• Journal of Soil and Groundwater Environment
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• v.15 no.3
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• pp.44-51
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• 2010

Contamination of groundwater from point and non-point sources is one of major problems of water resource manangement in Jeju island. This study characterized groundwater and soil contamination in Hallim area which is one of the areas of significantly contaminated soil and groundwater in Jeju Island. The amount of loaded contaminant (ALC) of Jeju area was estimated as 13,212 ton N/yr and 3,210 ton P/yr, The ALC of Hallim area was amounted to 2,895 ton N/yr and 1,102 ton P/yr, which accounted for 21.9% and 34.3% of the Jeju's ALC, respectively. The soil pH values (5.6-5.9) were not much different in land use areas. By contrat, average cation exchange capacity (CEC) of 14.1 $cmol^+/kg$ was high comparing to the nationwide range of 7.7-10.9 $cmol^+/kg$. Further, Sodium adsorption ratios (SARs) of horse ranch, pasture, and cultivating land for livestock were as high as 0.19, 0.17, and 0.16 respectively, comparing to the other landuse areas. Nitrate nitrogen at 22.2% of total groundwater wells exceeded 10 mg/L (the criteria of nitrate nitrogen for drinking water), averaginged 6.62 mg/L with maximum 28.95 mg/L. Groundwater types belonged to Mg-$HCO_3$, Na-$HCO_3$, Ca-$HCO_3$, and Na-Cl, among which Mg-$HCO_3$ type occupied more than 70% of the total samples, indicating the presence of anthropogenic sources. The concentration of nitrate nitrogen was negatively related to altitude and well depth, and positively related to the concentration of Ca, Mg, and $SO_4$ which might originate from chemical fertilizer. The ratio of nitrogen isotopes was estimated as an average of 8.10$^{\circ}/_{\circ\circ}$, and the maximum value of 17.9$^{\circ}/_{\circ\circ}$. According to the nitrogen isotope ratio, the most important nitrogen source was assessed as chemical fertilizer (52.6%) followed by sewage (26.3%) and livestock manures (21.1%).

• Korean Journal of Ecology and Environment
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• v.34 no.3 s.95
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• pp.166-174
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• 2001

The autochthonous and allochthonous organic carbon loading were measured in Lake Soyang, to estimate the amount of carbon loading into the lake and the contribution of their sources to tile lake's carbon loading. Autochthonous carbon loading was estimated from phytoplankton primary production with the extracellular organic carbon (EOC). Allochthonous loading was determined by measuring dissolved organic carbon (DOC) and particulate organic carbon (POC) concentration in the main inflowing Soyang River. Both autochthonous and allochthonous organic carbon loading were high during the svmmer, from July to September, and accounted for 43.2% and 71.7% of the annual loading, respectively. Primary productivity was elevated up to $1,000\;mgC\;m^{-2}\;d^{-1}$ during summer and lowest in winter. EOC production from phytoplankton was also large in summer, resulting in a high DOC concentration in the lake water. Primary production of phytoplankton and allochthonous organic matter loading from the watershed contributed to 53.6% and 46.4% of total loading, respectively. The EOC production accounted far $4.4{\sim}21.2%$ of POC primary production, implying that EOC production of phytolankton must be considered in estimation of primary production.

• Korean Journal of Ecology and Environment
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• v.33 no.4 s.92
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• pp.350-357
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• 2000

This paper evaluated the influence of point source and flow events on inorganic nitrogen fractions at 17 sites of Taechung Reservoir during 1993${\sim}$1994. Total nitrogen (TN) averaged 1.53 mg/L during the study and ranged between 0.70 and 2.56 mg/L. Dissolved inorganic nitrogen(DIN) accounted for >90% of TN regardless of season and location, indicating a nitrogen-rich system showing eutrophic${\sim}$hypereutrophic conditions. Some 67${\sim}$94% of DIN was NO$_{3}$-N, whereas mean level of NH$_{4}$-N was less than 5% of DIN. During monsoon 1993, dilution of NO$_{3}$-N was evident in the headwaters as a result of mixing of lake water with rain water, while NH$_{4}$-N increased>100% compared to the premonsoon. Values of NH$_{4}$-N had a positive correlation with rainfall (r=0.85; p<0.001) and negative correlations with theoretical water residence time(r=-0.90; p<0.001) and conductivity(r=-0.78, p<0.001), respectively. These outcomes suggest that NH$_{4}$-N came from external input from the watershed during the monsoon. In both years, mean TN was greater in the mid-lake sites than any other sites. A great amount of TN in the mid-lake was most pronounced in monsoon 1994 because of an accumulated influence of the point sources during low inflow. Overall data suggest that concentrations of TN in this system did not show large differences along the longitudinal gradients and its distributions is likely determined by point-sources rather than inflow regime.

• Ocean and Polar Research
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• v.24 no.2
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• pp.123-134
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• 2002

Seasonal variations of settling particles and metal fluxes were monitored at a nearshore site of Marian Cove, King Geroge Island, Antarctica from 28th February 1998 to 22nd January 2000. Near-bottom sediment traps were deployed at 30m water depth of the cove, and sampling bottles were recovered every month by SCUBA divers. Total particulate flux and metal concentrations were determined from the samples. Total particulate flux showed a distinct seasonality, high in austral summer and low in austral winter: the highest flux $(21.97g\;m^{-2}d^{-1})$ was found in February of 1999, and the lowest $(2.47g\;m^{-2}d^{-1})$ in September of 1998, when sea surface was frozen completely. Lithogenic particle flux accounted for 90% of the total flux, and showed a significantly negative correlation with the thickness of snow accumulation around the study site. It was suggested that the most of the lithogenic particles trapped in the bottles was transported by melt water stream from the surrounding land. Fluxes of Al, Fe, Ti, Mn, Zn, Cii, Co, Ni, Cr, Cd, and Pb showed similar seasonal variations with the total flux, and their averaged fluxes were 34000, 9000,960, 180, 13.8, 17.6, 3.0,2.1, 5.4, 0.02, and $1.5nmol\;m^{-2}d^{-1}$ respectively. Among the metals, Cu and Cd showed the most noticeable seasonal patterns. The Cd flux correlated positively with the fluxes of biogenic components while the Cu flux correlated with both the lithogenic and biogenic particle fluxes. The Cu flux peak in the late summer is likely related to a substantial amount of inflow of ice melt water laden with Cu-enriched lithogenic particles. On the other hands, the Cd flux peak in the early spring may be associated with the unusually early occurred phytoplankton bloom.

• Korean Journal of Ecology and Environment
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• v.33 no.1 s.89
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• pp.23-30
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• 2000

n situ sediment oxygen demand (SOD), which takes place with the uptake of dissolved oxygen for biological metabolism and chemical oxidation in sediments, ranged from 1.57 to $12.55\;mg\;O_2\;m^{-2}\;h^{-1}$ in onshore of Lake Paldang from April to November 1999. SOD was influenced by the amount of organics and oxygen diffusion. Comparing the oxygen demands partitioning between overlying water and sediment during initial phase, SOD accounted for $63.8{\sim}94%$ of total oxygen demand in Lake Paldang. The chemical SOD and nitrogenous oxygen demand ranged $1.2{\sim}18.3%$ and $8.3{\sim}51.7%$ of total SOD, respectively. This result indicated that SOD in Lake Paldang occurred mainly by aerobic respiration and nitrification. Although the flow velocity could increase SOD within a certain limit, the effect of sediment depth on SOD was dependent on physicochemical properties of the sediment. This study showed that SOD can represent a significant portion of the total oxygen up-take in Lake Paldang. Therefore, the assessment of SOD might be necessary for the control of water quality.

• Korean Journal of Agricultural Science
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• v.31 no.1
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• pp.53-75
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• 2004

This study is aimed at identifying the national economic value of the irrigation facilities by reviewing the existing papers on economic values of the irrigation facilities and presenting current status of dual O & M problems of the irrigation facilities. This study suggested the unified O & M system rather than continuing the existing dual O & M system of irrigation facilities based on the surveyed results of the activities of irrigation fraternities in Chungnam Province. The findings and proposals for the successful unified and mono O & M system of the irrigation facilities are as follows: (1) Total number of irrigation facilities in the nation accounts for 67,582, while the total length of irrigation and drainage canals amounted to about 174,259km. On account of the total length of structural canals was estimated at 31%, much losses of water and much O & M costs have been inevitable for the full irrigation rice culture. In spite of the past heavy investment for irrigation facilities, the ratio of rain-fed and partially irrigated paddy fields accounts for 23% in 2003. Both Korea Agricultural and Rural Infrastructure Corporation (KARICO) and the city and Gun Governments have managed the irrigation facilities separately by irrigation fraternities. The KARICO have commanded 59% of irrigation paddy area with 18% of the total irrigation facilities, while the city and Gun governments covered 41% of irrigation paddy area with 82% of the existing number of irrigation facilities representing small and medium scale. (2) The 1999 demand prices of irrigation water per ton expressed in 2000 constant market price was estimated at 388 won, the supply price was amounted to 184 won per ton. Considering the supply and demand curve of the irrigation water, the existing irrigation facilities could not satisfy the demand of irrigation water. (3) In 1999, total present added value of the irrigation facilities during the economic life accounted for 48 trillion won, while total supply cost was 44.7 trillion won. The marginal benefit and cost ratio of irrigation water was 1.08. (4) The total O & M cost per year amounting to 681.1 billion won have been required to maintain and repair the existing irrigation facilities in Korea. For the successful unified O & M of irrigation facilities covering whole irrigated paddy field in Korea, 950 billion won of O & M costs are required to keep up the marginal benefit of irrigation water as 2,800 billion won per year. The total O & M cost as 950 billion won should be allocated 40%, 380 billion won for O & M costs of irrigation facilities and 60%, 570 billion won for improvement of irrigation facilities. (5) The study investigated and reviewed the present O & M status of the irrigation facilities by small and medium irrigation fraternities. Most of the farmers belong to the irrigation fraternities preferred not only unified O & M but also KARICO take-over of the whole O & M activities of the irrigation facilities. The prevailing O & M cost per 10a expended by the Corporation was amounted to 104,890 won, while that of city and Gun governments was only amounted to 4,600 won per 10a. regarding the small amount of O & M cost expended by city and Gun governments, it is evident that the existing irrigation system have been managed ineffectively and deteriorated the facilities comparing that of KARICO. In conclusion, the Government could not satisfied the demand of irrigation water by suppling water with existing irrigation facilities. Therefore new additional investment and financial support for irrigation water development should be made to convert rain-fed and partially irrigated paddy fields into fully irrigated ones. The operation and maintenance cost should be supported to keep the marginal values of rice production of existing irrigation facilities in the national economy and to modernize the obsolete irrigation facilities. By unifying the existing dual O & M systems, all the farmers belong to the irrigated paddy fields have to be equally benefited and could be increased their farm income and be stabilized their rural lives.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.8-9
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• 2017

Soybean yield has been low and unstable in Japan and other areas in East Asia, despite long history of cultivation. This is contrasting with consistent increase of yield in North and South America. This presentation tries to describe perspective of breaking stagnation of soybean yield in East Asia, considering the factors of the different yields between regions. Large amount of rainfall with occasional dry-spell in the summer is a nature of monsoon climate and as frequently stated excess water is the factor of low and unstable soybean yield. For example, there exists a great deal of field-to-field variation in yield of 'Tanbaguro' soybean, which is reputed for high market value and thus cultivated intensively and this results in low average yield. According to our field survey, a major portion of yield variation occurs in early growth period. Soybean production on drained paddy fields is also vulnerable to drought stress after flowering. An analysis at the above study site demonstrated a substantial field-to-field variation of canopy transpiration activity in the mid-summer, but the variation of pod-set was not as large as that of early growth. As frequently mentioned by the contest winners of good practice farming, avoidance of excess water problem in the early growth period is of greatest importance. A series of technological development took place in Japan in crop management for stable crop establishment and growth, that includes seed-bed preparation with ridge and/or chisel ploughing, adjustment of seed moisture content, seed treatment with mancozeb+metalaxyl and the water table control system, FOEAS. A unique success is seen in the tidal swamp area in South Sumatra with the Saturated Soil Culture (SSC), which is for managing acidity problem of pyrite soils. In 2016, an average yield of $2.4tha^{-1}$ was recorded for a 450 ha area with SSC (Ghulamahdi 2017, personal communication). This is a sort of raised bed culture and thus the moisture condition is kept markedly stable during growth period. For genetic control, too, many attempts are on-going for better emergence and plant growth after emergence under excess water. There seems to exist two aspects of excess water resistance, one related to phytophthora resistance and the other with better growth under excess water. The improvement for the latter is particularly challenging and genomic approach is expected to be effectively utilized. The crop model simulation would estimate/evaluate the impact of environmental and genetic factors. But comprehensive crop models for soybean are mainly for cultivations on upland fields and crop response to excess water is not fully accounted for. A soybean model for production on drained paddy fields under monsoon climate is demanded to coordinate technological development under changing climate. We recently recognized that the yield potential of recent US cultivars is greater than that of Japanese cultivars and this also may be responsible for different yield trends. Cultivar comparisons proved that higher yields are associated with greater biomass production specifically during early seed filling, in which high and well sustained activity of leaf gas exchange is related. In fact, the leaf stomatal conductance is considered to have been improved during last a couple of decades in the USA through selections for high yield in several crop species. It is suspected that priority to product quality of soybean as food crop, especially large seed size in Japan, did not allow efficient improvement of productivity. We also recently found a substantial variation of yielding performance under an environment of Indonesia among divergent cultivars from tropical and temperate regions through in a part biomass productivity. Gas exchange activity again seems to be involved. Unlike in North America where transpiration adjustment is considered necessary to avoid terminal drought, under the monsoon climate with wet summer plants with higher activity of gas exchange than current level might be advantageous. In order to explore higher or better-adjusted canopy function, the methodological development is demanded for canopy-level evaluation of transpiration activity. The stagnation of soybean yield would be broken through controlling variable water environment and breeding efforts to improve the quality-oriented cultivars for stable and high yield.

• 한국유가공학회:학술대회논문집
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• 2002.04a
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• pp.59-60
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• 2002

Edible films such as wax coatings, sugar and chocolate covers, and sausage casings, have been used in food applications for years$^{(1)}$ However, interest in edible films and biodegradable polymers has been renewed due to concerns about the environment, a need to reduce the quantity of disposable packaging, and demand by the consumer for higher quality food products. Edible films can function as secondary packaging materials to enhance food quality and reduce the amount of traditional packaging needed. For example, edible films can serve to enhance food quality by acting as moisture and gas barriers, thus, providing protection to a food product after the primary packaging is opened. Edible films are not meant to replace synthetic packaging materials; instead, they provide the potential as food packagings where traditional synthetic or biodegradable plastics cannot function. For instance, edible films can be used as convenient soluble pouches containing single-servings for products such as instant noodles and soup/seasoning combination. In the food industry, they can be used as ingredient delivery systems for delivering pre-measured ingredients during processing. Edible films also can provide the food processors with a variety of new opportunities for product development and processing. Depends on materials of edible films, they also can be sources of nutritional supplements. Especially, whey proteins have excellent amino acid balance while some edible films resources lack adequate amount of certain amino acids, for example, soy protein is low in methionine and wheat flour is low in lysine$^{(2)}$. Whey proteins have a surplus of the essential amino acid lysine, threonine, methionine and isoleucine. Thus, the idea of using whey protein-based films to individually pack cereal products, which often deficient in these amino acids, become very attractive$^{(3)}$. Whey is a by-product of cheese manufacturing and much of annual production is not utilized$^{(4)}$. Development of edible films from whey protein is one of the ways to recover whey from dairy industry waste. Whey proteins as raw materials of film production can be obtained at inexpensive cost. I hypothesize that it is possible to make whey protein-based edible films with improved moisture barrier properties without significantly altering other properties by producing whey protein/lipid emulsion films and these films will be suitable far food applications. The fellowing are the specific otjectives of this research: 1. Develop whey protein/lipid emulsion edible films and determine their microstructures, barrier (moisture and oxygen) and mechanical (tensile strength and elongation) properties. 2. Study the nature of interactions involved in the formation and stability of the films. 3. Investigate thermal properties, heat sealability, and sealing properties of the films. 4. Demonstrate suitability of their application in foods as packaging materials. Methodologies were developed to produce edible films from whey protein isolate (WPI) and concentrate (WPC), and film-forming procedure was optimized. Lipids, butter fat (BF) and candelilla wax (CW), were added into film-forming solutions to produce whey protein/lipid emulsion edible films. Significant reduction in water vapor and oxygen permeabilities of the films could be achieved upon addition of BF and CW. Mechanical properties were also influenced by the lipid type. Microstructures of the films accounted for the differences in their barrier and mechanical properties. Studies with bond-dissociating agents indicated that disulfide and hydrogen bonds, cooperatively, were the primary forces involved in the formation and stability of whey protein/lipid emulsion films. Contribution of hydrophobic interactions was secondary. Thermal properties of the films were studied using differential scanning calorimetry, and the results were used to optimize heat-sealing conditions for the films. Electron spectroscopy for chemical analysis (ESCA) was used to study the nature of the interfacial interaction of sealed films. All films were heat sealable and showed good seal strengths while the plasticizer type influenced optimum heat-sealing temperatures of the films, 130$^{\circ}$C for sorbitol-plasticized WPI films and 110$^{\circ}$C for glycerol-plasticized WPI films. ESCA spectra showed that the main interactions responsible for the heat-sealed joint of whey protein-based edible films were hydrogen bonds and covalent bonds involving C-0-H and N-C components. Finally, solubility in water, moisture contents, moisture sorption isotherms and sensory attributes (using a trained sensory panel) of the films were determined. Solubility was influenced primarily by the plasticizer in the films, and the higher the plasticizer content, the greater was the solubility of the films in water. Moisture contents of the films showed a strong relationship with moisture sorption isotherm properties of the films. Lower moisture content of the films resulted in lower equilibrium moisture contents at all aw levels. Sensory evaluation of the films revealed that no distinctive odor existed in WPI films. All films tested showed slight sweetness and adhesiveness. Films with lipids were scored as being opaque while films without lipids were scored to be clear. Whey protein/lipid emulsion edible films may be suitable for packaging of powder mix and should be suitable for packaging of non-hygroscopic foods$^{(5,6,7,8,)}$.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.17 no.4
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• pp.243-251
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• 2012

Real-time monitoring for environmental factors(temperature, salinity, chlorophyll, etc.) and carbonate components( pH and $fCO_2$) was conducted during 5-6th of July, 2012 at a seaweeds farm in Gijang, Busan. Surface temperature and salinity were ranged from $12.5{\sim}17.6^{\circ}C$ and 33.7~34.0, respectively, with highly daily and inter-daily variations due to tide, light frequency(day and night) and currents. Surface $fCO_2$ and pH showed a range of $381{\sim}402{\mu}atm$ and 8.03~8.15, and chlorophyll-a concentration in surface seawater ranged 0.8~5.8 ${\mu}g\;L^{-1}$. Environmental and carbonate factors showed the highest/lowest values around 5 pm of 5th July when the lowest tidal height and strongest thermocline in the water column, suggesting that biological production resulted in decrease of $CO_2$ and increase of pH in the seaweed farm. Processes affecting the surface $fCO_2$ distribution were evaluated using a simple budget model. In day time, biological productions by phytoplankton and macro algae are the main factors for $CO_2$ drawdown and counteracted the amount of $CO_2$ increase by temperature and air-sea exchange. The model values were a little higher than observed values in night time due to the over-estimation of physical mixing. The model suggested that algal production accounted about 14-40% of total $CO_2$ variation in seaweed farm.

• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.66-77
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• 2015

In order to survey the seasonal variation of the chemical composition of particulate matter of $2.5{\mu}m$ or less ($PM_{2.5}$), $PM_{2.5}$ was sampled from 8 February 2013 to 31 March 2014 in an industrial area of Chiba Prefecture, Japan. Chemical measurements of the sample included: ionic components ($Na^+$, $NH_4{^+}$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Cl^-$, $NO_3{^-}$ and $SO_4{^{2-}}$), carbonaceous components - organic carbon (OC) and elemental carbon (EC), and water-soluble organic carbon (WSOC). Also, secondary organic carbon (SOC) was measured based using the EC tracer method, and char-EC and soot-EC were calculated from the analytical results. The data obtained were interpreted in terms of temporal variation. Of the overall mean value of $PM_{2.5}$ mass concentration obtained during the study period, ionic components, OC and EC accounted for 45.3%, 19.7%, and 8.0%, respectively. $NO_3{^-}$ showed a unique seasonal distribution pattern due to a dependence on temperature and absolute humidity. It was estimated that an approximate temperature of $14^{\circ}C$, and absolute humidity of $7g/m^3$ were critical for the reversible reaction of $NH_4NO_3(p){\leftrightharpoons}NH_3(g)+HNO_3(g)$. The amount of OC and EC contributing to the monthly $PM_{2.5}$ mass concentration was higher in autumn and winter compared to spring and summer. This result could be attributed to the impact of burning biomass, since WSOC and the ratio of char-EC/soot-EC showed a similar pattern during the corresponding period. From the comparison of monthly WSOC/OC values, a maximum ratio of 83% was obtained in August (summer). The WSOC and estimated SOC levels derived from the EC tracer method correlated (R=0.77) in summer. The high occurrence of WSOC during summer was mainly due to the formation of SOC by photochemical reactions. Through long-term observation of $PM_{2.5}$ chemical components, we established that the degree to which the above-mentioned factors influence $PM_{2.5}$ composition, fluctuates with seasonal changes.