• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.947-953
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• 2012

In this study we investigated the manufacturing method for the activated carbon using the char from the pyrolysis of waste tire. The physical activation method using the steam in the fixed-bed quartz reactor was used for preparation of activated carbon. The primary experiment parameters are the activation temperature, activation time, heating rate, and the injection quantity of active agent. From the results of pore distribution of activated carbon, the micropore which was made in $850^{\circ}C$ of activation temperature, $5^{\circ}C$/min of heating rate, and 3 hours of activation time was developed in biggest quantity, and mesopore and macropore were developed in the biggest quantity too. The optimum conditions for producing the activated carbon using the pyrolysis residue were $850^{\circ}C$ of activation temperature, 3 hours of activation time, $5^{\circ}C$/min of heating rate, and 3 g $H_2O/char-g{\cdot}hr$ of active agent through this study. The produced activated carbon in these conditions showed that the potentiality of utilization as activated carbon because the BET specific surface area was $517.6m^2/g$ and total pore volume was $0.648cm^3/g$.

• Resources Recycling
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• v.15 no.2 s.70
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• pp.50-57
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• 2006

Production of activated carbon from woody fish parking cases has been studied using waste sulfuric acid as an activating agent for the purpose or promoted recycling of woody fishing port wastes. The adsorption capacity of produced activated carbon was observed to increase with activation temperature and reached its maximum at ca. $650^{\circ}C$ under the experimental conditions. However, the adsorption capacity of activated carbon became deteriorated above this temperature due to the thermal degeneration of its structure. Optimal activation time was found to be about 120 minutes and 1:3 weight ratio of raw material and activating agent was appropriate for increased adsorption capacity of activated carbon under the conditions of $550^{\circ}C$ and 60 minutes of activation time. Regarding the effect of the concentration of activating agent on activation, ca. 1.2 M of sulfuric acid was observed to be proper for an optimal activation or raw material. Comparison of the activation power of sulfuric acid with nitric acid showed that sulfuric acid was superior to nitric acid, however, with regard to the yield of activated carbon there was no significant difference between the two activating agents. The degree of dispersion of carbon particles was shown to be relatively high in neutral condition and the produced activated carbon was considered to be effectively employed for the treatment of metal ions in wastewater due to its negative surface charge in aqueous condition.

• Physical Therapy Korea
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• v.19 no.2
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• pp.29-38
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• 2012

This study aimed to identify the asymmetry observed in the electromyography (EMG) activity patterns of selected trunk and thigh muscles between the affected and unaffected sides during the sit-to-stand movement in ambulatory patients with post-stroke hemiparesis. This study included 20 patients with post-stroke hemiparesis. The differences between stroke fast walkers (${\geq}8m/s$, 11 subjects) and stroke slow walkers (<8 m/s, 9 subjects) were compared. The activation magnitude and onset time of the multifidus, lumbar erector spinae, hamstrings, and quadriceps during the sit-to-stand movement were recorded through surface EMG. Moreover, the EMG activation magnitude and onset time ratios of each bilateral corresponding muscle from the trunk and leg were measured by dividing the relevant values of the unaffected side by those of the affected side. In all the subjects, the activation magnitudes of the multifidus, hamstring, and quadriceps on the affected side significantly decreased compared to those on the unaffected side (p<.05). The onset time of muscle activity in the affected side was markedly delayed for the multifidus and quadriceps during the task (p<.05). The activation magnitude ratios of the quadriceps were markedly decreased in the stroke slow walkers as compared to those in the stroke fast walkers. These findings indicate that the asymmetry in the multifidus, hamstring, and quadriceps muscle activation patterns in patients with post-stroke hemiparesis may be due to the excessive muscle activation in the unaffected side to compensate for the weakened muscle activity in the affected side. Our findings may provide researchers and clinicians with information that can be useful in rehabilitation therapy.

• Resources Recycling
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• v.12 no.3
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• pp.13-24
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• 2003

The production characteristics of activated carbon from waste walnut shell have been investigated by taking activation temperature, activation time, amount of activating agent, and kind of activating agent as the major influential factors. The adsorption capacity of the activated carbon which was produced using phosphoric acid as the activating agent increased with activation temperature and showed its greatest value at about $550^{\circ}C$. Yield for activated carbon was observed to decrease continuously as the activation temperature was raised. The optimal activation time for the highest adsorption capacity was found to be about 2 hr, and as the activation time increased the yield for activated carbon was showed to decrease continuously. The increase in the amount of activating agent resulted in the increase of the yield for activated carbon, however, excessive amount of activating agent deteriorated its adsorption capacity reversely. The variations of the microstructure of activated carbon observed by SEM with several influential factors, correlated very well with its changes in the adsorbability with the same factors and the kind of activating agent was found to play an important role in the determination of the adsorption capacity of activated carbon. To investigate the adsorption characteristics of the produced activated carbon, the adsorption reactions of $Cu^{2+}$ ion were examined using the produced activated carbon as the adsorbent. In general, the kinetics of the adsorption of $Cu^{2+}$ ion was observed to follow a 2nd-order reaction and the rate constant for adsorption reaction increased as the initial concentration of adsorbate was diminished. The equilibrium adsorption of $Cu^{2+}$ was explained well with Freundlich model and its adsorption reaction was found to be endothermic. The activation energy for adsorption was calculated to be 13.07 kcal/mol, which implied that the adsorption reaction was very irreversible, and several thermodynamic parameters of adsorption reaction were estimated using van't. Hoff equation and thermodynamic relationships.

• Journal of the Korean Chemical Society
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• v.56 no.1
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• pp.20-27
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• 2012

Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density ($\rho$) and refractive index ($n_D$) are also measured. These parameters are used to determine excess dielectric constant, excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.

• Journal of the Korean Wood Science and Technology
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• v.16 no.3
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• pp.5-16
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• 1988

This experiment was executed to investigate the effect of activation of veneer surface by oxidizing agents, hydrogen peroxide and nitric acid, on bonding characteristics of Malas(Homalium foetidum Benth) plywood, in which the effects of these oxidizing agents amount, pretreatment time, and pressing time and temperatue on shear strength of the plywood were examined and discussed. In this research the activation of veneer surface by oxidants was effective in raising shear strength but the difference in shear strength was not observed between hydrogen peroxide and nitric acid treatment. Hydrogen peroxide treatment, however, seemed to be more profitable to industrial application because of its lower concentration and easier handling than nitric acid. The bonding method by lignin-phenol adhesive through surface activation revealed inferior shear strength to phenol- and urea-formaldehyde adhesive but superior water resistance to urea-formaldehyde adhesive and this bonding method, in addition, have the advantage of lower cost compared with phenol-formaldehyde adhesive, Therefore, this bonding method by lignin-phenol adhesive through surface activation seemed to economical in manufacturing of water-resistant wood panel materials in future.

• Journal of Biomedical Engineering Research
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• v.18 no.4
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• pp.413-420
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• 1997

In this paper, we analyzed the contraction patterns of active elbow muscles during isometric, concentric and eccentric contraction. The analysis parameters consist of frequency domain parameters (mean frequency, median frequency, peak frequency, peak power, skewness, kurtosis) and time domain paraseters (zero crossing, positive maxima, integrated EMG). The results of this study were as follows; The BR/BB of isometric contraction appeared to be Venter as the elbow joint was more extended. The BR /BB during concentric and eccentric contraction tended to increase with more extension of the elbow joint angle, but there was no significant difference between concentric and eccentric contraction. Further, the EMG power spectrum due to the type of contraction were different betwen eccentric and concentric contraction. According to the results, it was found that the activation pattern in elbow flexor muscles was different during three different muscle contraction pattern. Therefore, elbow flexor muscles should not be considered a single functioning unit. Especially, at the time domain analysis, IEMG is a dominant parameter for analysis of activation patterns, and the skewness kurtosis can be useful parameters in functional recognition for prosthesis control purpose.

• Journal of Magnetics
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• v.8 no.3
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• pp.108-112
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• 2003

We report the experimental finding that there exists a transition of magnetization reversal process with varying the applied field in Co/Pd multilayer. We have measured the wall-motion speed V and the nucleation rate R during magnetization reversal via time-resolved direct domain observation, where the magnetization reversal process of Co/Pd multilayer is found to take a transition from thermal activation process to viscous process at the critical field of about 1.87 H$\_$C/ (coercivity). In the thermal activation regime, we find that the field dependences of two activation volumes for the wall-motion process and the nucleation process are different with each other, which reveals that the wall-motion and nucleation experience completely different interactions. In the viscous regime, we find that the wall-mobility is much smaller than a typical value for the sandwiched Co films, which implies that the Co/Pd interfaces in multilayer substantially contribute to the dynamic dissipation.

• Fire Science and Engineering
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• v.18 no.3
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• pp.1-8
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• 2004

As a predominant active fire suppression method, closed-type sprinkler systems are used for the purpose of fire control and suppression at the nuclear power plants as well as the industrial facilities. It goes without saying that the proper selection of the system guarantees the adequate actuation of the thermal device. Consequently, the appropriate evaluation should be executed for the thermal behavior with the theoretical and empirical approach. For this purpose, the comparison of activation time for the fusible-link type sprinkler head with the simplified fire case and t-square fire growth case was evaluated. At this paper, the comparison output was presented with the tendency of thermal behavior. In addition, we issued some technical comments for the most appropriate equation in case of the estimation of the sprinkler head activation time. We also raised some idea that should be incorporated for the usage of the t-square equation for the realistic application in the field of the performance-base fire protection approach.

• Journal of Embryo Transfer
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• v.15 no.1
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• pp.23-31
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• 2000

This study was conducted to investigate the effects of quiescent treatment of donor cells and activation treatment time of recipient cytoplasm on nuclear remodeling and in vitro development of somatic cell-cloned bovine embryos. Serum starved, confluent and nonquiescent cycling adult skin cells were teansferred into enucleated oocytes. Nuclear transfer oocytes were activated at 30 min, 1 and 2 hrs after electrofusion. Some nuclear transfer embryos(23% to 35%) extruded a polar body, which was not affected by quiescent treatment of donor cells and activiation time of recipient cytoplasm. About 68% of nuclear transfer embryos fused with a serum starved cells has a chromatin clump, but which was not different from embryos fused with confluent(51%) and nonquiescent(47%) cells. The proportion of embryos with a single chromatin clump was sightly increased when nuclear transfer embryos were activated within 30 min after fusion(69%) compared to those were activated at 1 and 2 hrs after fusion, but there was not significantly different. Development rates to the blastocyst stage were 8.6% and 15.9% when serum starved and confluent cells were transferred, which were higher than that of control group. Developmental rate to the blastocyst stage was higher in embryos were activated within 30 min after fusion (17.3%) compared to those of embryos were activated at 1 and 2 hrs after fusion (P<0.05). From the present result, it is suggested that quiescent treatment of donor cells and activation time of recipient cytoplasm can affect the in vitro development. Quiescent plasm activation within 30 min after fusion could increase the number of embryos with a normal chromation structure, which results in increased in vitro development.