• Title/Summary/Keyword: Active Metal

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Study on the feasibility of metallic saggar for synthesizing NCM cathode active materials-I (NCM 계 양극활물질 합성용 금속질 내화갑 가능성 연구-I)

  • Yong Il Park;Ji Hun Jung;Sung Hyun Woo;Jung Heon Lee;Hyeong-Jun Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.3
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    • pp.103-107
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    • 2024
  • In this study, nickel, a pure metal material, was proposed as a saggar for synthesizing NCM [Li(NixCoyMnz)O2] cathode active material. Nickel is known as a metal that is resistant to oxidation and has a high melting point. Nickel is one of the main components of NCM cathode material and was expected to be free from problems with contamination from saggar during cathode material synthesis. We sought to confirm the possibility of nickel as a saggar for synthesizing NCM cathode active materials. When a Ni metal crucible and Ni0.8Co0.1Mn0.1(OH)2 (NCM 811) precursor material were reacted at 900℃ for a long time, the change in the reaction layer on the surface of the crucible over time was analyzed. The nickel crucible reaction layer formed during heat treatment at 900℃ was nickel oxide, and is thought to have been created by simultaneous oxygen diffusion from the cathode precursor oxide and reaction with oxygen in the atmosphere. The change in thickness of the oxide layer appears to slow down after 480 hours, which suggests that the rate of oxygen diffusion from the precursor is reduced. It remained combined without falling out of the crucible until 480 hours. However, it was confirmed that the oxide layer falls off after 720 hours, so it is thought that it can be used as saggar for NCM synthesis only for a certain period of time.

Effect of Cutting Fluid on the Metal-Cutting Mechanism (절삭유제가 금속절삭기구에 미치는 영향에 관한 연구)

  • Seo, Nam-Seob
    • Journal of the Korean Society for Precision Engineering
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    • v.2 no.2
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    • pp.69-75
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    • 1985
  • The object of this study is to discuss the effect of cutting fluid on the mechanism of chip formation in orthogonal cutting. Rehbinder effect has been known as a phenomenon, the reduction of mechanical strength, when the metal is exposed in a polar organic environment or the surface of metal is coated with some polar organic substances. About the cause of Rehbinder effect there have been many different ideas by Rehbinder, Merchant, Shaw, Sakakida and etc. In this report, the effects of surface active medium (magic ink) upon the mechanism of chip formation on the orthogonal cutting of copper and the mechanical properties of the work material are experimentally discussed with constant rake angle. Under the condition of polar organic environment the experimental results are as follows; 1) The chip thickness becomes thinner and slip line pitch on the free surface of chip becomes smaller than that of dried cutting area. 2) The order of alternation of cutting ratio was changed. 3) The friction angle on the tool face is not affected by the depth of cut. 4) The cutting force and shear strain on the shear plane decrease remarkably, therefore the work material must be embrittled under polar organic environment.

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Effect of Interlayer Materials on Bending Strength and Reliability of Si$_3$N$_4$/S. S316 Joint (Si$_3$N$_4$/S. S316 접합에서 중간재가 접합강도 및 신회도에 미치는 영향)

  • 윤호욱;박상환;최성민;임연수;정윤중
    • Journal of the Korean Ceramic Society
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    • v.35 no.3
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    • pp.219-230
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    • 1998
  • Various interlayer materials have been tested for active metal(Cusil ABA) brazing of Si3N4/S. S316 joint. In general multilayer joint had higher strength(80-150 MPa) and better reliability than monolayered one. The joint with Cu(0.2)/Mo(0.3)/Cu(0.2mm) interlayer showed the highest bending strength of abou 490 MPa and the joint with Cu(0.2)/Mo(0.3mm) interlayer the best reliability (14.6 Weibull modulus). The stresses distributed in joint materials during 4-point bending test were estimated by CAE von Mises analysis; the estimated stresses were In good agreement with the measured data. In multilayer joint Cu was though to reduce the residual stresses induced by the difference in thermal expansion coefficient between the ceramic Mo and metal It apperared that a Cu/Mo was optimum interlayer material for Si3N4/S. S316 joint with high bending strength (420 MPa) and reliability. In addition the various shapes and types of compound were examined by EPMA in joining interface.

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Development of an Electronic Ballast for 70W Ceramic Discharge Metal Halide Lamps with Step Down Converter (강압형 컨버터를 이용한 70W CDM 램프용 전자식 안정 기의 개발)

  • 김일권;길경석;김진모
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.6 no.7
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    • pp.1055-1061
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    • 2002
  • This paper deals with a design and fabrication of an electronic ballast for 70[W] ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active power factor correction circuit (PFC), a half-bridge inverter, a LC resonant circuit and a microprocessor. The developed ballast also includes a specially designed time circuit which provides reignition signal of lamps. Running frequency of the ballast is .jet at 40[kHz] to avoid acoustic-resonance and flickering. From the experimental results, input power factor and efficiency of the ballast are estimated 99.8[%] and 93.1[%], respectively.

Identification of Novel Non-Metal Haloperoxidases from the Marine Metagenome

  • Gwon, Hui-Jeong;Teruhiko, Ide;Shigeaki, Harayama;Baik, Sang-Ho
    • Journal of Microbiology and Biotechnology
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    • v.24 no.6
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    • pp.835-842
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    • 2014
  • Haloperoxidase (HPO, E.C.1.11.1.7) is a metal-containing enzyme oxidizing halonium species, which can be used in the synthesis of halogenated organic compounds, for instance in the production of antimicrobial agents, cosmetics, etc., in the presence of halides and $H_2O_2$. To isolate and evaluate a novel non-metal HPO using a culture-independent method, a cassette PCR library was constructed from marine seawater in Japan. We first isolated a novel HPO gene from Pseudomonas putida ATCC11172 by PCR for constructing the chimeric HPO library (HPO11172). HPO11172 showed each single open-reading frame of 828 base pairs coding for 276 amino acids, respectively, and showed 87% similarity with P. putida IF-3 sequences. Approximately 600 transformants screened for chimeric genes between P. putida ATCC11173 and HPO central fragments were able to identify 113 active clones. Among them, we finally isolated 20 novel HPO genes. Sequence analyses of the obtained 20 clones showed higher homology genes with P. putida or Sinorhizobium or Streptomyces strains. Although the HPO A9 clone showed the lowest homology with HPO11172, clones in group B, including CS19, showed a relatively higher homology of 80%, with 70% identy. E. coli cells expressing these HPO chimeric genes were able to successfully bioconvert chlorodimedone with KBr or KCl as substrate.

Au Deposition on Amorphous Ga-In-Zn-O (Gallium-Indium-Zinc-Oxide) Film

  • Gang, Se-Jun;Yu, Han-Byeol;Baek, Jae-Yun;Thakur, Anup;Kim, Hyeong-Do;Sin, Hyeon-Jun;Jeong, Jae-Gwan;Lee, Jae-Cheol;Lee, Jae-Hak
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.89-89
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    • 2011
  • a-GIZO(비정질 Ga-In-Zn-O)박막은 유연하며 광학적으로 투명하고 높은 전자의 이동도를 갖는 반도체적 특성을 갖기 때문에 차세대 display분야에서 TFT(Thin-Film-Transistor)의 high speed active-matrix layer로써 각광을 받고 있다. 이 물질의 표면은 환경 및 표면처리에 매우 민감하며 [1,2], 이 표면에 metal이 증착되는 경우에도, 선행 연구에 의하면, 다양한 chemical state가 나타남을 알 수 있었다. 이것은 metal의 증착에 따라 metal과 a-GIZO 사이의 contact 저항이 달라짐을 의미한다. 우리는 a-GIZO 박막 위에 Au를 단계적으로 증착시키면서, Au coverage 증가에 따른 core-level과 valence에서의 x-ray photoelectron spectra의 변화를 살펴봄으로써 a-GIZO박막과 Au의 계면에서 일어나는 chemical state의 변화를 알 수 있었다. 특히, Au deposition의 전 처리과정으로써 Ne ion sputtering을 두 단계로 다르게 하여 a-GIZO의 표면환경에 따른 Au 증착의 영향을 살펴보았다.

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Solar $CO_2$ Reforming of Methane Using $Ni/{\gamma}-Al_2O_3/Metallic$ foam device ($Ni/{\gamma}-Al_2O_3/Metallic$ device를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Shin, Il-Yoong;Lee, Ju-Han;Lee, Jin-Gyu;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.275-281
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    • 2011
  • Solar reforming of methane with $CO_2$ was successfully tested with a direct irradiated absorber on a parabolic dish capable of $5kW_{th}$ solar power. The new type of catalytically activated metallic foam absorber was prepared, and its activity was tested. Ni was applied as the active metal on the gamma - alumina coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically-activated ceramic foam absorber, this new metallic foam absorber is found to exhibit a superior reaction performance at the relatively low insolation or at low temperatures. In addition, unlike direct irradiation of the catalytically-activated ceramic foam absorber, metallic foam absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 2.1kW and the maximum $CH_4$ conversion was almost 40%.

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Magnetic Sensor Using Giant Magneto-Impedance Effect (거대자기임피던스 효과를 이용한 자기 센서)

  • Choi, Kyoo-Nam
    • The Journal of the Korea institute of electronic communication sciences
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    • v.12 no.6
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    • pp.1057-1064
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    • 2017
  • High sensitivity magnetic sensor having foreign metal detection capability is proposed utilizing giant magneto-impedance effect. Strip sensor showed the increasing output voltage when the external magnetic field was applied along with strip from strip grounding point, although the initial DC voltage varied depending on the pointing direction of strip sensor. Proposed sensor was able to eliminate more than half of background noise using active noise filter to achive high sensitivity, and it showed the capability to detect magnetized foreign metal object independent of ambient electro-magnetic noise and earth magnet. In case of ferrous sphere, the metal detection up to 0.8mm diameter was experimentally demonstrated at 5mm distance from strip sensor.

A Study on the Development of an Electronic Ballast for 70W Ceramic Discharge Metal Halide Lamps (70W 세라믹 방전관 메탈할라이드 램프용 전자식 안정기 개발에 관한 연구)

  • 김일권;길경석;이성근;김진모
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.05a
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    • pp.301-304
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    • 2002
  • This paper describes a design and fabrication of an electronic ballast for 70[W]ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active PFC, a half-bridge inverter, a LC resonant circuit and a controller. The design also includes a specially designed time circuit which provides reignition of the lamp. Running frequency of the ballast is set at 45[KHz]to avoid acoustic-resonance and flicker. from the test results, input power factor and efficiency of the ballast were estimated 91[%] and 97.7[%], respectively.

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Development of an Electronic Ballast for 70W Ceramic Discharge Metal Halide Lamps with Step Down Converter (강압형 컨버터를 이용한 70W CDM 램프용 전자식 안정기의 개발)

  • 김일권;길경석;김진모
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.435-439
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    • 2002
  • This paper describes a design and fabrication of an electronic ballast for 70[W] ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active power factor correction circuit (PFC), a half-bridge inverter, a LC resonant circuit and a microprocessor. The developed ballast also includes a specially designed time circuit which provides reignition of lamps. Running frequency of the ballast is set at 40[kHz] to avoid acoustic-resonance and flickering. From the experimental results, input power factor and efficiency of the ballast are estimated 99.8[%] and 93.1[%)] respectively.

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