• Title/Summary/Keyword: Activity of cement

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Characteristics of MgO concrete hydrate (MgO를 혼입한 콘크리트의 수화생성물 특성)

  • Jang, Bong-Seok;Kim, Tae-Sang;Jung, Sang-Hwa;Kim, Wan-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.363-364
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    • 2009
  • The activity and stability test of low-temperature(850 $\sim$ 1,000 ${^\circ}C$) firing MgO which is expected to improve the performance of the crack resistance wee conducted and The degree of hydration for the 10% MgO-mixed cement paste was analyzed after 1day, 3days, 7days, 28days, 56days, 90days, and 180days using SEM, XRD, DSC.

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A STUDY FOR THE CHANGES OF THE MASTICATORY MUSCLES AND THE MANDIBULER MOVEMENT EFFECTED BY INTENTIONAL INCREASE OF ANTERIOR GUIDANCE ANGLE (전치 유도각의 인위적 증가에 의한 저작근과 하악 운동 양상의 변화에 대한 연구)

  • Lee, Yong-Sik;Choi, Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.2
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    • pp.245-257
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    • 1998
  • This study was performed to measure the changes of the mandibular movement and the masticatory muscular activities - anterior temporal and masseter muscle of both side - reflected by intentional increase of anterior guidance angie. For this study, 5 volunteers (3 males and 2 females with average age of 24.0) were selected. Each volunteer had Angle's classification I and did not have any missing tooth except third molar and any extensive restorations. Metallic guide plate was made at volunteer's working model fabricated by improved dental stone and cemented to the palatal surface of maxillary central incisor using resin cement(Panavia $21^{(R)}$) and then adjusted not to give any occlusal interferences at intercuspal position. The activity of masticatory muscles and the changes of mandibular movement were recorded by EMG and Sirognathograph in Biopak analysing system(Bioresearch Inc., Milwaukee, Wisconsin, USA). Measurement was done at before experiment, immediatley after placement, 1 week after placement, immediately after removal, and 1 week after removal. The results were as follows: 1. Moderate phonetic disturbance and mild headache were occured to 3 volunteers for 2 days after setting and 1 volunteer had positive reaction to percussion and slight midline diastema. But all of these clinical signs were diappeared 1 week after removal and the other volunteer did not have any special clinical sign. 2. In the EMG of the mandibular rest position, the mean value of anterior tempotal muscle was increased immediately after placement(p<0.01) and then decreased 1 week after placement(p<0.05) and increased 1 week after removal(p<0.05) but not recovered as before experiment. The mean value of masseter muscle was decreased during the experiment period. 3. In the EMG during mandibular protrusive movement, all muscular activity was decreased during the experiment period. Reduced activity was not recovered 1 week after removal(p<0.03). 4. During the habitual opening, anteroposterior movement of mandible was decreased immediately after placement(p<0.05) and then increased 1 week after placement but not statistically significant(p>0.1). Vertical movement was not shown significant difference during the experiment period(p>0.1). Lateral movement was decreased immediately after placement(p<0.05) and then increased 1 week after placement but not recovered as before experiment. The opening and closing velocity of mandible was shown minor changes but not statistically significant. 5. During the habitual opening, anteroposterior movement of mandible was decreased 1 week after placement(p<0.05) and then increased immediately after removal and recovered 1 week after removal as before experiment. Vertical movement was not shown significant changes. Lateral displacement of mandible was increased continuously and recovered 1 week after removal. Opening velocity was temporarily increased immediately after removal but recovered and closing velocity was not shown significant changes. 6. During the right side chewing, anteroposterior movement of mandible was increased immediately after removal but recovered and vertical movement was not shown statistically significant results. Lateral displacement and velocity of mandible were not shown significant results. 7. During the left side chewing, the changes of mandibular movement pattern were not shown statistically significant results.

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Properties of Chemically Activated MSWI(Municipal Solid Waste Incinerator) Mortar (도시 폐기물 소각재를 이용한 화학적 활성화 모르타르의 특성)

  • Jo, Byung-Wan;Kim, Kwang-Il;Park, Jong-Chil;Park, Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.589-594
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    • 2006
  • The recycling of industrial wastes in the concrete manufacturing is of increasing interest worldwide, due to the high environmental impact of the cement and concrete industries and to the rising demand of infrastructures, both in industrialized and developing countries. The production of municipal wastes in the South Korea is estimated at about 49,902 ton per day and only 14.5% of these are incinerated and principally disposed of in landfill. These quantities will increase considerably with the growth of municipal waste production, the progressive closing of landfill, so the disposal of municipal solid waste incinerator(MSWI) ashes has become a continuous and significant issue facing society, both environmentally and economically. MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1,000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development composition variation of such alkali-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H). The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a alkali-activator. Compressive strengths with values in the 40.5 MPa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.

Exposure Characteristics of Construction Painters to Organic Solvents

  • Park, Hyunhee;Park, Hae Dong;Jang, Jae-Kil
    • Safety and Health at Work
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    • v.7 no.1
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    • pp.63-71
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    • 2016
  • Background: Construction painters have not been studied well in terms of their hazards exposure. The objective of this study was to evaluate the exposure levels of total volatile organic compounds (TVOCs) for painters in the construction industry. Methods: Activity-specific personal air samplings were carried out in three waterproofing activities [polyurethane (PU), asphalt, and cement mortar] and three painting activities (epoxy, oil based, and water based) by using organic-vapor-monitor passive-sampling devices. Gas chromatograph with flame ionization detector could be used for identifying and quantifying individual organic chemicals. The levels of TVOCs, by summing up 15 targeted substances, were expressed in exposure-index (EI) values. Results: As arithmetic means in the order of concentration levels, the EIs of TVOCs in waterproofing works were 10.77, 2.42, 1.78, 1.68, 0.47, 0.07, and none detected (ND) for indoor PU-primer task, outdoor PU-primer task, outdoor PU-resin task, indoor PU-resin task, asphalt-primer task, asphalt-adhesive task, and cement-mortar task, respectively. The highest EI for painting works was 5.61 for indoor epoxyprimer task, followed by indoor epoxy-resin task (2.03), outdoor oil-based-spray-paint task (1.65), outdoor water-based-paint task (0.66), and indoor oil-based-paint task (0.15). Assuming that the operations were carried out continuously for 8 hours without breaks and by using the arithmetic means of EIs for each of the 12 tasks in this study, 58.3% (7 out of 12) exceeded the exposure limit of 100% (EI > 1.0), while 8.3% (1 out of 12) was in 50e100% of exposure limit (0.5 > EI > 1.0), and 4 tasks out of 12 were located in less than 50% of the limit range (EI < 0.5). Conclusion: From this study, we recognized that construction painters are exposed to various solvents, including carcinogens and reproductive toxins, and the levels of TVOC concentration in many of the painting tasks exceeded the exposure limits. Construction workers need to be protected from chemical agents during their painting works by using personal protective devices and/or work practice measures. Additional studies should focus on the exposure assessment of other hazards for construction workers, in order to identify high-risk tasks and to improve hazardous work environments.

A Hydration Reaction and Strength Development Properties of Cement Using Pond Ash in Coal Fired Power Plant (화력 발전소 매립회를 치환한 시멘트의 수화반응 및 강도발현 특성)

  • Lee, Jae-Seung;Noh, Sang-Kyun;Shin, Hong-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.578-584
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    • 2021
  • This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)2 consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

Experimental Study on Physical Properties of High-Strength Concrete Using Sea Sand (해사 사용 고강도 콘크리트의 물성에 관한 실험적 연구)

  • 정영수;배수호;박종협
    • Magazine of the Korea Concrete Institute
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    • v.8 no.3
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    • pp.219-229
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    • 1996
  • Recent construction activity of infrastructures has been booming and accelerating to incur shortage of river sand for concrete works. Thus, sea sand has been excessively used instead of river sa.nd, that directly causes to decrease the quality and the durability of concrete, and then might lead to the collapse of concrete structures. The purpose of this experimental research is not only to develop high-strength concrete using sea sand, but also to investigate mechanical properties of high-strength concrete, such as elastic moduli, compressive strength and etc, which could be used for important design data of concrete structures. Rational analytic formula for elastic moduli have been proposed together with those for the splitting tensile strength and the flexural strength, which are to be predicted from compressive strength of concrete cylinder. Optimum water-cement and water-binder ratio have been experimentally obtained so as to develop high compressive strength with and without using silica fume as a admixture for concrete. It is noted that experimental elastic moduli for high strength concrete above aCk=330kgf /cm2 are less than those by the Code. Appropriate amount of concrete mixture has been experimentally investigated so as to develop maximum compressive, flexural and splitting tensile strength.

Evaluation of Durability Performance in Concrete Incorporating Low Fineness of GGBFS (3000 Grade) (저분말도 고로슬래그 미분말(3000급)을 혼입한 콘크리트의 내구성능평가)

  • Lee, Seung-Heun;Cho, Sung-Jun;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.96-102
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    • 2019
  • When GGBFS(Ground Granulated Blast Furnace Slag) with high blaine is incorporated in concrete, compressive strength in the initial period is improved, but several engineering problems arise such as heat of hydration and quality control. In this paper, compressive strength and durability performance of concrete with 3,000 Grade-low fineness slag are evaluated. Three conditions of concrete mixtures are considered considering workability, and the related durability tests are performed. Although the strength of concrete with 3,000 Grade slag is slightly lower than the OPC(Ordinary Portland Cement) concrete at the age of 28 days, but insignificant difference is observed in long-term compressive strength due to latent hydration activity. The durability performances in concrete with low fineness slag show that the resistances to carbonation and freezing/thawing action are slightly higher than those of concrete with high fineness slag, since reduced unit water content is considered in 3,000 Grade slag mixture. For the long-term age, the chloride diffusion coefficient of the 3000-grade slag mixture is reduced to 20% compared to the OPC mixture, and the excellent chloride resistance are evaluated. Compared with concrete with OPC and high fineness GGBFS, concrete with lower fineness GGBFS can keep reasonable workability and durability performance with reduced water content.

Morphology of Bone-like Apatite Formation on Sr and Si-doped Hydroxyapatite Surface of Ti-6Al-4V Alloy after Plasma Electrolytic Oxidation

  • Yu, Ji-Min;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.79-79
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    • 2017
  • Metallic biomaterials have been mainly used for the fabrication of medical devices for the replacement of hard tissue such as artificial hip joints, bone plates, and dental implants. Because they are very reliable on the viewpoint of mechanical performance. This trend is expected to continue. Especially, Ti and Ti alloys are bioinert. So, they do not chemically bond to the bone, whereas they physically bond with bone tissue. For their poor surface biocompatibility, the surface of Ti alloys has to be modified to improve the surface osteoinductivity. Recently, ceramic-like coatings on titanium, produced by plasma electrolytic oxidation (PEO), have been developed with calciumand phosphorus-enriched surfaces. A lso included the influences of coatings, which can accelerate healing and cell integration, as well as improve tribological properties. However, the adhesions of these coatings to the Ti surface need to be improved for clinical use. Particularly Silicon (Si) has been found to be essential for normal bone, cartilage growth and development. This hydroxyapatite, modified with the inclusion of small concentrations of silicon has been demonstrating to improve the osteoblast proliferation and the bone extracellular matrix production. Strontium-containing hydroxyapatite (Sr-HA) was designed as a filling material to improve the biocompatibility of bone cement. In vitro, the presence of strontium in the coating enhances osteoblast activity and differentiation, whereas it inhibits osteoclast production and proliferation. The objective of this work was to study Morphology of bone-like apatite formation on Sr and Si-doped hydroxyapatite surface of Ti-6Al-4V alloy after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages with various concentrations of Si and Sr ions. Bone-like apatite formation was carried out in SBF solution. The morphology of PEO, phase and composition of oxide surface of Ti-6Al-4V alloys were examined by FE-SEM, EDS, and XRD.

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Influence of nano-silica on the failure mechanism of concrete specimens

  • Nazerigivi, Amin;Nejati, Hamid Reza;Ghazvinian, Abdolhadi;Najigivi, Alireza
    • Computers and Concrete
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    • v.19 no.4
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    • pp.429-434
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    • 2017
  • Failure of basic structures material is usually accompanied by expansion of interior cracks due to stress concentration at the cracks tip. This phenomenon shows the importance of examination of the failure behavior of concrete structures. To this end, 4 types of mortar samples with different amounts of nano-silica (0%, 0.5%, 1%, and 1.5%) were made to prepare twelve $50{\times}50{\times}50mm$ cubic samples. The goal of this study was to describe the failure and micro-crack growth behavior of the cement mortars in presence of nano-silica particles and control mortars during different curing days. Failure of mortar samples under compressive strength were sensed with acoustic emission technique (AET) at different curing days. It was concluded that the addition of nano-silica particles could modify failure and micro-crack growth behavior of mortar samples. Also, monitoring of acoustic emission parameters exposed differences in failure behavior due to the addition of the nanoparticles. Mortar samples of nano-silica particles revealed stronger shear mode characteristics than those without nanoparticles, which revealed high acoustic activity due to heterogeneous matrix. It is worth mentioning that the highest compressive strength for 3 and 7 test ages obtained from samples with the addition of 1.5% nano-silica particles. On the other hand maximum compressive strength of 28 curing days obtained from samples with 1% combination of nano-silica particles.

Development of Participatory Ecological Restoration System through Integrative Categorization of Disturbed Areas in BaigDooDaeGahn (백두대간 대규모 훼손지의 통합적 유형구분을 통한 참여형 복원 시스템 개발 - 도입프로그램(생태교육·생태관광)을 중심으로 -)

  • Ahn, Tong Mahn;Kim, In Ho;Lee, Jae Young;Kim, Chan Kook;Chae, Hye Sung;Lee, Young;Min, So Young;Kim, Min Woo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.4
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    • pp.11-22
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    • 2009
  • This was a 2nd-year study aiming at developing the procedure of alternative system that was intended to restore not only biophysically disturbed areas but also psychologically and socially damaged community. It was suggested that this participatory restoration system could be constructed based on integrative categorization processes consisting of damage types and readiness of local residents for participation. Three case study sites-High-One resort, Lafarge-Halla cement, and high-altitude farmland near Gangneung city, were selected to apply the theoretical framework proposed as a result of 1st-year work. In order to develop introductory programs, key concepts such as forest for future, carbon offset forest, and healing forest, have been suggested based on analysis of 6 system components including human resources, communication, legal and institutional support, financial sources, restoration methods, and activity programs for each site. More detailed processes and procedures can be identified, defined, and refined after the end of final, 3rd-stage of the study in April of 2010.