• Title/Summary/Keyword: Additive Mixing

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Effects of the Mixing of an Active Material and a Conductive Additive on the Electric Double Layer Capacitor Performance in Organic Electrolyte

  • Yang, Inchan;Kwon, Soon Hyung;Kim, Bum-Soo;Kim, Sang-Gil;Lee, Byung-Jun;Kim, Myung-Soo;Jung, Ji Chul
    • Korean Journal of Materials Research
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    • v.25 no.3
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    • pp.132-137
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    • 2015
  • The effects of the mixing of an active material and a conductive additive on the electrochemical performance of an electric double layer capacitor (EDLC) electrode were investigated. Coin-type EDLC cells with an organic electrolyte were fabricated using the electrode samples with different ball-milling times for the mixing of an active material and a conductive additive. The ball-milling time had a strong influence on the electrochemical performance of the EDLC electrode. The homogeneous mixing of the active material and the conductive additive by ball-milling was very important to obtain an efficient EDLC electrode. However, an EDLC electrode with an excessive ball-milling time displayed low electrical conductivity due to the characteristic change of a conductive additive, leading to poor electrochemical performance. The mixing of an active material and a conductive additive played a crucial role in determining the electrochemical performance of EDLC electrode. The optimal ball-milling time contributed to a homogeneous mixing of an active material and a conductive additive, leading to good electrochemical performance of the EDLC electrode.

Homogeneous Mixing of Si3N4 with Sintering Additives by Coprecipitation Method (질화규소의 소결첨가제의 공침법에 의한 균일혼합)

  • 김지순
    • Journal of the Korean Ceramic Society
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    • v.30 no.10
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    • pp.829-837
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    • 1993
  • Chemically and geometrically homogeneous mixing of Si3N4 powders with sintering additives(YAG, 3Y2O3$.$5Al2O3) was attempted via coprecipitation method. X-ray dot maps for the additive elements(Al and Y) showed that the additives are evenly distributed in the powder mixture prepared by coprecipitation method(CP). TEM observation of the coprecipittion-treated Si3N4 powders revealed that they are covered with extremely fine crystallites of additive. The shift in isoelectric point(IEP) of Si3N4 powders from pH 6.7 to pH 7.9 after coprecipitation mixing gave another evidence for coating of Si3N4 powders with YAG additives. SIMS analysis for composition on the surface and in the matrix of mixed powders showed that the YAG additives are highly enriched on the surface of coprecipitation-treated Si3N4 powders. Especially when a small amount of additive was used, the effect of homogeneous additive distribution on densification was preceptible: After pressureless-sintering of powder compacts containing 5 mol% YAG at 1800$^{\circ}C$ for 0.5h, a sintered density of 96.5% theoretical was obtained from the specimens prepared bycoprecipitation in comparison with 93.8% from the mechanically-mixed one.

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Analysis of Mechanical Properties of Colored EPDM Based on Additive Mixing Ratio Using Mixture Design of Experimental Method (혼합물 실험계획법을 이용한 유색 EPDM의 첨가제 배합비에 따른 기계적 특성 분석)

  • Park, Yoon-A;Jeon, Euy-Sik;Kim, Young-Shin;Lee, Hyun-Seung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.8
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    • pp.79-86
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    • 2022
  • With the recent increase in the demand for electric vehicles, it is necessary to identify the high current safety of automobile parts. Among the automobile parts, the EPDM parts required colored parts from the existing black; therefore, it was necessary to change the basic filler from carbon black to silica. The rubber used in automobile parts is flexible and exhibits basic characteristics of high strength and elongation. However, as the filler is changed to silica, its physical properties, such as tensile strength and elongation, are lower than those of the existing carbon black base. Therefore, it is necessary to evaluate the mechanical properties with the addition of the EPDM compound using silica as a base without degrading the physical properties of EPDM. In this study, an experiment based on the additive content was performed using the mixture experimental planning method to analyze the mechanical properties according to the additive type and mixing ratio of silica-based EPDM. The mixing ratio of the four additives was set using a simplex lattice design, and the tensile strength, elongation, modulus 300%, and permanent compression reduction rate were analyzed for mechanical characteristics, and rheometer experiments were performed for vulcanization characteristics. Through statistical analysis of the measured data, the main effects and interactions of the EPDM-blended rubber additives were analyzed. These results can be used to derive a mixing ratio of additives that satisfies the required characteristics of the EPDM compound.

A study on development of artificial aggregates for embankment using reclaimed coal ash from thermoelectric power station (화력발전소 매립석탄회를 이용한 성토용 인공골재 개발 연구)

  • Yoon, Myung-Seok;Ahn, Dong-Wook;Jang, Nam-Ju;Han, Sang-Jae;Kim, Soo-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1051-1060
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    • 2008
  • The use of the coal ash for surcharge material, in a view of the environmental aspect, can decrease amount of the reclamation through recycling waste materials as well as prevent a destruction of the ecosystem attributed to sand picking. In addition, it can reduce both unit cost of material and construction expenses. In this study, new construction material as alternative surcharge material using coal ash, which is by-product from thermoelectric power plant, were developed. Mixing ratios of fly ash and bottom ash derived from the coal ash in Samchunpo thermoelectric power plants were determined. Furthermore, mixing conditions depending on the ratios of the cement and gypsum used for chemical additive were determined too. Uniaxial compression strength tests were conducted at different mixing conditions and Design graph of optimum mixing ratio at each required strength for economic efficiency is indicated in this paper.

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Effect of Cow Manure and Saw Dust as the Additive Materials for Efficient Vermistabilization

  • Kim, Cbul;Son, Hee-Jeoog;Yoon, Tae-Kyung
    • Journal of Environmental Health Sciences
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    • v.33 no.6
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    • pp.488-492
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    • 2007
  • The influence of additive materials including saw dust and cow manure in the ripening of leather sludge for the efficient vermisabilization was studied. The ripening characteristics of the leather sludge, the growth of earthworms in the growth bed and the by-products like cast were observed according to the mixing ratio of additive materials. When the mixed leather sludge of which the additive materials contents were over 20% were ripened for 50 days, the values of ORP and alkalinity were changed to the favorable ranges for earthworms, the positive (+) and below 1,000 mg/l as $CaCO_3$, respectively. The velocity of ripening improving the characteristics of the leather sludge was faster in the sludge mixed with cow manure than saw dust. This results could also be verified from the monitoring of the states of earthworm growth using the survival rate, the increase rate of lifeweight and the hatching rate of earthworm cocoon in the their growth bed packed with the ripened sludge. The values of CEC in cast, the vermi-stabilized sludge, were increased with the mixing ratio of additive materials, but the content of heavy metals was drcreased by the dilution effect and accumulation in the earthworm body. Above results show that the leather sludge might be efficiently stabilized by earthworms through the ripening for 50 days using additive materials. Cow manure can be used as a good additive materials for leather sludge as much as saw dust, and the optimum content of additive materials in the well-ripened leather sludge was about 30%.

Delayed compaction effect on the strength and dynamic properties of clay treated with lime

  • Turkoz, Murat
    • Geomechanics and Engineering
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    • v.18 no.5
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    • pp.471-480
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    • 2019
  • The constructions of engineering structures such as airports, highways and railway on clayey soils may create many problems. The economic losses and damages caused by these soils have led researchers to do many studies using different chemical additives for the stabilization of them. Lime is a popular additive used to stabilize the clayey soils. When the base course is stabilized by mixing with an additive, inevitable delays may occur during compaction due to reasons like insufficient workers, breakdown of compaction equipment, etc. The main purpose of this study is to research the effect of compaction delay time (7 days) on the strength, compaction, and dynamic properties of a clay soil stabilized with lime content of 0, 3, 6, 9, 12 and 15% by dry weight of soil. Compaction characteristics of these mixes were determined immediately after mixing, and after 7 days from the end of mixing process. Within this context, unconfined compressive strength (UCS) under the various curing periods (uncured, 7 and 28 days) and dynamic triaxial tests were performed on the compacted specimens. The results of UCS and dynamic triaxial tests showed that delayed compaction on the strength of the lime-stabilized clay soil were significantly effective. Especially with the lime content of 9%, the increase in the shear modulus (G) and UCS of 28 days curing were more prominent after 7 days mellowing period. Because of the complex forms of hysteresis loops caused by the lime additive, the damping ratio (D) values differed from the trends presented in the literature and showed a scattered relationship.

Increasing of Thermal Conductivity from Mixing of Additive on a Domestic Compacted Bentonite Buffer (국산 압축벤토나이트 완충재의 첨가제 혼합을 통한 열전도도 향상)

  • Lee, Jong-Pyo;Choi, Heui-Joo;Choi, Jong-Won;Lee, Minsoo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.1
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    • pp.11-21
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    • 2013
  • The Geyoungju Ca-bentonite with dry density of 1.6 g/$cm^3$ has been considered as a standard buffer material for the disposal of high level waste in KAERI disposal system design. But it had relatively lower thermal conductivity compared with other surrounding materials, that was one of key parameters to limit the increase of the disposal density in the disposal system. In this study, various additives were selected and mixed with the Ca-bentonite in different mixing methods in order to increase the thermal conductivity from 0.8 W/mK to 1.0 W/mK. As an additive, CNT (Cabon Nano Tube), graphite, alumina, CuO, and $Fe_2O_3$ were selected, which are chemically stable and have good thermal conductivity. As mixing methods, dry hand-mixer mixing, wet milling and dry ball mill mixing were applied for the mixing. Above all, the ball mill mixing was proved to be most effective since the produced mixture was most homogeneous and showed higher increase in the thermal conductivity. From this study, it was confirmed that the thermal conductivity for the Geyoungju Ca-bentonite could be improved by adding small amount of highly thermal conductive material to 1.0 W/mk. In conclusion, it was believed that the experimental results will be valuable in the disposal system design if the additive effects on the swelling and permeability on the compact bentonite are also approved in further studies.

Evaluating Shrinkage Characteristic of Ternary Grout for PSC Bridge Using Expansive Additive and Shrinkage Reducing Agent (팽창재 및 수축저감제를 이용한 PSC 교량용 3성분계 그라우트의 수축특성 평가)

  • Yuan, Tian-Feng;An, Gi-Hong;Ryu, Gum-Sung;Koh, Kyoung-Taek;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.28 no.5
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    • pp.519-525
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    • 2016
  • This paper reports on analyzing the free and restrained shrinkage characteristic of ternary grout used cementitious admixture. In this study, the cementitious admixture was used such as fly ash, ziricania silica fume by combination of expansive additive (a, b) and shrinkage reducing agent. And a number of basic performance tests were conducted to investigate bleeding, volume change, fluidity and compressive strength behavior. According to the results, within appropriate mixing ratio, even the fluidity is not influenced by expansive additive and shrinkage reducing agent, the resistant properties of bleeding, volume change, shrinkage and compressive strength are increased. Comparing with plain grout, the free shrinkage reduced by a minimum of 29% which specimens are added expansive additive and shrinkage reducing agent. The combination of expansive additive a and shrinkage reducing agent is the most effective for reduction of shrinkage. And increasing the mixing ratio of expansive additive and shrinkage reducing agent extended cracking time. Nevertheless, combined addition of expansive additive a 2.0% and shrinkage reducing agent 0.50% has best shrinkage reduction behavior and not appeared cracking. From the above, the mixing ratio of 2.0% of expansive additive a and 0.50% of shrinkage reducing agent is high performance ternary grout for PSC bridge.

Effect of Additive Powder on Microstructural Evolutions and Mechanical Properties of the Wide-gap Brazed Region in IN738 superalloy (초내열합금 wide-gap 브레이징부의 미세조직 및 기계적 성질 변화에 미치는 첨가금속분말의 영향)

  • Kim Y. H.;Kwun S. I.;Byeon J. W.;Lee W. S.
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.399-407
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    • 2005
  • The effect of IN738 additive powder on microstructure and mechanical properties of the wide-gap region brazed with BNi-3 filler metal powder was investigated. The wide-gap brazing was conducted in a vacuum of $2\times10^{-5}torr\;at\;1200^{\circ}C$ with various powder mixing ratios of additive to filler powders. The microstructures of the wide-gap brazed region were analyzed by SEM and AES. The region brazed with only BNi-3 filler metal powder had a microstructure consisted of proeutectic, binary eutectic and ternary eutectic structure, while that brazed with a mixture of IN738 additive powder and BNi-3 filler metal powder had a microstructure consisted of IN738 additive powder, binary eutectic of $Ni_3B-Ni$ solid solution and (Cr, W)B. The fracture strength of the wide-gap brazed region was about 680 MPa regardless of the additive powder mixing ratios. Cracks were initiated at the (Cr, W)B and binary eutectic of $Ni_3B-Ni$ solid solution, and propagated through them in the wide-gap brazed region, which lowered the fracture strength of the region.

Design of QPSK Demodulator Using CMOS BPSK Receiver and Reflection-Type Phase Shifter (CMOS 기반 BPSK 수신기와 반사형 위상 천이기를 이용한 QPSK 복조기 설계)

  • Moon, Seong-Mo;Park, Dong-Hoon;Yu, Jong-Won;Lee, Moon-Que
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.8
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    • pp.770-776
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    • 2009
  • We propose and demonstrate an I/Q demodulator using four-port BPSK demodulator base on additive mixing and reflection-type phase shifter using hybrid technique. Previously, the conventional I/Q demodulator base on multiplicative or additive mixing method divides I/Q signal path from mixer to parallel-to-serial converter. In this paper, we propose new I/Q demodulator without dividing I/Q baseband signal path. The proposed schematic requires half size in implementation and half power consumption in baseband path compared with the conventional receiver. Also, the proposed receiver eliminates parallel-to-serial converter after data decoding. The proposed circuit has been successfully demodulated a QPSK signal with the L-band carrier frequency and 20 Mbps data rate.