing, it is possible to save time for impression taking and reduce patient discomfort. Furthermore, the margins can be clearly obtained without the intervention of gingival fluid or blood, making it possible to manufacture more accurate restorations. In the following cases of patients with partial tooth defects, esthetic ceramic partial-coverage restorations with supra-gingival margin was applied using minimally invasive tooth preparation method according to the concept of adhesive dentistry. Therefore, unnecessary tooth abutment preparation was prevented and residual tooth structure could be preserved as much as possible. After delivery of the ceramic partial-coverage restorations, favorable outcome was obtained.

• Composites Research
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• v.33 no.6
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• pp.360-364
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• 2020

Although research and development of existing steel-made Cowl Cross Member(CCM) was carried out with magnesium and plastic to make vehicles lighter, it is difficult to apply them to performance problems in the vehicle's mounting condition. Recently, the company is conducting research on the injection CCM of the composite insert as a lightweight component that is most suitable for mass-production of automotive parts. This is a manufacturing process that inserts composite injection bracket parts into aluminum bar, and the adhesion of the two parts is one of the important factors considering the vehicle's mounting conditions. In this study, the joint strength of Aluminum bar is one of the important factors as a study for the injection of aluminum bar into PA6-GF60 composite material. For the analysis of these research, the method of spraying adhesive to the aluminum bar and the case of knurling treatment have been analyzed and the bonding strength of the direction of rotation and lateral direction has been analyzed for each part between the aluminum bar of the cowl cross member and the shape of the injection component of composite materials.

• Journal of Surface Science and Engineering
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• v.55 no.6
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• pp.390-397
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• 2022

Parylene-C which was mainly used for industries such as electronics, machinery and semiconductors has recently been in the spotlight in the medical field due to its properties such as corrosion resistance and biocompatibility. In this study we intend to derive a plan to improve the bonding strength of Parylene-C coating with the SUS304 base material for medical use which can be applied to various medical fields such as needles, micro needles and in vitro diagnostic device sensors. Through plasma pretreatment the bonding strength between Parylene-C and metal materials was improved. It was confirmed that the coated surface was hydrophobic by measuring the contact angle and the improvement of the surface roughness of the sample manufactured through CNC machining was confirmed by measuring the surface roughness with SEM. Through the above results, it is thought that it will be effective in increasing usability and reducing pain in patients by minimizing friction when inserting medical devices and in contact with skin. In addition it can be applied to various application fields such as human implantable stents and catheters, and is expected to improve the performance and lifespan of medical parts.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.4
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• pp.73-80
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• 2022

This study evaluated changes in fluidity and rheological properties over time for 3D printed composite materials, and evaluated compressive strength and splitting tensile strength properties for laminated and molded specimens. The composite material for 3D printing starts to change rapidly after 30 minutes of extrusion, and the viscosity of the material tends to be maintained up to 90 minutes, but it was confirmed that construction within 60 minutes after mixing is effective. The compressive strength of the laminated test specimen showed equivalent or better performance at all ages compared to the molded test specimen. In the stress-strain curve of the laminated specimen, the initial slope was similar to that of the molded specimen, but the descending slope was on average 1.9 times higher than that of the molded specimen, indicating relatively brittle behavior. The splitting tensile strength of the P-V laminated specimen was about 6% lower than that of the molded specimen. It is judged that this is because the interfacial adhesion force against the vertical load is affected by the pattern direction of the laminated test specimen.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.3
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• pp.244-250
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• 2023

In this paper, mortar mixed with tapioca starch was manufactured to evaluate the effect of tapioca starch on mortar, through evaluating the quality characteristics of mortar, the impact of tapioca starch on improving the performance and basic quality of mortar was examined. Tapioca starch tended to decrease flow by increasing the viscosity of the dough consistency of fresh mortar, which tended to reduce flow, and decreased by about 10 % as the tapioca starch mixing ratio increased by 0.025 %. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mix ing tapioca starch. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mixing tapioca starch. The speed of strength development improved by about 20 % when mixing 0.050 % tapioca starch. The adhesion strength improved by about 60 % when mixing 0.050 % tapioca starch, and the final shrinkage in length change decreased by 5 %.

• Composites Research
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• v.36 no.6
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• pp.441-447
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• 2023

Recently, as demand for high-strength, lightweight materials has increased, there has been great interest in joining with metals. In the case of mechanical bonding, such as bolting and riveting, chemical bonding using adhesives is attracting attention as stress concentration, cracks, and peeling occur. In this paper, surface treatment was performed to improve the adhesive strength, and the change in adhesive strength was analyzed. For the adhesive strength test were conducted with Carbon Fiber Reinforced Plastic(CFRP), CR340(Steel), and Al6061(Aluminum), and laser and plasma surface treatment were used. After plasma surface treatment, the adhesive strength improved by 7.3% and 39.2% in CFRP-CR340 and CFRP-Al6061, respectively. CR340-Al6061 was improved by 56.2% in laser surface treatment. Surface free energy(SFE) was measured by contact angle after plasma treatment, and it is thought that the adhesion strength was improved by minimizing damage through a chemical reaction mechanism. For laser surface treatment, it is thought that creates a rough bonding surface and improves adhesive strength due to the mechanical interlocking effect. Therefore, surface treatment is effect to improve adhesive strength, and based on this paper, the long-term fatigue test will be conducted to prevent fatigue failure, which is a representative cause of actual structural damage.

• Journal of Surface Science and Engineering
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• v.56 no.6
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• pp.412-419
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• 2023

Anion exchange membrane electrolysis is considered a promising next-generation hydrogen production technology that can produce low-cost, clean hydrogen. However, anion exchange membrane electrolysis technology is in its early stages of development and requires intensive research on electrodes, which are a key component of the catalyst-system interface. In this study, we optimized the pressure conditions of the hot-pressing process to manufacture cobalt oxide electrodes for the development of a high uniformity and high adhesion electrode production process for the oxygen evolution reaction. As the pressure increased, the reduction of pores within the electrode and increased densification of catalytic particles led to the formation of a uniform electrode surface. The cobalt oxide electrode optimized for pressure conditions exhibited improved catalytic activity and durability. The optimized electrode was used as the anode in an AEMWE single cell, exhibiting a current density of 1.53 A cm^-2 at a cell voltage of 1.85 V. In a durability test conducted for 100 h at a constant current density of 500 mA cm^-2, it demonstrated excellent durability with a low degradation rate of 15.9 mV kh^-1, maintaining 99% of its initial performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.2
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• pp.128-134
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• 2024

Asphalt-based waterproofing materials for bridge decks face issues such as softening or liquefaction of the material during the process of pouring hot asphalt concrete on top of the waterproofing layer. This leads to instability and reduced thickness of the waterproofing layer. To address these problems, new solutions beyond the existing materials, including the development and adoption of new materials, are required. Therefore, this study investigates the properties of MMA(Methyl Methacrylate) coating waterproofing material, which meets the basic physical properties for bridge deck waterproofing. We examined the overall quality standards in a system where the substrate concrete, waterproofing material, and paving layer are integrated. The study confirmed the applicability of MMA coating waterproofing material on bridge decks. The results indicate that a stable application of MMA coating waterproofing material for civil engineering structures' bridge decks can be achieved with a mix ratio of hard MMA resin : soft MMA resin : powder = 6 : 34 : 60. Additionally, when using emulsified asphalt with hardening characteristics for the adhesion between the dissimilar materials of MMA waterproofing and asphalt concrete, it is expected to meet the minimum quality standards of the Ministry of Land, Infrastructure, and Transport's 'Guidelines for Asphalt Concrete Pavement Construction (2021.07)'.

• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.309-315
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• 2024

Silicon and carbon composite (SiC) is considered one of the most promising anode materials for the commercialization of Si-based anodes, as it could simultaneously satisfy the high theoretical capacity of Si and the high electronic conductivity of carbon. However, SiC active material undergoes repeated volumetric changes during charge/discharge processes, leading to continuous electrolyte decomposition and capacity fading, which is still considered an issue that needs to be addressed. To solve this issue, we suggest a 4,4'-Methylenebis(cyclohexyl isocyanate) (H₁₂MDI)-based waterborne polyurethane binder (HPUD), which forms a 3D network structure through thermal cross-linking reaction. The cross-linked HPUD (denoted as CHPU) was prepared using an epoxy ring-opening reaction of the cross-linker, triglycidyl isocyanurate (TGIC), via simple thermal treatment during the SiC anode drying process. The SiC anode with the CHPU binder, which exhibited superior mechanical and adhesion properties, not only demonstrated excellent rate and cycling performance but also alleviated the volume expansion of the SiC anode. This work implies that eco-friendly binders with cross-linked structures could be utilized for various Si-based anodes.