• Bulletin of the Korean Chemical Society
• /
• v.31 no.4
• /
• pp.859-862
• /
• 2010

The reactions of ketene dithioacetals with ethane-1,2-diamine, propane-1,3-diamine, 2-aminoethanol, 3-aminopropanol, and 2-aminoethanethiol in ordinary water in the absence of any acid/base catalyst afforded the heterocyclic ketene N,N-, N,O- and N,S-acetals in good yields.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.18 no.5
• /
• pp.455-461
• /
• 2009

In a scanning electron microscopy, image distortion is a critical issue and it is needed to be eliminated by some kinds of schemes. In this work, scanning frequency and scanning wave form are adjusted to have an improved image. The relationship between scan coil and its driver is investigated and appropriate frequency and wave form are suggested. It is proved that the selected frequency and wave form showed an enhanced image with less distortion, which were done by experiments. In addition, a noise elimination is addressed, providing improved image with a GROUND signal integration with the amplifier and the scan driver.

• YAKHAK HOEJI
• /
• v.27 no.2
• /
• pp.149-154
• /
• 1983

The effect of hydrochlorothiazide on the pharmacokinetics of carteolol in rabbits was studied. Animals were divided into two groups (group I and group II). Group I received carteolol (12mg/kg) and group II received carteolol (12mg/kg) with hydrochlorothiazide (20mg/kg) orally. The carteolol concentration in serum was measured by spectrofluorometric method and its pharmacokinetic parameter values were calculated. The serum concentration of carteolol in group II was significantly increased when compared with those in group I at 10min (p<0.01), and at 30min (p<0.05) after p. o. administration. In addition, the absorption rate constant of carteolol in group II was slightly increased and Tmax of carteolol in group II was significantly shortened (p<0.05) and Cmax of carteolol in group II was significantly increased (p<0.02) when compared with those in group I. But elimination rate constant and biological half-life of carteolol were similar in both groups.

• Journal of the Korean Chemical Society
• /
• v.18 no.4
• /
• pp.251-258
• /
• 1974

The rate constants for the nucleophilic substitution reactions of substituted benzoyl chlorides with p-nitroaniline in such solvents as acetone, acetonitrile, methanol, ethanol, etc. were conductometrically determined, and the activation thermodynamic parameters were also evaluated. In result, the reaction rates were faster in protic solvents than in aprotic solvent; in the solvents of similar property, the reaction rate in the solvent of the large dielectric constant was faster than that in the solvent of the small dielectric constant. Hammett plots in individual solvents showed the straight lines with positive slope; and we concluded that the reaction occurred via the addition-elimination mechanism.

• The Transactions of the Korean Institute of Electrical Engineers B
• /
• v.48 no.12
• /
• pp.715-726
• /
• 1999

This paper estimates the capacity of shunt type active power filters(APF) for harmonic/reactive power compensation with a thyristor converter load. The base capacity requirement of APF is defined for idealized converter load current waveform and the effect of commutation overlap on the APF capacity is examined. The APF capacity required for reactive power compensation in addition to the harmonic elimination is estimated to give maximum achievable power factor for various operating condition of the partially-loaded thyristor converter. The method of current limit of APF is introduced, and it is shown that the APF capacity can be considerably reduced by deliberately limiting the peak current while maintaining the filtering performance to meet the level std 519 regulation.

• The Transactions of the Korean Institute of Electrical Engineers B
• /
• v.49 no.4
• /
• pp.233-239
• /
• 2000

There are many difficult problems in analyzing the gas flow in puffer type circuit breaker such as complex geometry, moving boundary, shock wave and so on. To predict the interruption performance accurately, these should be considered in the simulation. In this paper, the analysis procedure of the cold gas flow in the circuit breaker is presented. Euler equation is solved by FVFLIC method which is an explicit time difference scheme for an unsteady flow computation. Moving boundaries are treated with a cell elimination-addition technique. The pressure and density in front of piston are calculated from the rate of the cell volume change. The presented method is applied to the real circuit breaker model and the pressure in front of the piston is good agreement with the experimental one.

• Journal of Power Electronics
• /
• v.7 no.3
• /
• pp.257-264
• /
• 2007

Active power filters can be cost-effective for use in practical systems with the insertion of a few passive elements in shunt or series configuration. The resulting hybrid filters can be designed to provide dominant lower order harmonic elimination and reactive power support by the passive elements so that the burden on the active filter counterpart is reduced. In this paper, the rate reduction in the shunt active filter is estimated when it is connected in parallel with suitable passive tuned harmonic filters. The active filtering system is based on an appropriate control scheme. The simulation and the experimental results of the shunt active filter, along with the estimated value of reduction in rating, show that the hybrid shunt filtering system is quite effective in compensating for the harmonics and reactive power, in addition to being cost-effective.

• Bulletin of the Korean Chemical Society
• /
• v.13 no.1
• /
• pp.83-87
• /
• 1992

The ring expansion of 1,3-thiazolidines 4 derived from ${\beta}$-ketoacid derivatives to the corresponding dihydro-1,4-thiazines 1 by using the action of chlorine on 4 has been achieved. In the chlorinolysis unisolable sulfenyl chlorides 5 may be formed from chlorosulfonium ions 11 by ${\beta}$-elimination involving carbonyl activated methylene hydrogens. Addition of sulfenyl chloride to the internal double bond appears to form probable thiiranium ions 14, which in turn gave 1 with loss of acidic proton. Imminium ions 15 could be hydrolyzed easily to give enol 8. As a side reaction, dihydrothiazine that was formed was further chlorinated to produce dichlorides 16 which were rearranged readily to the chloromethyl compounds 10.

• Bulletin of the Korean Chemical Society
• /
• v.18 no.9
• /
• pp.1017-1021
• /
• 1997

Solvolyses of p-methoxyphenyl chloroformate in water, D2O, CH3OD, 50% D2O-CH3OD, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25.0 ℃. Product selectivities are reported at 25 ℃ for a wide range of ethanol-water and methanol-water solvent compositions. The Grunwald-Winstein plots of first-order rate constants for p-methoxyphenyl chloroformate with YCl (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. Third-order rate constants, kww, kaw, kwa and kaa were calculated from the observed kww and kaa values together with kaw and kwa calculated from the intercept and slope of the plot of 1/S vs. [alcohol]/[water]. The calculated rate constants, kcalc and mol % of ester agree satisfactorily with those of the observed rate constants, kobs and mol % of ester, supporting the stoichiometric solvation effect analysis. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination.

• Bulletin of the Korean Chemical Society
• /
• v.12 no.4
• /
• pp.392-397
• /
• 1991

A stereocontrolled synthesis of (${\pm}$)-isocomene (1) via selective monoketalization of tricyclo[6.3.0.$0^{1.5}$]undeca-4,7-dione(13) was reported. Grignard reaction of bicyclic enone 10, which was prepared from 2-methyl-1,3-cyclopentadione, gave the 1,4-addition product 11. The subsequent aldol condensation product 12 was converted to mesyl derivative 13. Transformation from 13 to the desired product 19 was achieved by a series of reactions, i.e., the selective monoketalization at C-4 carbonyl group, the elimination of a mesyl group, Birch alkylation, methylation at C-6, the reduction of carbonyl group, the dehydration of alcohol 18, and hydrolysis of the ketal group.