• Title/Summary/Keyword: Activation method

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Isoconversional Cure Kinetics of Modified Urea-Formaldehyde Resins with Additives

  • Park, Byung-Dae
    • Current Research on Agriculture and Life Sciences
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    • v.30 no.1
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    • pp.41-50
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    • 2012
  • As a part of abating formaldehyde emission of urea-formaldehyde resin, this study was conducted to investigate the rmalcure kinetics of both neat and modified urea-formaldehyde resins using differential scanning calorimetry. Neat urea-formaldehyde resins with three different formaldehyde/urea mol ratios (1.4, 1.2 and 1.0) were modified by adding three different additives (sodium bisulfite, sodium hydrosulfite and acrylamide) at two different levels (1 and 3wt%). An isoconversional method at four different heating rates was employed to characterize thermal cure kinetics of these urea-formaldehyde resins to obtain activation energy ($E{\alpha}$) dependent on the degree of conversion (${\alpha}$). The $E{\alpha}$ values of neat urea-formaldehyde resins (formaldehyde/urea = 1.4 and 1.2) consistently changed as the ${\alpha}$ increased. Neat and modified urea-formaldehyde resins of these two F/U mol ratios did show a decrease of the $E{\alpha}$ at the final stage of the conversion while the $E{\alpha}$ of neat urea-formaldehyde resin (formaldehyde/urea = 1.0) increased as the ${\alpha}$ increased, indicating the presence of incomplete cure. However, the change of the $E{\alpha}$ values of all urea-formaldehyde resins was consistent to that of the Ea values. The isoconversional method indicated that thermal cure kinetics of neat and modified urea-formaldehyde resins showed a strong dependence on the resin viscosity as well as diffusion control reaction at the final stage of the conversion.

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The Fabrication of PVDF Organic Thin Films by Physical Vapor Deposition Method and Their Electrical Conductivity Phenomena (진공증착법을 이용한 PVDF 유기박막의 제조와 전기전도현상)

  • 임응춘;이덕출
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.217-225
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    • 1997
  • In this study, the PVDF organic thin film was fabricated by the physical vapor deposition method to be dry-process. The distance of heat source and substrate was 5[cm] and the temperature of substrate was 30[.deg. C], when the pressure had reached 2.0 x 10$^{-5}$ [Torr], the temperature of heat source was reached to 285[.deg. C] to heat at 6-8[.deg. C/min] rate, the shutter was opened and deposition was started. TG-DTA(Thermogravimetric-Differential Thermal Analysis) spectrum of PVDF pellets showed that endothermic peak arose at 170[.deg. C] and exothermic peak at 524[.deg. C], but that of thin PVDF film showed that endothermic peak arose at 145[.deg. C] and exothermic peak at 443[.deg C]. The current density was increased linearly with increasing voltage but increased nonlinearly with higher electric field than 250[kV/cm] and activation energy was about 0.667[eV] at the temperature of 30-90[.deg. C].

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Improvement in the Position and Speed Control of a Dc-Servo Motor Using Back Propagation Method (역전달 학습법(BP)을 이용한 직류 서보 전동기의 위치및 속도 제어 특성개선)

  • Kim, Cheol-Am;Lee, Eun-Chul;Kim, Soo-Hyun;Kim, Nak-Kyo;Nam, Moon-Hyun
    • Proceedings of the KIEE Conference
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    • 1992.07a
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    • pp.242-244
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    • 1992
  • Conventionally in the industrial control, PlD controller has been used because of its robustness, and nonlinear characteristic of a system under control. Although the PlD controller produce suitable parameter of the each system and also variable of PlD controller should be changed according to environment, disturbance, load. In this paper, the convergence and learning accuracy of the back-propagation(BP) method in neural network are investigated by analyzing the reason for decelerating the convergence of BP method. and examining the rapid deceleration of the convergence when the learning is executed on the part of sigmoid activation function with the very small first derivative. The modified logistic activation function it proposed by defining the convergence factor based on the analysis and applied to the position and speed control of a DC-servo motor. This paper revealed for experimental, a neural network and a PD controller combined off-line system using developed the position and speed characteristics of a DC-servo motor.

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Study on TSD Characteristics of LiF ( Mg , Cu , P ) Single Crystal (LiF ( Mg , Cu , P ) 단결정의 TSD 특성에 관한 연구)

  • 도시홍
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.26 no.1
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    • pp.8-13
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    • 1990
  • The microscopic relaxation parameters for the single crystal were measured by using thermally stimulated depolarization (TSD). Initial rise method, various heating rate method and total glow peak method were used for the determination of the activation energy and Debye relaxation time from TSD glow curves. Activation energy, pre-exponential factor and relaxation time for impurity-vacancy dipole reorientation were 0.55eV, 1.97$\times$10 super(-12) sec and 12.19sec in average, respectively. Dielectric dissipation factor for the crystal was calculated from the measured TSD glow curve, its value being about 3$\times$10 super(-2).

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Combustion Characteristics of Domestic Anthracite with High-Pressure TGA (가압열중량분석기를 이용한 국내무연탄의 연소특성 해석)

  • 류호정;한근희;진경태;이계봉;최정후
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.243-252
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    • 2001
  • Combustion characteristics of domestic anthracite coal were observed by high-pressure thermogravimetric analyzer with variation of pressure (1~16 atm) and heating rate (15, 20, $25^{\circ}C$/min) with non-iso-thermal method (temperature range : 25~100$0^{\circ}C$). Measured combustion reaction rate increased with increasing pressure. This result could be explained by the fact that the activation energy of coal combustion decreased with increasing pressure. Reaction order of coal combustion determined by Freeman and Carroll$^{[11]}$ method linearly increased from 1.04 to 1.30 and activation energy decreased from 47.37 to 14.42 Kcal/mol as pressure increased from 1 to 16 attn.

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The CO sensing properties of thick film gas sensor using Co3O4 powders prepared by hydrothermal reaction method (수열합성법으로 제조된 Co3O4 분말을 사용한후막 가스센서의 CO 감지 특성)

  • Kim, Kwang-Hee;Kim, Jeong-Gyoo;Park, Ki-Cheol
    • Journal of Sensor Science and Technology
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    • v.19 no.5
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    • pp.385-390
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    • 2010
  • CO sensing thick film gas sensors using $Co_3O_4$ powders prepared by hydrothermal reaction method, were fabricated, and their structural, electrical and CO gas sensing properties were investigated. The specific surface area of the $Co_3O_4$ powders obtained from BET analysis was about 79.0 $m^2/g$. XRD and SEM results show that the thick films heat-treated at $500^{\circ}C$ for 30 min after screen printing had the preferred orientation of (311) direction and the crystalline size was calculated to 221 $\AA$. The maximum activation energy obtained from the temperature-resistance characteristics was 3.11 eV in the temperature range of $290^{\circ}C$ to $310^{\circ}C$. The sensitivity to 1,000 ppm CO was about 150 %. The specific surface area, crystalline size, and maximum activation energy were increased significantly and the sensitivity for CO gas was improved largely.

Memory Access for High-Performance Hologram Generation Hardware (고속 홀로그램 생성 하드웨어를 위한 메모리 접근)

  • Lee, Yoon-Hyuk;Park, Sung-Ho;Seo, Young-Ho;Kim, Dong-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.18 no.2
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    • pp.335-344
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    • 2014
  • In this paper we analysis for in out signal by previous study and implement virtual master that generate CGH processor signals. Also, we propose memory address mapping. By constructing the system model of our method and by analyzing the latencies according to the memory access methods in a system including our model and several other models, the low-latency memory access method has been obtained. The proposed method is reduce number of activation in DRAM.

A study on the growth of undoped-lnSe single crystal by vertical Bridgman method and Zn diffusion in Sn-doped InSe (수직 Bridgman법에 의한 InSe 단결정의 성장 및 Sn이 첨가된 InSe에서 Zn의 확산에 잔한 연구)

  • 정회준;문동찬;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.464-467
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    • 1999
  • The undoped-InSe and Sn-doped InSe single crystals were grown by vertical Bridgman method and their properties were invesigated. The orientations and the crystallinites of these crystals were identified by X-ray diffraction(XRD), double crystal rocking curve(DCRC) and etch-pit density(EPD) measurements. From the Raman spectrum at room temperature, TO, LO modes and together with their overtones and combinations were observed. Optical properties were inves ated by PL at 12K and direct band gap of these crystals obtained from optical absorption spectrum. Compared with undo&-InSe, electrical properties of Sn-doped InSe were increased and the electrical conductivity type were n-type. But electrical properties along growth direction of crystals and radial direction of wafer showed nearly uniform distribution. The Zn diffusion mechanism in InSe could be explained by interstitial-substitutional and vacancy complex models and the activation energy of 1.15-3.01eV were needed for diffusion.fusion.

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Suboptimal video coding for machines method based on selective activation of in-loop filter

  • Ayoung Kim;Eun-Vin An;Soon-heung Jung;Hyon-Gon Choo;Jeongil Seo;Kwang-deok Seo
    • ETRI Journal
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    • v.46 no.3
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    • pp.538-549
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    • 2024
  • A conventional codec aims to increase the compression efficiency for transmission and storage while maintaining video quality. However, as the number of platforms using machine vision rapidly increases, a codec that increases the compression efficiency and maintains the accuracy of machine vision tasks must be devised. Hence, the Moving Picture Experts Group created a standardization process for video coding for machines (VCM) to reduce bitrates while maintaining the accuracy of machine vision tasks. In particular, in-loop filters have been developed for improving the subjective quality and machine vision task accuracy. However, the high computational complexity of in-loop filters limits the development of a high-performance VCM architecture. We analyze the effect of an in-loop filter on the VCM performance and propose a suboptimal VCM method based on the selective activation of in-loop filters. The proposed method reduces the computation time for video coding by approximately 5% when using the enhanced compression model and 2% when employing a Versatile Video Coding test model while maintaining the machine vision accuracy and compression efficiency of the VCM architecture.

A feasibility study on new stimulation method in fMRI language examinations using custom designed images (기능적 자기공명영상의 언어기능검사 시 image를 이용한 자극방법의 타당성 연구)

  • Choi, Kwan-Woo;Son, Soon-Yong;Jeong, Mi-Ae;Min, Jung-Whan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.11
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    • pp.5005-5011
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    • 2011
  • The purpose of this work is to know the validity of a new stimulation method in cognitive functional imaging using custom-designed images correspond to words or syllables improving the shortcomings of existing method using text. From March 2011 to May five Subjects in need of language related functional MRI scanning were selected and both of text stimulating method and image stimulating method sacanning were carried out three times each. Using 3.0T Philps MRI machine and Invivo Co's Eloquence system, data acquisition was performed with EPI-BOLD technique. Post processing was performed with SPM 99 while the activated signals were determined within 95 percent confidence level.The number of activation clusters and the activation ratio inside ROI were compared. As as result, all of the subject showed activation inside Broca area but it did not have statistical significance. In conclusion, the image sitimulation method has potential because image itself is a common means of recognition and it can be recognised easily even if there language barrier. This stimulation method can be applied to replacing the exising scanning method especially in the elderly, infants, foerigners who may not fully understand about the examination.