• Title/Summary/Keyword: Activation condition

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Oxidation Behavior of Ag-Cu-Tio Brazing Alloys (Ag-Cu-Ti 브레이징 합금의 산화거동)

  • 우지호;이동복;장희석;박상환
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.55-65
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    • 1998
  • The oxidation behavior of Ag-36.8a%Cu-7.4at%Ti alloy brazed on Si3N4 substrate was investigated at 400, 500 and 600$^{\circ}C$ in air. Under this experimental condition Si3N4 and Ag were not oxidized whereas Cu and Ti among the brazing alloy components were oxidizied obeying the parabolic oxidation rate law. The activation energy of oxidation was found to be 80kj/ mol which was smaller than that of pure Cu owing to the presence of oxygen active element of Ti. The outer oxide scale formed from the initial oxidation state was always composed of Cu oxides which were known to be growing by the outward diffusion of Cu ions. As the oxidation progressed the concentration gradient occurred due to the continuous consumption of Cu as Cu oxides and consequently build-up of an Ag-enriched layer below the Cu oxides resulted in the formation of multiple oxide scales composed of Cu oxide (CuO) /Ag-enriched layer/Cu oxide (Cu2O) /Ag-enriched layer. Also the inward diffusing of oxygen through Cu oxide and Ag-enriched layers led to the formation of internal oxides of TiO2.

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Leaching of copper and silver from ground mobile phone printed circuit boards using nitric acid (핸드폰 기판(基板)으로부터 구리와 은의 질산(窒酸) 침출(浸出) 연구(硏究))

  • Le, Long Hoang;Yoo, Kyong-Keun;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.17 no.3
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    • pp.48-55
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    • 2008
  • Leaching of copper and silver from mobile phone PCBs(printed circuit boards) with nitric acid was performed to investigate the effects of nitric acid concentrations, leaching temperatures, agitation speeds, and pulp densities on the leaching behaviors of Cu and Ag. The leaching rate considerably increased with increasing acid concentration and temperature. The leaching ratios of Cu and Ag were found to be 96.4% and 96.5%, respectively, under the optimum condition; at $80^{\circ}C$ with 2mol/L $HNO_3$ and 120g/L in pulp density within 39minutes. The kinetic parameters were determined based on the shrinking core model with reaction control corresponding to small particles. The activation energies for the leaching of copper and silver were found to be 45.5kJ/mol and 60.5kJ/mol at $35{\sim}80^{\circ}C$ with 2mol/L $HNO_3$, respectively.

Basic Properties of Concrete with Ultrafine-Blaine Air Cooling Slag as Admixture (초미분말 서냉 슬래그를 혼화재로 사용한 콘크리트의 기초적 특성)

  • Heo, Jae-Hyuk;Jeong, Sung-Wook;Her, Jae-Won;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.2
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    • pp.77-83
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    • 2009
  • In this study, a test has been carried out to solve the problem with ground granulated blast-furnace slag, low early strength & lack of supply and to find out a way to use as concrete admixture of the ultrafine blaine air cooling slag which is all disposed as the by product of air cooling slag and its test was conducted to the replacement rate of ultrafine blaine air cooling slag & mixing condition of every concrete admixtures by type for the purpose of obtaining later a basic data for practical use of the cement that used ultrafine blaine air cooling slag by conducting comparative analysis. If ultrafine-blaine air cooling slag is used to the concrete following the results, a high efficiency water reducing agent won't be needed much for flow acquisition due to a high increase in flow, and the stripping time of concrete form will be shortened thanks to the acquisition of early strength, And though, it has the problems with long term strength which is similar or a little lower than the 3 types of ground granulated blast-furnace slag, it's still applicable as the substitute materials for 3 types of ground granulated blast-furnace slag at 10, 15% replacement rate of ultrafine-blaine air cooling slag, at which it shows higher activation index than 3 types of ground granulated blast-furnace slag.

Study on the Performance Evaluation of the Explosive Bolt that has been Natural Aging (자연 노화된 폭발볼트의 성능 평가에 관한 연구)

  • Kim, Dongjin;Jeong, Donghee;Lee, Yeungjo;Lee, Youngwoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.84-90
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    • 2017
  • Explosive bolt is coupled in a variety of guided weapons and space projectiles, to perform the separation function. Thus, the role of the explosive bolt in guided weapons systems is very important, as it can cause failure of the entire system in the case of mission failure. For this reason, the design life prediction for explosive bolt is highly and frequently required recently, but its accurate prediction method has not been presented. In order to apply the existing accelerated aging process, we should know the activation energy and the acceleration factor of the explosive bolt. Since the information required for accelerated aging is not presently secured, it is difficult to predict the design life of explosive. Thus, in the present study, we have evaluated the performance of actual explosive bolts in the condition of natural aging over 10 years in order to present a minimum design life.

GABAA Receptor- and Non-NMDA Glutamate Receptor-Mediated Actions of Korean Red Ginseng Extract on the Gonadotropin Releasing Hormone Neurons

  • Cho, Dong-Hyu;Bhattarai, Janardhan Prasad;Han, Seong-Kyu
    • Journal of Ginseng Research
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    • v.36 no.1
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    • pp.47-54
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    • 2012
  • Korean red ginseng (KRG) has been used worldwide as a traditional medicine for the treatment of various reproductive diseases. Gonadotropin releasing hormone (GnRH) neurons are the fundamental regulators of pulsatile release of gonadotropin required for fertility. In this study, an extract of KRG (KRGE) was applied to GnRH neurons to identify the receptors activated by KRGE. The brain slice patch clamp technique in whole cell and perforated patch was used to clarify the effect of KRGE on the membrane currents and membrane potentials of GnRH neurons. Application of KRGE (3 ${\mu}g$/${\mu}L$) under whole cell patch induced remarkable inward currents (56.17${\pm}$7.45 pA, n=25) and depolarization (12.91${\pm}$3.80 mV, n=4) in GnRH neurons under high $Cl^-$ pipette solution condition. These inward currents were not only reproducible, but also concentration dependent. In addition, inward currents and depolarization induced by KRGE persisted in the presence of the voltage gated $Na^+$ channel blocker tetrodotoxin (TTX), suggesting that the responses by KRGE were postsynaptic events. Application of KRGE under the gramicidin perforated patch induced depolarization in the presence of TTX suggesting its physiological significance on GnRH response. Further, the KRGE-induced inward currents were partially blocked by 6-cyano-7-nitroquinoxaline-2,3-dione (CNQX; non-NMDA glutamate receptor antagonist, 10 ${\mu}M$) or picrotoxin (PIC; $GABA_A$ receptor antagonist, 50 ${\mu}M$), and almost blocked by PIC and CNQX mixture. Taken together, these results suggest that KRGE contains ingredients with possible GABA and non-NMDA glutamate receptor mimetic activity, and may play an important role in the endocrine function of reproductive physiology, via activation of $GABA_A$ and non-NMDA glutamate receptors in GnRH neurons.

Synthesis and crystallization of solder glass for electronic package (전자 Package 봉착유리의 합성과 결정화)

  • Kyung Nam Choi;Byoung Chan Kim;Byoung Woo Kim;Hyung Suk Kim;Hee Chan Park;Myung Mo Son;Heon Soo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.6
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    • pp.407-411
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    • 2000
  • Low-temperature solder glass for use in electronic package was experimentally prepared and its crystallization behavior was investigated using differential thermal analysis (DTA) under nonisothermal condition. The composition of the solder glass was determined from PbO-ZnO-$B_2$$O_3$-$TiO_2$ glasses containing small amounts of CaO, $SiO_2$$A1_2$$O_3$ and $P_2$$O_5$. The crystallization exotherm corresponding to the formation of lead titanate (PbTiO$_3$) was observed. The crystallization of $PbTiO_3$was a three-dimensional process with the average activation energy of 223$\pm$3 kJ/mol for the crystallization from the glass matrix.

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Characterization of energetic meterials using thermal calorimetry (등전환 방법을 이용한 고에너지 물질의 노화 효과 예측)

  • Kim, Yoocheon;Oh, Juyoung;Ambekar, Aniruda;Yoh, Jai-ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.547-553
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    • 2017
  • Thermal analysis of three energetic materials used in pyroelectric device was performed using Differential Scanning Calorimetry (DSC). The theoretical method for extracting the reaction rate equation of energetic materials using DSC experimental data is proposed and the reaction rate extraction is performed. The results of the DSC were analyzed by the conversion method such as Friedman. Activation energy and frequency factor according to mass fraction were extracted to complete the reaction rate equation. The extracted reaction rate equation has a form that represents the entire chemical reaction process, not the assumption that the chemical reaction process of the high energy material is a main step in several stages. It has considerable advantages in terms of theoretical and accuracy as compared with the chemical reaction rate form extracted through conventional thermal analysis experiments. Using the derived reaction rate equation, we predicted the performance change of three energetic materials operating on actual storage condition over 20 years.

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Effects of Luteolin on Fetal Bovine Serum-induced Events in Cultured Rat Vascular Smooth Muscle Cells (소태아혈청으로 유도된 흰쥐 혈관평활근세포의 luteolin 효과)

  • Lim, Yong
    • Journal of Life Science
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    • v.22 no.12
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    • pp.1595-1599
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    • 2012
  • Cell cycle activation and progression in vascular proliferative disease represent potent therapeutic targets. Luteolin, which occurs as glycosylated forms in celery, green pepper, perilla leaf, and camomile tea, has demonstrated antimutagenic, antitumorigenic, antioxidant, and antiinflammatory properties. In this study, we investigated the effect of luteolin on the proliferation of primary cultured rat aortic vascular smooth muscle cells induced by 5% fetal bovine serum. Luteolin at concentrations of 5, 20, and $50{\mu}M$ significantly inhibited this proliferation by 29.6, 50.8, and 83.1%, respectively. The incorporation of $[^3H]$-thymidine into DNA was also inhibited by 25.8, 57.6, and 81.0%, respectively. Flow cytometry analysis of DNA content revealed that FBS-inducible cell cycle progression was blocked by luteolin. Luteolin showed no cytotoxicity in VSMCs in this experimental condition according to WST-1 assays. Luteolin may represent a potential anti-proliferative agent for treatment of angioplasty restenosis and atherosclerosis.

Effect of Shoe Heel Height on Vastus Medialis and Vastus Lateralis Electromyographic Activity During Stair Ascending and Descending (신발 뒤굽 높이가 계단 올라가기 및 내려오기 동안 내측광근과 외측광근의 근 활성도에 미치는 영향)

  • Oh, Duck-Won;Kim, Suhn-Yeop
    • Physical Therapy Korea
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    • v.16 no.3
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    • pp.24-31
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    • 2009
  • This study aimed to investigate the effect of differing heel heights on the electromyographic (EMG) activity in vastus medialis (VM) and vastus lateralis (VL) during stair ascending and descending activities. A total of 26 healthy women volunteered to perform stair-ascending and stair-descending tasks with 3 heel heights: barefoot, 3 cm, and 7 cm. The EMG activities of the VM and VL were recorded during the tasks. During the stair ascending and descending tasks, the EMG activities of both VM and VL significantly changed with differing the heel heights (p<.05). Moreover, the EMG activities of VM and VL during the stair ascending task were significantly higher than the corresponding values during the stair-descending task (p<.05). However, there were no significant differences between the VM:VL EMG ratios for the 3 heel heights (p>.05). The VM:VL EMG ratios between the 2 tasks differed significantly in the 7 cm high heel condition (p<.05). Despite an increase in the EMG activities in both VM and VL during stair ascending and descending tasks, there was no change in the relative EMG intensities of VM and VL, which was measured by calculating the VM:VL ratio this result indicates that no VM:VL imbalances were elicited. The relative EMG intensities of VM and VL during stair descent were lower than the corresponding values during the ascent, suggesting that VM and VL may show an imbalance in the eccentric activation during the weight-acceptance phase. This study provides useful information that will facilitate future research on how heel height affects muscle activity around the knee joint.

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An Analysis on the Advancement of Korean Energy Technology Innovation System (한국 에너지기술혁신체제 분석 및 개선방안 연구)

  • Park, Jung-Gu;Yoon, Seong-Pil;Park, Sung-Hwan
    • Journal of Energy Engineering
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    • v.22 no.3
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    • pp.312-325
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    • 2013
  • This article analyzes the lock-in factors and their advancement direction of Korean energy innovation system(EIS), using case-study methodology. As the lock-in factors, which have been structural and complicated ones in the developing process of Korean EIS, are postulated government policies, market, industrial network, and demand condition. The lock-in phenomena result from connecting and conflicting incompletely among government policies, competing and controlling oligopolistically in market, constructing insufficiently in intra-industrial value-chain, and lowering in demand efficiency. To cope with these lock-in structure, connection among government policies, activation in market competition, coordination of industrial structure for added values, and uprading in energy efficiency are needed.