• Title/Summary/Keyword: Active Metal

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Characteristics of Exhaust Emission Reduction of Heavy Duty Diesel Engine by Oxidation Catalyst - Reactor Test - (산화촉매에 의한 대형디젤엔진의 배출가스 정화 특성 - Reactor 실험을 중심으로 -)

  • Jo, Gang-Rae;Kim, Yong-U;Kim, Hui-Gang
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.313-320
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    • 1998
  • The most desirable diesel oxidation catalyst (DOC) should have the properties of oxidibing CO and HC effectively at low exhaust gas temperature while minimizing the formation of sulfate at high exhaust gas temperature. Precious metals such as platinum and palladium have been known to be sufficiently active for oxidizing CO and HC and also to have high activity for the oxidation of sulfur dioxide (SO2) to sulfor trioxide (SO3). There is a need to develop a highly selective catalyst which can promote the oxidation of CO and HC efficiently, but, on the other hand, suppress the oxidation of SO2. One approach to solve this problem is to load a base metal such as vanadium in Pt-based catalyst to suppress sulfate formation. In this study, a Pt-V catalyst was prepared by impregnating platinum and vanadium onto a Ti-Si wash coated catalyst in a laboratory reactor by changing the formulations and reaction temperatures.

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Physical and catalytic properties of CMCase encoded by Bacillus subtilis gene in B. megaterium

  • Kim, Hoon;Kim, Ha-Geun;Park, Moo-Young
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1986.12a
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    • pp.524.3-524
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    • 1986
  • Carboxymethyl cellulase (CMCase) produced by cloned B. megaterium was found to contain 5.2% carbohydrate but no metal ion. The enzyme was isoelectric at pH 7.23 and was high is basic amino acids. The N-terminal of the enzyme was glutamic acid. The cellulolytic activity of this enzyme was extended to the small molecular substrates such as from cellotriose to cellopentaose. In additon, the enzyme showed transglycoslation activity. The pK values of the enzyme we estimated to be 4.4 and 6.7, andthat of the enzyme-substrate complex were 4.2 and 7.2, respectively. The enzyme was not affected by the treatment with iodoacetic acid, but the modification of enzyme with carbodiimide and diethyl pyrocarbonate resulted in a marked loss of the enzyme activity. These results suggest that the active site of enzyme essentially contains carboxylic and imidazole group of amino acid residues.

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Field Welding Technology for Safe Manufacture of Welding Structure & Recent trend of Welding Technology (용접구조물의 안전시공을 위한 현장기술과 용접기술 동향)

  • 유택인
    • Journal of the Korean Professional Engineers Association
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    • v.34 no.2
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    • pp.37-41
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    • 2001
  • In recent days, welding technology developed in various field of industry, a ship, a building, a structure, a high pressure vessel ect. A welding structure should be base on a safety Welding engineers and welding technicians have a problem in acquiring welding technology, because young people avoid state of the art, beginning their careers In this field. The optimum welding state depends upon the most welding condition, mechanical properties of the base metal, welding processes and arc stability. Base on these fact, the suitable parameters of welding condition can be found through various welding experiments. Therefore, it Is very Important for welding professional engineers to take an active role In advancing new welding technology

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Examination of the Nickel Site Structure in Streptomyces seoulensis Superoxide Dismutase by EPR and X-ray Absorption Spectroscopy

  • Lee, Jin-Won;Yim, Yang-In;Michael J. Maroney;Kang, Sa-Ouk
    • Proceedings of the Korean Biophysical Society Conference
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    • 1998.06a
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    • pp.26-26
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    • 1998
  • Superoxide dismutases are metalloenzymes catalyzing the dimutation of superoxide anion radical to hydrogen peroxide and molecular oxygen. Examples of enzymes containing Cu, Mn and Fe as the redox-active metal have been characterized. Recently, an SOD containing one Ni atom per subunit was reported.(omitted)

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Preparation and Electronic Defect Characteristics of Pentacene Organic field Effect Transistors

  • Yang, Yong-Suk;Taehyoung Zyung
    • Macromolecular Research
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    • v.10 no.2
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    • pp.75-79
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    • 2002
  • Organic materials have considerable attention as active semiconductors for device applications such as thin-film transistors (TFTs) and diodes. Pentacene is a p-type organic semiconducting material investigated for TFTs. In this paper, we reported the morphological and electrical characteristics of pentacene TFT films. The pentacene transistors showed the mobility of 0.8 $\textrm{cm}^2$/Vs and the grains larger than 1 ${\mu}{\textrm}{m}$. Deep-level transient spectroscopy (DLTS) measurements were carried out on metal/insulator/organic semiconductor structure devices that had a depletion region at the insulator/organic-semiconductor interface. The duration of the capacitance transient in DLTS signals was several ten of seconds in the pentacene, which was longer than that of inorganic semiconductors such as Si. Based on the DLTS characteristics, the energy levels of hole and electron traps for the pentacene films were approximately 0.24, 1.08, and 0.31 eV above Ev, and 0.69 eV below Ec.

Studies on Air-bridge fabrication using thermal evaporation method and its aplication (열적 증착법을 이용한 air-bridge 제작과 그 응용에 관한 연구)

  • 이일형;김성수;윤관기;김상명;이진구
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.12
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    • pp.53-58
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    • 1996
  • In this paper, a simple fabrication technique of an air-bridge for interconnection of isolated electrodes of microwave active and passive devices and MMIC's is proposed. The proposed air-bridge proceses are mainly combinations of thermal evaporation, positive photoresist and image reversal processes for easy lift-off of up to 2.0 .mu.m thick metal. According to the resutls of air-birdge processes, it is confirmed that air-gap and thickness of theair-bridge are about 3.5.mu.m, and 2.0.mu.m, respectively. And it is also possible to make the fine air-bridge with widths of 5~60.mu.m and post-intervals of 25~200.mu.m withot collapse. finally, GaAs power MESFET's and rectangular spiral inductors are fabricatd and measured in order to confirm of feasibility of the proposed air-bridge processes. The MAG of the fabricated power MESFET's is 10dB at 10GHz, and the inductance of the (200.mu. * 6 turns) rectangular spiral inductors 4.5 nH inX-band.

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Thermal Deformation Characteristics of the Adaptive Machine Tools under Change of Thermal Environment (열적 환경변화에 의한 공작기계의 구조적 특성)

  • 이재종;이찬홍;최대봉;박현구
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.1023-1027
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    • 2000
  • In metal cutting, the machining accuracy is more affected by thermal errors than by geometric errors. This paper models of the thermal errors for error analysis and develops on-the-machine measurement system by which the volumetric error are measured and compensated. The thermal error is modeled by means of angularity errors of a column and thermal drift error of the spindle unit which are measured by the touch probe unit with a star type styluses, a designed spherical ball artifact, and five gap sensors. In order to analyze the thermal characteristics under several operating conditions, experiments performed with the touch probe unit and five gap sensors on the vertical and horizontal machining centers.

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Research Trends of Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes (OLED용 지연형광 소재의 연구 동향)

  • Lee, Ju Young
    • Ceramist
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    • v.22 no.3
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    • pp.218-229
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    • 2019
  • The development of highly efficient thermally activated delayed fluorescence (TADF) materials is an active area of recent research in organic light emitting diodes (OLEDs) since the first report by Chihaya Adachi in 2011. Traditional fluorescent materials can harvest only singlet excitons, leading to the theoretically highest external quantum efficiency (EQE) of 5% with considering about 20% light out-coupling efficiency in the device. On the other hand, TADF materials can harvest both singlet and triplet excitons through reverse intersystem crossing (RISC) from triplet to singlet excited states. It could provide 100% internal quantum efficiencies (IQE), resulting in comparable high EQE to traditional rare-metal complexes (phosphorescent materials). Thanks to a lot of efforts in this field, many highly efficient TADF materials have been developed. This review focused on recent molecular design concept and optoelectronic properties of TADF materials for high efficiency and long lifetime OLED application.

ZnO TFT with Organic Dielectric (유기절연체를 사용한 ZnO 박막트랜지스터)

  • Choi, Woon-Seop
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.56-56
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    • 2008
  • ZnO Oxide TFT with organic dielectric was prepared. ZnO thin film as active channel was prepared by plasma enhanced atomic deposition technique. Organic dielectric was spin coated on the gate metal. The structure of prepared TFT is bottom gate type and top contact structure. The characterization of oxide TFT was performed. We obtained the mobility of $0.7cm^2$/Vs, the threshold voltage of -14V, and the on-off ratio of $10^4$. We also obtained good output characterization with solid saturation.

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Efficiency Enhancement in Organic Polymer Solar Cells with Ferroelectric Films (강유전 고분자 박막을 이용한 유기고분자 태양전지에서의 효율 증대)

  • Park, Jayoung;Jung, Chi Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.126-132
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    • 2017
  • The power conversion efficiency of organic polymer solar cells was enhanced by introducing a ferroelectric polymer layer at the interface between active layer and metal electrode. The power conversion efficiency was increased by 50% through the enhancement of the open circuit voltage. To investigate the role of the ferroelectric layer on the dissociation process of the excitons, non-radiative portion of the exciton decay was directly measured by using photoacoustic technique. The results show that the ferroelectric nature of the buffer layer does not play any roles on the dissociation process of the excitons, which indicates the efficiency enhancement is not due to the ferroelectricity of the buffer layer.