• Title/Summary/Keyword: Acid Soil

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Desorption of Adsorbed Humic Acid on Carbon nano Tubes (카본나노튜브에 흡착된 휴믹산의 탈착에 관한 연구)

  • Jo, Mihyun;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.7
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    • pp.81-89
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    • 2013
  • Concerns have been raised over the impact of nano materials on soil and groundwater environment with the increasing attention to the potential applications of carbon nano materials in various fields. Particularly, carbon nano materials introduced into water environment readily make complexes with humic acid (HA) due to their hydrophobic nature, so there have been increasing numbers of studies on the interaction between HA and carbon nano materials. In this study, we investigated the solubility of HA and multiwalled carbon nanotubes (MWCNT) in three different surfactant solutions of sodium dodecyl sulfate (SDS), Brij 30 and Triton X-100, and evaluated whether the HA can be effectively desorbed from the surface of MWCNT by surfactant. The objective of this study was to determine the optimal adsorption condition for HA to MWCNT. Futhermore, sodium dodecyl sulfate (SDS), Brij 30, Triton X-100 were used to elucidate the effect of desorption and separation on adsorbed HA on MWCNT. As a result, HA solution with 12.7 mg of total organic carbon (TOC) and 5 mg of MWCNT showed the highest adsorption capacity at pH 3 reacted for 72 hrs. Weight solubilizing ratio (WSR) of surfactants on HA and MWCNT was calculated. HA had approximately 2 times lower adsorption capacity for the applied three surfactants compared to those of MWCNT, implying that the desorption of HA may occur from the HA/MWCNT complex. According to the results of adsorption isotherm and weight solubilizing ratio (WSR), the most effective surfactants was the SDS 1% soluiton, showing 53.63% desorption of HA at pH 3.

Treatment of Abandoned Coal Mine Discharged Waters Using Lime Wastes

  • Park Joon-Hong;Kim Hee-Joung;Yang Jae-E.;Ok Yong-Sik;Lee Jai-Young;Jun Sang-Ho
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.10a
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    • pp.59-61
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    • 2005
  • In Korea, hundreds of abandoned and closed coal and metallic mines are present in the steep mountain valleys due to the depression of the mining industry since the late 1980s. From these mines, enormous amounts of coal waste were dumped on the slopes, which causes sedimentation and acid mine drainage (AMD) to be discharged directly into streams causing detrimental effects on soil and water environments. A limestone slurry by-product (lime cake) is produced from the Solvay process in manufacturing soda ash. It has very fine particles, low hydraulic conductivities ($10^{-8}{\sim}10^{-9}cm/sec$), high pH, high EC due to the presence of CaO, MgO and $CaCl_2$ as major components, and traces of heavy metals. Due to these properties, it has potential to be used as a neutralizer for acid-producing materials. A field plot experiment was used to test the application of lime cake for reclaiming coal wastes. Each plot was 20 x 5 m (L x W) in size on a 56% slope. Treatments included a control (waste only), calcite ($CaCO_3$), and lime cake. The lime requirement (LR) for the coal waste to pH 7.0 was determined and treatments consisted of adding 100%, 50%, and 25% of the LR. The lime cake and calcite were also applied in either a layer between the coal waste and topsoil or mixed into the topsoil and coal waste. Each plot was hydroseeded with grasses and planted with trees. In each plot, surface runoff and subsurface water were collected. The lime cake treatments increased the pH of coal waste from 3.5 to 6, and neutralized the pH of the runoff and leachate of the coal waste from 4.3 to 6.7.

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Suppression of Pyrite Oxidation by Formation of Iron Hydroxide and Fe(III)-silicate Complex under Highly Oxidizing Condition

  • Lee, Jin-Soo;Chon, Chul-Min;Kim, Jae-Gon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.297-302
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    • 2011
  • Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

Effect of Plant (Salvia sp.) Growth Using Mixed Microorganisms (혼합 미생물이 식물(Salvia)의 생장에 미치는 영향)

  • Choi, Kyung-Min;Park, Eung-Roh;Ju, Hong-Shin;Yang, Jae-Kyung;Suh, Jeung-Keun;Lee, Sung-Taik;Park, Chang-Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.2
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    • pp.27-33
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    • 1996
  • Effect of effective microorganisms on the growth of plant (salvia sp.) was investigated. Microorganisms used were photosynthetic bacteria, lactic acid bacteria and yeasts. When photosynthetic bacteria were inoculated to soil by 100 dilution, treated plants showed 160% growth by length compared to control. When photosynthetic bacteria, lactic acid bacteria and yeasts were mixed, diluted by 10 and inoculated to soil, the plants showed 212% growth compared to control. Microbial populations were increased in the treated soil.

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Indole Acetic Acid Production of Rice Paddy Soils (논토양의 Indole Acetic Acid 생성능)

  • Suh, Jang-Sun;Noh, Hyung-Jun;Choi, Soo-Im
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.386-391
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    • 2006
  • This study was conducted to evaluate the indole acetic acid (IAA) formation in soils as a biological indicator for the health of rice paddy soils with control, nitrogen sole, chemical fertilizer (NPK), and chemical fertilizer plus compost (CNPK) plots. There was a positive relationship between colorimetric method and high performance liquid chromatography for IAA in soils determined, and the values were similar between two methods, as $0.83{\sim}1.23{\mu}g\;IAA\;g^{-1}h^{-1}$ in colorimetric method, $0.80{\sim}1.29{\mu}g\;IAA\;g^{-1}h^{-1}$ in HPLC method. Numbers of dehydrogenase-producing bacteria and the IAA production in soils were high in NPK and CNPK plots comparing with control and nitrogen sole plots. Also there was high correlation between numbers of dehydrogenase-producing bacteria and IAA production in soils.

Effect of Ferric and Ferrous Iron Irrigation on Brown-Colored Symptom of Leaf in Panax ginseng C. A. Meyer (산화철과 환원철이 인삼의 갈반형 황증 발생에 미치는 영향)

  • Lee, Sung Woo;Park, Kee Choon;Lee, Seung Ho;Jang, In Bok;Park, Kyung Hoon;Kim, Mi Lan;Park, Jin Myeon;Kim, Ki Hong
    • Korean Journal of Medicinal Crop Science
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    • v.22 no.1
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    • pp.32-37
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    • 2014
  • To study the cause of physiological disorder in leaf of ginseng cultivated at paddy soil, the degree of brown-colored symptom (BCS) and the contents of inorganic matter in leaf were investigated by irrigating the solution of ferric and ferrous iron of 0.1 ~ 2.0%, and citric acid of 1.0 ~ 4.0% on bed soil, respectively. Ratio of BCS by variety was as high as 85.0% in Yoenpoong, while it was as low as 5.4%, 7.5% in Chunpoong and Hwangsook, respectively. The contents of inorganic matter of leaf in Yoenpoong were lower in $P_2O_5$, Ca, and Mg, while it were higher in K, Fe, and Mn than other variety. Iron solution caused BCS more distinctly when each ferric and ferrous iron were dissolved with 1.0% citric acid than when each iron was dissolved without citric acid. Ferric iron caused BCS more effectively than ferrous iron. BCS occurred in 4.0% citric acid was as same as 2.0% ferric iron mixed with 1.0% citric acid. Low $P_2O_5$ and high Fe content in leaf appeared in both of artificial and natural symptoms. We concluded that excessive Fe uptake caused BCS to leaf because the solubility of iron was increased in condition of low soil pH.

The Relationship between Microbial Characteristics and Glomalin Concentrations of Controlled Horticultural Soils in Gyeongnam Province

  • Kim, Min Keun;Ok, Yong Sik;Heo, Jae-Young;Choi, Si-Lim;Lee, Sang-Dae;Shin, Hyun-Yul;Kim, Je-Hong;Kim, Hye Ran;Lee, Young Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.2
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    • pp.107-112
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    • 2014
  • Glomalin has been suggested as an enhancer for soil stability by promoting the aggregation. In this study, we examined the concentrations of glomalin and microbial characteristics in 25 controlled horticultural soils sampled from Gyeongnam Province. Total glomalin had a significant positive correlation with soil organic matter (p < 0.01), soil microbial biomass carbon (p < 0.05), and dehydrogenase activity (p < 0.05) in controlled horticultural soils. In addition, the total glomalin had a significant positive correlation with concentrations of total fatty acid methyl esters, Gram-negative and Gram-positive bacteria, fungi, and arbuscular mycorrhizal fungi in controlled horticultural soils (p < 0.001). In conclusion, the concentration of total glomalin could be an indicator of microbial biomass richness for sustainable agriculture in controlled horticultural soils.

A Study of Germination Characteristics of Dredged Soil Collected in Gunsan (군산 인근해역 준설토를 활용한 식생발아 특성 연구)

  • Kim, Dae-Hyeon;Yoon, Gil-Lim;Kim, Min-Seok;Park, Kyung-Ho
    • Journal of the Korean Geotechnical Society
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    • v.31 no.5
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    • pp.59-66
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    • 2015
  • This study aimed to analyze germination characteristics of dredged soil collected in Gunsan. This study develops the ecological environment materials for useable green soil that can be used in the stabilization of the dredged slope. In order to analyze the germination characteristics of dredged soil, specimens treated with Bio ameliorant (0, 6%), AC (Amino acid) ameliorant (0, 6%), Sawdust (0, 6%) and loess (0, 50%) were made. Based on the test results, it was found that dredged soils of Gunsan Saemangeum were classified as SM, and poor arboreal growth conditions were necessary to be treated with ameliorants (Sawdust, Bio ameliorant, etc.).

GIS Based Analysis of Landslide Effecting Factors in the Pyeongchang Area

  • Kim, Gihong;Won, Sangyeon;Kim, Dongmin
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.32 no.3
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    • pp.261-269
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    • 2014
  • Most areas in Gangwon-do are mountainous regions where causes heavy damages due to landslides. It is important to analyze basic factors influencing the cause of landslides in order to prevent such landslides. For this study, a landslide occurring site is extracted from aerial images taken after the landslide caused by typhoon 'Ewiniar' in Pyeongchang area 2006. Also, the overlay analysis with the topographic, forest, and soil maps in this area is performed using GIS based methods. In addition, the topographic, forest, and soil characteristics relating to the landslide factors are analyzed. As a result, large numbers of landslides occurred at a slope angle of $20^{\circ}-40^{\circ}$. In the case of the forest factors, there are close relationships between the artificial pine and larch forests and the frequency of landslides. The low forest density represents a weakness in landslides. In the case of the soil factors, a higher level in the surface soil with a type of sandy loam soil, a higher gravel content in subsoil, and a higher degree of acid rocks in soil parent materials cause higher frequencies in landslides.

Mechanism of P Solubilization in Vermicompost Treated Red Lateritic Soils

  • Pramanik, Prabhat;Chakraborty, Hritesh;Kim, Pil-Joo
    • 한국환경농학회:학술대회논문집
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    • 2011.07a
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    • pp.188-195
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    • 2011
  • Red lateritic soils are typically low in total organic carbon (TOC) and available phosphorus (AP) content and continuous fertilization is required to obtain desired crop yield. In this experiment, cattle manure in three forms (air-dried, composted and vermicomposted) were applied to red lateritic soil to study their effect on TOC and AP content of soil and probable mechanism of P-solubilization as affected by these treatments were also studied. Vermicompost was the most effective to solubilize insoluble P in red lateritic soil (Alfisols) as compared to other organic amendments (air-dried cattle manure and compost). The highest SPA in vermicompost-treated soil attributed to the comparatively higher concentration of all the three SPA isozymes in these soils. The maximum P-solubilization in these soils might be attributed to the highest SPA and presence of several organic acids like citric, lactic and oxalic acids in vermicompost-treated soils. Since, vermicompost application also increased TOC, mineralizable N and exchangeable K content of soil, vermicompost could be considered as the most rational organic amendment to improve chemical properties of red lateritic soils.

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