• Title/Summary/Keyword: Additional substrate

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Application of thermodynamics to chemical vapor deposition

  • Latifa Gueroudji;Hwang, Nong-Moon
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.1-20
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    • 1998
  • Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

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Electro-optic characteristic of homogeneously aligned LCD driven by an oblique field (경사 전기장 구동에 의한 수평배열 액정 디스플레이의 전기광학특성 연구)

  • Park, Sang-Hyun;Lee, Ji-Youn;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.104-108
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    • 2005
  • We have studied electrode-optic characteristics of IPS (in-plane switching) mode with electrode on top substrate. Because the IPS mode does not have electrode on top substrate. it shows not only slow response time due to weak electric field but also slow discharging problem when electrostatic field is generated after fabricating the cell. To solve these problems. we have formed additional electrode including dielectric layer in the inner part of the cell and studied electrode-optic characteristics of new IPS cell by changing thickness of dielectric layer.

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Low temperature preparation of $SnO_2$ films by ICP-CVD (ICP-CVD를 이용한 $SnO_2$ 박막 저온 증착)

  • Lee, H.Y.;Lee, J.J.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.157-158
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    • 2007
  • Tin oxide films were successfully crystallized without additional heating by inductively coupled plasma assisted chemical vapor deposition (ICP-CVD). The degree of crystallization was affected by the ICP power, hydrogen flow and ion bombardment induced by negative substrate bias. The substrate temperature was increased only up to $150^{\sim}180^{\circ}C$ by plasma heating, which suggests that the formation of $SnO_2$ crystalswas caused by enhanced reactivity of precursors in high density plasma. The hardness of deposited tin oxide films ranged from 5.5 to 11GPa at different hydrogen flow rates.

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Synthesis and Printability of Aqueous Ceramic Ink with Graft Polymer (Graft Polymer를 이용한 수계 세라믹 잉크의 합성 및 프린팅 특성평가)

  • Lee, Ji-Hyeon;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.639-646
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    • 2019
  • Ink-jet printing is a manufacturing process technology that directly prints a digitalized design pattern onto a substrate using a fine ink jetting system. In this study, environmentally friendly yellow aqueous ceramic ink is synthesized by mixture of distilled water, yellow ceramic pigment and additives for ink-jet printing. The graft polymer, which combines electrostatic repulsion and steric hindrance mechanism, is used as a surfactant for dispersion stability of aqueous ceramic ink. Synthesized ceramic ink with graft polymer surfactant shows better dispersion stability than did ceramic ink with PAA surfactant; synthesized ink also shows desirable ink-jet printability with the formation of a single ink droplet during printability test. Finally, ceramic ink printed on glass substrate and ceramic ink with graft polymer surfactant shows a high contact angle without surface treatment on glass substrate. Consequently, it is confirmed that the ceramic ink with graft polymer surfactant can achieve high printing resolution without additional surface treatment process.

High-performance filtering power divider based on air-filled substrate integrated waveguide technology

  • Ali-Reza Moznebi;Kambiz Afrooz;Mostafa Danaeian
    • ETRI Journal
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    • v.45 no.2
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    • pp.338-345
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    • 2023
  • A filtering power divider based on air-filled substrate-integrated waveguide (AFSIW) technology is proposed in this study. The AFSIW structure is used in the proposed filtering power divider for substantially reducing the transmission losses. This structure occupies a large area because of the use of air as a dielectric instead of typical dielectric materials. A filtering power divider provides power division and frequency selectivity simultaneously in a single device. The proposed filtering power divider comprises three AFSIW cavities. The filtering function is achieved using symmetrical inductive posts. The input and output ports of the proposed circuit are realized by directly connecting coaxial lines to the AFSIW cavities. This transition from the coaxial line to the AFSIW cavity eliminates the additional transitions, such as AFSIW-SIW and SIW-conductor-backed coplanar waveguide, applied in existing AFSIW circuits. The proposed power divider with a second-order bandpass filtering response is fabricated and measured at 5.5 GHz. The measurement results show that this circuit has a minimum insertion loss of 1 dB, 3-dB fractional bandwidth of 11.2%, and return loss exceeding 11 dB.

Effect of an additional resistance on Shapiro steps of the Josephson junction (조셉슨 접합의 샤피로 계단특성에 대한 부가저항의 효과)

  • Shim, Woo-Seok;Cho, Won-Il;Song, I-Hun;Kim, Do-Hyun;Park, Gwang-Seo;Song, In-Sang
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.223-228
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    • 1999
  • We have investigated the microwave properties of a high-T$_c$. superconducting Josephson junction by Shapiro step measurements. A Josephson junction was fabricated on the bicrystal MgO substrate using pulsed laser deposition method. We have measured Shapiro steps in the I-V characteristics under the irradiation of 1.36 cm wavelength up to 45 K and found inclined current steps above 50 K. In order to understand these results, we introduced an additional resistance connected in series to RSJ model. Using this modified RSJ model, we could explain the inclined current steps as a result of superposition of the junction and an additional resistance above certain temperatures. Also, we presented the received power of the Josephson junction above 50 K.

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Effect of Substrate Bias Voltage on the Electrical Properties of ZnO:Al Transparent Conducting Film Deposited on Organic Substrate (유기물 기판 위에 증착된 ZnO:Al 투명전도막의 전기적 특성에 미치는 기판 바이어스 전압의 효과)

  • Kwak, Dong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.1
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    • pp.78-84
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    • 2009
  • In this paper, ZnO:Al thin film was deposited on polyethylene terephthalate(PET) substrate by capacitively coupled r. f. magnetron sputtering method from a ZnO target mixed with 2wt[%] Al2O3 to investigate the possible application of ZnO:Al film as a transparent conducting electrode for film typed DSCs. The effect of substrate bias on the electrical properties and film structure were studied. The results showed that a positive bias applied to the substrate during sputtering contributed to an improvement of electrical properties of the film by attracting electrons in the plasma to bombard the growing films. These bombardments provided additional energy to the growing ZnO:Al film on the substrate, resulting in significant variations in film structure and electrical properties. Electrical resistivity of the film decreases significantly as the positive bias increases up to +30[V] However, as the positive bias increases over +30[V], the resistivity decreases. The transmittance varies little as the substrate bias is increased from 0 to +60[V], and as r. f. powers increases from 160[W] to 240[W]. The film with electrical resistivity as low as $1.8{\times}10^{-3}[{\Omega}-cm]$ and optical transmittance of about 87.8[%] were obtained for 1,012[nm] thick film deposited with a substrate bias of +30[V].

Models of Wastewater Treatment by Rotating Discs (회전원판접촉법(回轉圓板接觸法)에 의한 폐수처리(廢水處理)의 모형(模型)에 관한 연구(研究))

  • Chung, Tai Hak;Park, Chung Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.2
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    • pp.39-46
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    • 1982
  • A model of substrate removal by rotating discs has been developed for a better understanding of the process, and the performance of the system has been evaluated under steady and unsteady state. The model was constructed based upon mass transfer of the substrate from the bulk solution to the biofilm and a simultaneous removal of the substrate by the biomass. The model is composed of a few sets of differential equations representing mass balance within the elements of a liquid film and a biofilm, and in the bulk solution. Substrate removal efficiency of the process is largely dependent on a diffusion coefficient of the substrate within the biofilm and a maximum rate of substrate removal of the biomass. The efficiency is affected to a greater extent when the substrate concentration is low and the maximum substrate removal rate is high. The efficiency increases proportionally with increasing film depth when the biofilm is shallow, however, the rate of increase gradually decreases with an increase of the film depth. As the film reaches a limiting depth, the efficiency remains constant. Unlike the steady state, the effluent quality is affected by the tank volume under dynamic state. Increasing tank volume decreases peak concentration of the effluent under peak loading. Additional tank volume provides a buffer capacitya.gainst a peak loading and the holding tank behaves like an equalization tank.

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Effects of microplastics and salinity on food waste processing by black soldier fly (Hermetia illucens) larvae

  • Cho, Sam;Kim, Chul-Hwan;Kim, Min-Ji;Chung, Haegeun
    • Journal of Ecology and Environment
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    • v.44 no.1
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    • pp.45-53
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    • 2020
  • Background: The black soldier fly (Hermetia illucens) is gaining attention as an efficient decomposer of food waste. However, recalcitrant compounds such as plastics mixed into food waste may have negative effects on its growth and survival. Moreover, its efficiency of food waste degradation may also be affected by plastics. In addition, salt (NaCl) can also be present in high concentrations, which also reduces the efficiency of H. illucens-mediated food waste treatment. In this study, we assessed the growth of black soldier fly larvae (BSFL) reared on food waste containing polyethylene (PE) and polystyrene (PS) and NaCl. The weight of BSFL was measured every 2-4 days. Survival and substrate reduction rates and pupation ratio were determined at the end of the experiment. Results: The total larval weight of Hermetia illucens reared on food waste containing PS was greater than that of the control on days 20 and 24. However, the survival rate was lower in the group treated with 5% PS, as was substrate reduction in all PS-treated groups. The weight of BSFL reared on food waste containing PE was lower than that of the control on day 6. PE in food waste did not affect the survival rate, but the pupation ratio increased and substrate consumption decreased with increasing PE concentrations. Regardless of the plastic type, the addition of NaCl resulted in decreased larval weight and pupation ratio. Conclusions: Larval growth of black soldier fly was inhibited not by plastics but by substrate salinity. Additional safety assessments of larvae reared on food waste containing impurities are needed to enable wider application of BSFL in vermicomposting.

A Substrate Serves as a Hydrogen Atom Donor in the Enzyme-Initiated Catalytic Mechanism of Dual Positional Specific Maize Lipoxygenase-1

  • Huon, Thavrak;Jang, Sung-Kuk;Cho, Kyoung-Won;Rakwal, Randeep;Woo, Je-Chang;Kim, Il-Chul;Chi, Seung-Wook;Han, Ok-Soo
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.917-923
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    • 2009
  • The maize lipoxgyenase-1 is a non-traditional dual positional specific enzyme and the reaction proceeds via enzyme-initiated catalysis. Bioinformatic analysis indicated that the maize lipoxygenase-1 is structurally more similar to soybean LOX1 than pea LOXN2 in that it has an additional external loop (residues 318-351) in the carboxy-terminal catalytic domain. We analyzed the dependence of product distribution on concentration of linoleic acid and monitored the formation of hydroperoxyoctadecadienoic acid as a function of enzyme concentration. Product distribution was strongly influenced by substrate concentration, such that kinetically-controlled regioisomers were enriched and thermodynamically-controlled regioisomers were depleted at high substrate concentration. Kinetic studies indicated that the formation of hydroperoxyoctadecadienoic acid saturated rapidly in an enzyme concentration-dependent manner, which implied that reactivation by reoxidation of inactive Fe(II) failed to occur. Our results support the previously proposed enzyme-initiated catalytic mechanism of the maize lipoxgyenase-1 and reveals that a substrate molecule serves as a hydrogen atom donor in its enzyme-initiated catalysis.