• Title/Summary/Keyword: Active Metal

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Hyperaccumulation mechanism in plants and the effects of roots on rhizosphere soil chemistry - A critical review (고축적식물의 중금속 흡수기작과 뿌리에 의한 근권 토양의 화학변화 - 총설)

  • Kim, Kwon-Rae;Owens, Gary;Naidu, Ravi;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.280-291
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    • 2007
  • Much research has been conducted in the field of phytoremediation since the discovery of the range of plants known as hyperaccumulators. Research has focused simultaneously on elucidating the mechanism of metal(loid) accumulation and development of practical techniques to enhance accumulation efficiency. To date, it is generally understood that there are five specific mechanisms employed by hyperaccumulating plant species that are either not or under utilized by non-hyperaccumulators. These include 1) enhanced metal(loid)s uptake through the root cell, 2) enhanced translocation in plant tissue, 3) detoxification and sequestration, 4) enhanced metal availability in soil:root interface, and 5) active root foraging toward metal(loid) enriched soils. Among these mechanisms, understanding of the plant-root effect on metal(loid) dynamics and subsequent plant uptake is vital to overcome the inherit limitation of phytoremediation caused by low metal(loid) solubility in soils. Plant roots can influence the soil chemistry in the rhizosphere through changes in pH and exudation of organic compounds such as low-molecular-weight organic acids (LMWOAs) which consequently change metal(loid) solubility. The decrease in soil pH by plant release of $H^+$ results in increased metal solubility. Elevated levels of organic compounds in response to high metal soil concentrations by plant exudation may also increases metal concentration in soil solution through formation of organometallic complexes.

A Study on the Interfacial Bonding in AlN Ceramics/Metals Joints: I. Residual Stress Analysis of AlN/Cu and AlN/W Joints Produced by Active-Metal Brazing (AlN 세라믹스와 금속간 계면접합에 관한 연구 : I. AlN/Cu 및 AlN/W 활성금속브레이징 접합체의 잔류응력 해석)

  • Park, Sung-Gye;Lee, Seung-Hae;Kim, Ji-Soon;You, Hee;Yum, Young-Jin
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.962-969
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    • 1999
  • Elastic and elasto-plastic stress analyses of AlN/Cu and AlN/W pints produced by active-metal brazing method using Ag-Cu-Ti insert-metal were performed with use of Finite-Element-Method(FEM). The results of stress analyses were compared with those from the pint strength tests and the observations of fracture behaviors. It was shown that a remarkably larger maximum principal stress is built in the AlN/Cu pint compared to the A1N/ W joint. Especially, the stress concentration with tensile component was confirmed at the free surface close to the bonded interface of AlN/Cu. The elasto-plastic analysis under consideration of stress relaxation effect of Ag-Cu-Ti insert possessing a so-called 'soft-metal effect' showed that the insert leads to a lowering of maximum principal stress in AlNiCu pint, even though an increase of the insert thickness above 100$\mu\textrm{m}$ could not bring its further decrease. The maximum pint strengths measured by shear test were 52 and 108 MPa for AlNiCu and AlN/W pints. respectively. Typical fractures of AlN/Cu pints occurred in a form of 'dome' which initiated from the free surface of AlN close to the bonded interface and proceeded towards the AlN inside forming a large angle. AlN/W pints were usually fractured at AlN side along the interface of AlN/insert-metal.

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Design and Implementation of Emulator for Standard Conformance Test of Active RFID (능동형 RFID의 표준적합성 시험용 에뮬레이터 설계 및 구현)

  • Song, Tae-Seung;Kim, Tae-Yeon;Lyou, Joon
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.45 no.5
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    • pp.201-208
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    • 2008
  • An active RFID system has the advantages of a long identification distance and a good identification rate as well as overcoming the passive RFID's drawback such as the lowering of identification rate on metal materials. So, the development of an active RFID system has been gradually increasing in harbor logistics and the national defense area. On the other hand, some identification failures between products developed under the same standards have been reported, and there are difficulties in evaluating the interoperability between developed Products and standard conformance test because an accurate evaluation method and equipment has not been established at the international level. Motivated by these, this study presents a realization of the hardware and software of emulator to evaluate the standard conformance of an active RFID system, Performance of the designed system are then analyzed by means of simulations of Matlab/Simulink, and the applicability of the emulator is verified by evaluating the standard conformance of a real active RFID tag.

Immobile Artificial Metalloproteases

  • Kim, Myoung-Soon;Suh, Jung-Hun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.1911-1920
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    • 2005
  • Effective artificial metalloproteases have been designed by using cross-linked polystyrene as the backbone. Artificial active sites comprising Cu(II) complexes as the catalytic site and other metal centers or organic functionalities as binding sites were synthesized. The activity of Cu(II) centers for peptide hydrolysis was greatly enhanced on attachment to polystyrene. By placing binding sites in proximity to the catalytic centers, the ability to hydrolyze a variety of protein substrates at selected cleavage sites was improved. Thus far, the most advanced immobile artificial proteases have been obtained by attaching the aldehyde group in proximity to the Cu(II) complex of cyclen.

Electronic Ratio Control of Metal Belt CVT (금속벨트 CVT 변속비 전자제어화)

  • 김달철;김현수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.4
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    • pp.100-109
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    • 2000
  • In this paper a stepping motor drive electronic ratio control system for a metal belt CVT is suggested. The electronic ratio control system developed in this study is designed to control flow rate which is required to obtain the shift speed and to control the primary actuator pressure to maintain the desired ratio. Considering these control characterstics a fuzzy logic is used for the CVT ratio control. Using the fuzzy logic dynamic models of the ratio control system is investigated and compared with the experimental results. The experimental and simulation results show that the electronic ratio control system developed in this study can be used in CVT system for the active control of the speed ratio.

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A Study on the Oxidation of CO and $C_3H_6$ over Noble Metal Supported Catalysts on Monolith (Monolith에 담지한 귀금속촉매상에서 CO와 $C_3H_6$의 동시적 산화반응에 관한 연구)

  • 김태원;고형림;김재형;김경림
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.1
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    • pp.63-72
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    • 1998
  • Simultaneous CO and $C_3H_6$ oxidation was carried out over noble metal supported monolith catalysts in a flow thorugh type reactor at the temperature ranging from room temperature to $500^\circ$C. Pt and Pd were selected as major active species, 10wt% of Ce was impregnated as an additive and alumina and silica were used as supports. The reactant gases were simulated and the reaction products were analyzed by on-line G.C.. EDX, SEM, TGA, XRD and optical microscope were used to analyze the characteristics of the prepared catalysts. Under the given conditions in this study, the catalysts supported on alumina showed better activity for CO oxidation, while Pd catalysts showed better activity for $C_3H_6$ oxidation. The improvement of conversion due to increase in thermal stability possibily by Ce addition was observed only for Pt catalysts.

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방사성 동위원소를 이용한 문화재의 과학적보존 -고고유품 및 미술품의 조사감식법-

  • 김유선
    • Nuclear Engineering and Technology
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    • v.4 no.3
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    • pp.229-240
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    • 1972
  • Radioisotopes and their related techniques have recently been applied for scientific conservation works of cultural property and resulted many excellent findings or conservation data which could never be achieved by means of other techniques. Radiocarbon dating have widely been applied for dating the antique of organic origin, whereas the determination of radioactive contents in metal, ceramics, environmental soil, and classical objects could be able to afford many useful informations on the age, genuiness, and archeological significances as it had been produced. Trace quantity of contents of each antique have successfully been analyzed by means of radioactivation analysis or radio active tracer techniques, which could afford important technical data and results for tile conservation of each object. Radiography have also been applied for detecting the internal defects of metal objects and furthermore $\beta$-and ${\gamma}$-ray radiography were proved to be effective for such thin material as textile, painting, and fibres. In this article the detailed principle and procedures of each technique were presented so that the society could be able to make efforts to familiarize all concerns with these modern trends of the conservation techniques of cultural property.

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Applications of Semi-Solid Forming and its Problems (반용융 성형공정의 응용 및 문제점)

  • 강충길
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.06a
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    • pp.135-147
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    • 1997
  • The production of light metal parts using aluminum is mainly performed by die casting and squeeze casting, which directly fabricate the required shape from the liquid state. However, die casting is subject to defects such as shrinkage porosity and air trapped when molten metal enters the cavity, whilst squeeze casting also has defects due to turbulent flow in the die cavity. Both diecasting and sqeeze casting have inhomogeneous mechanical property in terms of dendritic structure during solidification. Active research has been carried out on semi-solid processing, rather than on conventional process methods such as die casting, which involve various problems. Therefore in this paper, to introduce the fundamental technology for d e design, in die casting and forging process with semi-solid materials, relationship between stress and strain of semi-solid materials, and for producing parts die design has been proposed as parameters of globulization of the microstructure and gate shape. The prevention of various defects to produce sound parts are also introduced.

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A dragonfly inspired flapping wing actuated by electro active polymers

  • Mukherjee, Sujoy;Ganguli, Ranjan
    • Smart Structures and Systems
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    • v.6 no.7
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    • pp.867-887
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    • 2010
  • An energy-based variational approach is used for structural dynamic modeling of the IPMC (Ionic Polymer Metal Composites) flapping wing. Dynamic characteristics of the wing are analyzed using numerical simulations. Starting with the initial design, critical parameters which have influence on the performance of the wing are identified through parametric studies. An optimization study is performed to obtain improved flapping actuation of the IPMC wing. It is shown that the optimization algorithm leads to a flapping wing with dimensions similar to the dragonfly Aeshna Multicolor wing. An unsteady aerodynamic model based on modified strip theory is used to obtain the aerodynamic forces. It is found that the IPMC wing generates sufficient lift to support its own weight and carry a small payload. It is therefore a potential candidate for flapping wing of micro air vehicles.