• Title/Summary/Keyword: Activated material

Search Result 745, Processing Time 0.026 seconds

Effects of surface properties and solution ph on the pollutants removal of K-PAC (K-PAC의 오염물질 제거에 대한 용액의 pH와 표면 특성의 효과)

  • Oh, Won-Chun;Bae, Jang-Soon
    • Analytical Science and Technology
    • /
    • v.18 no.5
    • /
    • pp.436-443
    • /
    • 2005
  • A study of physical properties and their application using K-powdered activated carbon system followed powdered carbon dispersion was carried out at laboratory. scale. Two types of K-powdered activated carbon for the dispersion have been used in this study to investigate the catalytic removal efficiency of pollutants from the wastewater. From the surface properties obtained for carbon samples treated with aqueous solutions containing potassium salts, main investigations were subjected to isotherm shape, SEM, EDX and surface functional groups. K-powdered activated carbons were dispersed to wastewater with pH variation to investigate the removal efficiency for the color, COD, T-N and T-P. From these removal results of the piggery waste using K-powdered activated carbon, satisfactory removal performance in the region of pH 6~8 was achieved. The excellent effects for the dispersion of the K-powdered activated carbon were proved by the above mentioned properties of the material for adsorption and trapping of organics, and catalytic effects.

Evaluation of Tubular Type Non-woven Fabric Filter for Solid-liquid Separation in Activated Sludge Reactor (활성슬러지조내 부직포 여재 관형필터의 고액분리 특성 평가)

  • Seo, Gyu-Tae;Lee, Teak-Soon;Park, Young-Mi
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.30 no.2
    • /
    • pp.234-238
    • /
    • 2008
  • Coarse pore filter could be an alternative of membrane for solid-liquid separation in an activated sludge reactor because of inexpensive cost of the filter material and high flux at low filtration pressure. However such filter module has much less specific filtration area compared to the membrane. Therefore a certain effort is required to increase the specific filtration area in the module design of such coarse pore filter for solid-liquid separation in an activated sludge reactor. In this study, tubular type coarse pore filter was designed at various diameter and configuration. The filtration performance was investigated to separate solid in the activated sludge reactor for domestic wastewater treatment. Tubular type coarse pore filter module could be successfully applicable to solid separation in the activated sludge reactor. The design parameters were the tube diameter of 10mm and vertical installation. Smaller diameter of the tube caused faster increase of the filtration pressure because of the hydraulic head loss in the tube channel.

Effect of Chemically Treated / Untreated Carbon Cloth: Potential Use as Electrode Materials in the Capacitive Deionization Process of Desalination of Aqueous Salt Solution

  • Thamilselvan, Annadurai;Nesaraj, A Samson;Noel, Michael;James, E.J.
    • Journal of Electrochemical Science and Technology
    • /
    • v.6 no.4
    • /
    • pp.139-145
    • /
    • 2015
  • Capacitive deionization (CDI) process is a novel approach for desalination of an aqueous salt solution. In the present study, an activated carbon cloth (ACC) is proposed as effective electrode material. Initially the carbon cloth was activated in 1 M and 8 M HNO3 for 9 hours at room temperature. The untreated and chemically activated carbon cloth (ACC) electrode materials were subjected to BET surface area measurements in order to get information about their specific surface area, average pore size, total pore volume and micropore area. The above materials were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) also. The electrochemical studies for the electrodes were done using cyclic voltammetry (CV) in 0.1 M Na2SO4 medium. From the studies, it was found that resistivity of the activated carbon cloth electrodes (treated in 1 M and 8 M HNO3) was decreased significantly by the chemical oxidation in nitric acid at room temperature and its capacitance was found to be 90 F/g (1 M HNO3) and 154 F/g (8 M HNO3) respectively in 0.1 M Na2SO4 solution. The capacitive deionization behavior of a single cell CDI with activated carbon cloth electrodes was also studied and reported in this work.

Performance of Electric Double Layers Capacitor Using Activated Carbon Materials from Rice Husk as Electrodes

  • Nguyen, Tuan Dung;Ryu, Jae Kyung;Bramhe, Sachin N.;Kim, Taik-Nam
    • Korean Journal of Materials Research
    • /
    • v.23 no.11
    • /
    • pp.643-648
    • /
    • 2013
  • Activated carbon (AC) was synthesized from rice husks using the chemical activation method with KOH, NaOH, a combination of (NaOH + $Na_2CO_3$), and a combination of (KOH + $K_2CO_3$) as the chemical activating reagents. The activated carbon with the highest surface area (around $2000m^2/g$) and high porosity, which allows the absorption of a large number of ions, was applied as electrode material in electric double layer capacitors (EDLCs). The AC for EDLC electrodes is required to have a high surface area and an optimal pore size distribution; these are important to attain high specific capacitance of the EDLC electrodes. The electrodes were fabricated by compounding the rice husk activated carbons with super-P and mixed with polyvinylidene difluoride (PVDF) at a weight ratio of 83:10:7. AC electrodes and nickel foams were assembled with potassium hydroxide (KOH) solution as the electrolyte. Electrochemical measurements were carried out with a three electrode cell using 6 M KOH as electrolyte and Hg/HgO as the reference electrode. The specific capacitance strongly depends on the pore structure; the highest specific capacitance was 179 F/g, obtained for the AC with the highest specific surface area. Additionally, different activation times, levels of heating, and chemical reagents were used to compare and determine the optimal parameters for obtaining high surface area of the activated carbon.

Comparison of Bacterial Regrowth on Plant- and Coal-based Granular Activated Carbon (식물계활성탄과 석탄계활성탄에서의 세균재생장 비교)

  • 이동근;박성주;하배진;하종명;이상현;이재화
    • KSBB Journal
    • /
    • v.19 no.2
    • /
    • pp.104-109
    • /
    • 2004
  • Activated carbon has been used in water treatment, because they strongly adsorb organic material including contaminant. Water purifier usually use activated carbon, and bacterial regrowth on that could induce many problems. Model columns, packed with coal- and plant-based granular activated carbon (GAC), were operated with rechlorinated tap water to compare the degree of bacterial regrowth on different GACs. GAC columns decreased the concentration of total organic carbon and chlorine, while they are not good for the decrease of ions. Breakthrough of bacteria were occurred after eight days of operation, and reached 1.1 ${\times}$ 10$^3$ CFU/mL on coal based GAC and 6.2 ${\times}$ 10$^2$ CFU/mL on coconut based one. Bacterial activities on GAC were between 15.35 ∼ 29.06 $\mu\textrm{g}$ INT-formazan/g-GAC/h. Bacterial concentration and activities were higher in coal based GAC than coconut based one. Bacterial regrowth on GAC was clarified and regrowth effect of coal-based GAC was higher than that of coconut-based one.

Adsorption Characteristics Analysis of Trimethoprim in Aqueous Solution by Magnetic Activated Carbon Prepared from Waste Citrus Peel Using Box-Behnken Design (Box-Behnken Design을 이용한 수용액 중의 Trimethoprim에 대한 폐감귤박 자성활성탄의 흡착 특성)

  • Lee, Chang-Han;Lee, Min-Gyu;Hu, Chul-Goo;Kam, Sang-Kyu
    • Journal of Environmental Science International
    • /
    • v.31 no.8
    • /
    • pp.691-706
    • /
    • 2022
  • Magnetic activated carbon was prepared by adding a magnetic material to activated carbon that had been prepared from waste citrus peel in Jeju. The adsorption characteristics of an aqueous solution of the antibiotic trimethoprim (TMP) were investigated using the magnetic activated carbon, as an adsorbent, and response surface methodology (RSM). Batch experiments were carried out according to a four-factor Box-Behnken experimental design affecting TMP adsorption with their input parameters (TMP concentration: 50~150 mg/L; pH: 4~10; temperature: 293~323 K; adsorbent dose: 0.05~0.15 g). The significance of the independent variables and their interaction was assessed by ANOVA and t-test statistical techniques. Statistical results showed that TMP concentration was the most effective parameter, compared with others. The adsorption process can be well described by the pseudo-second-order kinetic model. The experimental isotherm data followed the Langmuir isotherm model. The maximum adsorption capacities of TMP, estimated with the Langmuir isotherm model were 115.9-130.5 mg/g at 293-323 K. Also, both the thermodynamic parameters, ΔH and ΔG, have both positive values, indicating that the adsorption of TMP by the magnetic activated carbon is an endothermic reaction and proceeds via an involuntary process.

Study on Explosion Characteristics and Thermal Stability of Activated Carbon (활성탄의 폭발특성과 열안정성에 관한 연구)

  • Yi-Rac Choi;Dong-Hyun Seo;Ou-Sup Han;Hyo-Geun Cha
    • Journal of the Korean Institute of Gas
    • /
    • v.27 no.3
    • /
    • pp.134-140
    • /
    • 2023
  • Activated carbon is a carbonaceous material mainly used as a gaseous or liquid adsorbent. As fire-related accidents occur consistently due to the accumulation of heat of adsorption and oxidation of volatile organic compounds, the explosive characteristics and thermal stability of powdered and granular activated carbon made from coal and coconut shells were evaluated. As a result of the particle size analysis, the powdered activated carbon was in the particle size range (0.4~3) ㎛, and thermal properties such as exothermic onset temperature and decomposition behavior were analyzed using a differential scanning calorimetry and a thermogravimetric analysis. As a result of the evaluation of the explosion hazards for dust, both coal-based and coconut-based powdered activated carbon are classified as St1 class with weak explosion, but this is a relative and does not mean that the explosion hazards is absolutely low. Therefore, it is necessary to establish countermeasures for reducing the damage.

Experimental study on chemical activation of recycled powder as a cementitious material in mine paste backfilling

  • Liu, Yin;Lu, Chang;Zhang, Haoqiang;Li, Jinping
    • Environmental Engineering Research
    • /
    • v.21 no.4
    • /
    • pp.341-349
    • /
    • 2016
  • To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

Effect of Composite Conductor on Characteristics of Electric Double Layer Capacitor (전기이중층 커패시터의 특성에 미치는 혼성 도전재의 영향)

  • 김익준;이선영;문성인
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.1
    • /
    • pp.107-111
    • /
    • 2004
  • This work describes the effect of composite conductor on the characteristics of electric double layer capacitor. Test cell, which was fabricated with conducting composite consisted of 80% of SPB and 20% of VGCF, exhibits the better tate capability and the lower resistance than those of the cells fabricated with single electronic conductor. These enhanced properties could be related with the decrease of contact resistance between the activated carbon powders.