• Title/Summary/Keyword: Acid resistance

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Evaluation on the Corrosion Resistance of Three Types of Galvanizing Steels in 1% H2SO4 Solution

  • Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Jeong, Jae-Hyun;Baek, Tae-Sil
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.245-251
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    • 2016
  • Galvanizing method has been extensively used to the numerous constructional steels such as a guard rail of high way, various types of structural steel for ship building and various types of steels for the industrial fields etc.. However, the galvanized structures would be inevitably corroded rapidly with increasing exposed time because an acid rain due to environmental contamination has been much dropped more and more. Therefore, it has been made an effort to improve the corrosion resistance of the galvanizing film through various methods. In this study, comparison evaluation on the corrosion resistance of three types of the samples, that is, the hot dip galvanizing with pure zinc(GI), the hot dip galvanizing of alloy bath with zinc and aluminum(GL) and the pure zinc galvanizing steel immersed again to chromate treatment bath(Chro.)were investigated using electrochemical methods in 1% $H_2SO_4$ solution. The Chro. and GI samples exhibited the highest and lowest corrosion resistance respectively in 1% $H_2SO_4$ solution, however, the GI sample revealed the highest impedance at 0.01 Hz due to its high resistance polarization caused by corrosion products deposited on the surface, while Chro. sample exhibited the lowest impedance at 0.01 Hz because of little corrosion products on the surface. Consequently, it is suggested that the chromate treated steel has a better corrosion resistance in acid environment compared to pure galvanizing(GI) or galvalume(GL) steels.

The Effects of Long-Term, Low-Level Exposure to Monocyclic Aromatic Hydrocarbons on Worker's Insulin Resistance

  • Won, Yong-Lim;Ko, Yong;Heo, Kyung-Hwa;Ko, Kyung-Sun;Lee, Mi-Young;Kim, Ki-Woong
    • Safety and Health at Work
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    • v.2 no.4
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    • pp.365-374
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    • 2011
  • Objectives: This study was designed to investigate whether long-term, low-level exposure to monocyclic aromatic hydrocarbons (MAHs) induced insulin resistance. Methods: The subjects were 110 male workers who were occupationally exposed to styrene, toluene, and xylene. One hundred and ten age-matched male workers who had never been occupationally exposed to organic solvents were selected as a control group. Cytokines, which have played a key role in the pathogenesis of insulin resistance, and oxidative stress indices were measured. Assessment of exposure to MAHs was performed by measuring their ambient levels and their urinary metabolites in exposed workers, and the resulting parameters between the exposed group and non-exposed control groups were compared. Results: There was no significant difference in general characteristics and anthropometric parameters between the two groups; however, total cholesterol, fasting glucose, fasting insulin, and homeostasis model assessment of insulin resistance levels were significantly higher in the exposed group. Phenylglyoxylic acid levels showed significant association with tumor necrosis factor-${\alpha}$, total oxidative status, and oxidative stress index via multiple linear regression analysis. Further, there was a negative correlation between methylhippuric acid levels and total anti-oxidative capacity, and there was a significant relationship between MAHs exposure and fasting glucose levels, as found by multiple logistic regression analysis (odds ratio = 3.95, 95% confidence interval = 1.074-14.530). Conclusion: This study indicated that MAHs increase fasting glucose level and insulin resistance. Furthermore, these results suggested that absorbing the organic solvent itself and active metabolic intermediates can increase oxidative stress and cytokine levels, resulting in the changes in glucose metabolism and the induction of insulin resistance.

Effect of Iron Availability on Induction of Systemic Resistance to Fusarium Wilt of Chickpea by Pseudomonas spp.

  • Saikia, Ratul;Srivastava, Alok K.;Singh, Kiran;Arora, Dilip K.;Lee, Min-Woong
    • Mycobiology
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    • v.33 no.1
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    • pp.35-40
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    • 2005
  • Selected isolates of Pseudomonas fluorescens (Pf4-92 and PfRsC5) and P. aeruginosa (PaRsG18 and PaRsG27) were examined for growth promotion and induced systemic resistance against Fusarium wilt of chickpea. Significant increase in plant height was observed in Pseudomonas treated plants. However, plant growth was inhibited when isolates of Pseudomonas were used in combination with Fusarium oxysporum f. sp. ciceri (FocRs1). It was also observed that the Pseudomonas spp. was colonized in root of chickpea and significantly suppressed the disease in greenhouse condition. Rock wool bioassay technique was used to study the effect of iron availability on the induction of systemic resistance to Fusarium wilt of chickpea mediated by the Pseudomonas spp. All the isolates of Pseudomonas spp. showed greater disease control in the induced systemic resistance (ISR) bioassay when iron availability in the nutrient solution was low. High performance liquid chromatography (HPLC) analysis indicated that an the bacterial isolates produced more salicylic acid (SA) at low iron ($10\;{\mu}M$ EDDHA) than high iron availability ($10\;{\mu}Fe^{3+}$ EDDHA). Except PaRsG27, all the three isolates produced more pseudobactin at low iron than high iron availability.

The Strength and Durability of Polymer-Cement Mortars (폴리머-시멘트 모르타르의 강도와 내구성)

  • Hwang, Eui-Hwan;Hwang, Taek-Bung;Ohama, Yoshihiko
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.786-794
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    • 1994
  • The strength and durability of polymer-cement mortars were investigated. The specimens of polymer-cement mortar were prepared by using styrene-butadiene rubber(SBR) latex, ethylene-vinyl acetate(EVA) emulsion and polyacrylic ester(PAE) emulsion with various polymer-cement ratios(5, 10, 15, 20wt%). For the evaluation of durability of polymer-cement mortars, freezing-thawing, acid resistance and heat resistance tests were conducted. With an increase of polymer-cement ratio, the frost resistance of polymer-cement mortars was greatly improved, but acid and heat resistance were deteriorated. The compressive and flexural strengths of SBR polymer-cement mortars were improved with an increase of polymer-cement ratio, whereas those of EVA and PAE polymer-cement mortars reached maximum value at polymer-cement ratio of 10wt%.

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Flowing Ability and Mechanical Properties of Polypropylene Fiber Reinforced High Performance Concrete

  • Kim, Young-Ik;Sung, Chan-Yong
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.7
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    • pp.27-37
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    • 2003
  • This study was performed to examine the flowing ability and filling ability of polypropylene fiber reinforced high performance concrete. The slump flow was decreased with increasing the polypropylene fiber content, rapidly. At the box-type filling ability, the difference of box height was increased with increasing the fiber content and the box-type passing ability was closed in fiber content 1 %. The final flowing distance of L-type was decreased with increasing the fiber content. Also, it was decreased above 0.75% of polypropylene fiber content, rapidly. The filling ability of L-type was badly showed above polypropylene fiber content 0.75%. Also, the compressive strength was decreased with increasing the fiber content, but the flexural strength was shown higher than that of the concrete without fiber. At the impact resistance, drop numbers for reaching in final fracture were increased with increasing the fiber content. Also, the drop numbers for reaching initial fracture of 1mm were increased with increasing the fiber content. At the acid resistance, the percent of original mass was decreased with increasing the fiber content.

Membrane Fouling Effect with Organic-Inorganic Materials Using the Membrane Separation in Drinking Water Treatment Process (분리막을 이용한 정수처리공정에서 유, 무기물질이 막오염에 끼치는 영향)

  • 이용택;오중교
    • Membrane Journal
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    • v.13 no.4
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    • pp.219-228
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    • 2003
  • This study was carried to investigate the effect of humic acid and kaloin which cause the turbidity and organic substance component for optimization of drinking water treatment process using the membrane separation. Also we were ovserved the optimum operating condition which flux was stabilized, while specific resistance value in membrane was minimized. As the result, the membrane separation was operated at low specific resistance value with the increase of the pressure. And then, cake load decreased by high velocity with the increase of the linear velocity, and the tendency in which specific resistance value and flux increased. Therefore, we confirmed the optimum operating condition as pressure $2.0 kgf/cm^2,$ 0.92 m/sec linear velocity.

Comparative Study on Antioxidant Activity and Multi-drug Resistance Reversing Activity in Korean Colored Soybean Cultivars

  • Boo, Hee-Ock;Lee, Jong-Ill;Koshio, Kaihei;Song, Won-Seob;Chon, Sang-Uk
    • Korean Journal of Plant Resources
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    • v.24 no.3
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    • pp.319-323
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    • 2011
  • The purpose of this study is to analyze antioxidant activity and multidrug resistance reversing activity in several Korean colored soybean (Glycine max Merr.) cultivars. Antioxidant activity of methanol extracts from colored soybean cultivars was evaluated by TBARS (thiobarbituric acid reactive substances), DPPH (1, 1-diphenyl-2-picrylhydrazyl) and ABTS (2,2'-azino-bis (3-ethylbenzothiazoline-6-sulphonic acid) methods. By means of TBARS, cultivar "Jeonnam #1" showed the highest activity until 7 days, and followed by "Black #1", "Jinyul" and "Black #3", showing lower activity than that of BHT (butylated hydroxytoluene). Methanol extracts of all cultivars proved that DPPH radical scavenging activity is dose-dependent. Methanol extract from cultivar "Jeonnam #1" showed highest DPPH radical scavenging activity, and followed by cultivars "Black #1". MDR (multi-drug resistance reversing) activity, however, showed the highest effect in "Black #3" and the lowest "Black #1" cultivar. These results suggest that seed colors of soybean may play an important role in antioxidant activity and MDR activity.

Determinants of Plant Growth-promoting Ochrobactrum lupini KUDC1013 Involved in Induction of Systemic Resistance against Pectobacterium carotovorum subsp. carotovorum in Tobacco Leaves

  • Sumayo, Marilyn;Hahm, Mi-Seon;Ghim, Sa-Youl
    • The Plant Pathology Journal
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    • v.29 no.2
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    • pp.174-181
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    • 2013
  • The plant growth-promoting rhizobacterium Ochrobactrum lupini KUDC1013 elicited induced systemic resistance (ISR) in tobacco against soft rot disease caused by Pectobacterium carotovorum subsp. carotovorum. We investigated of its factors involved in ISR elicitation. To characterize the ISR determinants, KUDC1013 cell suspension, heat-treated cells, supernatant from a culture medium, crude bacterial lipopolysaccharide (LPS) and flagella were tested for their ISR activities. Both LPS and flagella from KUDC1013 were effective in ISR elicitation. Crude cell free supernatant elicited ISR and factors with the highest ISR activity were retained in the n-butanol fraction. Analysis of the ISR-active fraction revealed the metabolites, phenylacetic acid (PAA), 1-hexadecene and linoleic acid (LA), as elicitors of ISR. Treatment of tobacco with these compounds significantly decreased the soft rot disease symptoms. This is the first report on the ISR determinants by plant growth-promoting rhizobacteria (PGPR) KUDC1013 and identifying PAA, 1-hexadecene and LA as ISR-related compounds. This study shows that KUDC1013 has a great potential as biological control agent because of its multiple factors involved in induction of systemic resistance against phytopathogens.

Monitoring of Initial Stages of Atmospheric Zinc Corrosion in Simulated Acid Rain Solution under Wet-dry Cyclic Conditions

  • EL-Mahdy, Gamal A.;Kim, Kwang B.
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.251-256
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    • 2004
  • Exposure of zinc samples in simulated acid rain solution (SARS) was investigated under a periodic wet-dry conditions using an AC impedance technique. The periodic wet and dry exposure consisted of the immersion of zinc samples in SARS for one hour followed by exposure to 7 hours drying at 60% RH. Phases of the corrosion products were indentified by X-ray diffraction (XRD). The influence of relative humdiity (RH), temperature, and surface inclination on the atmospheric corrosion of zinc is described. The reciprocal of polarization resistance (1/Rp) decreases rapidly during the initial stages then slowly and eventually attains a steady state as exposure time progresses. The average of reciprocal of polarization resistance per cycle, (ARPR) was calculated and found to decrease as number of exposure cycle increases. An increase of temperature enhances the corrsion rate of zinc. The values of ARPR, of a sample inclined at 30 o are lower than those for a sample oriented horizontally. The experiment result shows a pronounced dependence of reciprocal of polarization resistance on RH. Exposure in the presence of carbonate anions gives rise to more protective corrosion products than in nitrate anion solution. The corrosion mechanism during the initial stages of atmospheric zinc corrosion under wet-dry cyclic conditions is suggested.

A Study on The Variation of Penetration According to The Shielding Gas in A1100 Aluminum Welding (A1100 알루미늄 용접에서 실드가스의 종류에 따른 용입부의 변화 연구)

  • Kim, Jin-Su;Kim, Bub-Hun;Kim, Gue-Tae;Park, Yong-Hwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.2
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    • pp.49-54
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    • 2013
  • Recently welding of aluminum material is actively carried out to make lightweight in the fields of LNG vessels, aircraft, chemical plants, etc. To obtain high strength, hardness and elongation, elements such as manganese, zinc, silicon, etc should be added in aluminum alloy, which has been improved on the mechanical properties like precipitation hardening, age hardening, loosening, corrosion resistance acid resistance. Ar gas is used as a shielding gas of MIG welding for aluminum, also $N_2$, $O_2$, $CO_2$, $H_2$ etc can be added depending on the composition of the alloy. In this study, Ar + $O_2$, Ar, and He were used for welding, hardness, penetration status and changes in composition of penetrated parts were compared and analyzed. This made it possible to know the status and changes of the process in the penetrated parts depending on used gas throughout this study.