• 제목/요약/키워드: Accelerated-Retardation

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단일과대하중에 의한 피로균열추전의 지대지연현상에 관한 연구 (A Study on the Delayed-Retardation of Fatigue Crack Growth Following Single Peak Overload)

  • 오세욱;강상훈
    • 대한기계학회논문집
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    • 제14권5호
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    • pp.1186-1192
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    • 1990
  • 본 연구에서는 이와 같은 과대인장하중의 제하과정중에 발생하는 과대압축소 성역이 과대하중에 의한 피로균열의 진전지연에 미치는 영향을 중심으로 하여, 각 소 성역 치수를 매개변수로 하는 해석적 방법을 통하여 가속지연모델을 제안하고, 이를 2024-T3 Al 합금을 이용한 단일과대하중에 의한 지연시험결과 및 Wheeler 나 Willenb- org 등의 기존의 지연모델과 비교 고찰하고자 한다.

A study of size and frictional effect on the evolution of melting PartII: Twin screw extruder

  • Kim, D.S.;Lee, B.K.;Kim, H.S.;Lee, J.W.;C.G. Gogos
    • Korea-Australia Rheology Journal
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    • 제13권2호
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    • pp.89-95
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    • 2001
  • Effects of particulate size and frictional characteristics were examined on the melting behavior of PP(polypropylene) in a twin screw extruder. Powder and pellet types of PP were used and each component was blended with PE(polyethylene) wax and clay, respectively. It was observed that small size particulates, 1.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive auditive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in both types of PP, contrary to the result found in a batch mixer. The tendency observed in variation of torque and exit temperature was explained in terms of frictional effect and length of compacted region formed during evolution of melting.

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Retardation of Degradation in Accelerated Aging of Cotton Cellulose Using Borohydride Reduction

  • Kim, Hye-Kyung;Choi, Hyung-Min
    • International Journal of Human Ecology
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    • 제8권1호
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    • pp.1-8
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    • 2007
  • Degradation of cellulose during prolonged exposure in atmospheric conditions has been recognized as one of main problems in preserving cellulose-made products. The purpose of this research was therefore to study effects of borohydride reduction in improving both the color and strength retention of cotton fabrics artificially aged at temperatures ranging from $100^{\circ}C$ to $150^{\circ}C$. Results indicated that the fabrics treated with either sodium or tetramethylammonium borohydrides (TMA) were degraded at rates about one-half that of water-washed cotton. These results were consistent over the temperature range. Calculation of the activation energy (Ea) by different methods showed $Ea\;=\;25.5{\pm}\;1.5\;Kcal$, in keeping with measurements made by others at lower temperatures. The TMA-treatment was effective in minimizing discoloration of the fabrics with pre-baking, but not of the un-prebaked fabrics.

$C_3S$-$C_3A$계의 초기수화 반응 특성에 미치는 석고의 영향(II) (Effect of Gypsum of the Early Hydration Characteristics of the System $C_3S$-$C_3A$(II))

  • 신규연;한기성
    • 한국세라믹학회지
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    • 제27권4호
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    • pp.560-566
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    • 1990
  • The early hydration characteristics according to the C3A polymorphism and the presence of gypsum, in order to establish the hydration mechanism of the system C3S-C3A, have been studied. The hydration rate of C3A was changed according to the its crystal structure and influenced the hydration of C3S. That is, the hydration rate of C3S was accelerated in case of orthorhombic-C3A, but that was slightly retarded in case of melt-C3A than that of cubic-C3A. In the system C3S-C3A-gypsum, the retardation phenomenon of the reaction of monosulfate formation was observed in case of both orthorhombic and melt-C3A.

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랜덤하중에서의 균열전파속도 추정법에 관한 연구 (A Prediction of Crack Propagation Rate under Random Loading)

  • 표동근;안태환
    • 한국해양공학회지
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    • 제8권2호
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    • pp.115-123
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    • 1994
  • Under variable amplitude loading conditions, retardation or accelerated condition of fatigue crack growth occurs with every cycle, Because fatigue crack growth behavior varied depend on load time history. The modeling of stress amplitude with storm loading acted to ships and offshore structures applied this paper. The crack closure behavior examine by recording the variation in load-strain relationship. By taking process mentioned above, fatigue crack growth rate, crack length, stress intensity factor, and crack closure stress intensity factor were obtained from the stress cycles of each type of storm ; A(6m), B(7m), C(8m), D(9m), E(11m) and F(15m) which was wave height. It showed that the good agreement with between the experiment results and simulation of storm loads. So this estimated method of crack propagtion rate gives a good criterion for the safe design of vessels and marine structure.

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UV-Degradation Chemistry of Oriental Lacquer Coating Containing Hindered Amine Light Stabilizer

  • 홍진후;박미영;김현경;최정오
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.61-64
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    • 2000
  • FT-IR/ATR analysis shows that the oriental lacquer coating network degrades mostly in the unsaturated side chain. The rate of increase in carbonyl intensity (a measure of photodegradation) during the accelerated weathering test was substantially different for the unstabilized and stabilized samples; adding 2 wt% HALS into the oriental lacquer formulation enhanced photostabilization up to three times. Weight loss measurements, another indication of photodegradation, and SEM analysis support this conclusion. Despite the presence of the photo-stabilizer, the other properties of the lacquer were not significantly affected. In particular, the curing behavior of purified lacquer (PL) and HALS-stabilized samples is similar, although the in-situ DETA analysis showed that addition of HALS can slightly retard the cure reaction rate in oriental lacquer coating. It is hypothesized that this cure retardation may be related to the salt formation between HALS and acid of oriental lacquer.

플라즈마를 이용한 미생물합성 폴리에스테르의 표면개질과 효소분해성 (Surface Modification and Enzymatic Degradation of Microbial Polyesters by Plasma Treatments)

  • 김준;이원기;류진호;하창식
    • 접착 및 계면
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    • 제7권2호
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    • pp.19-25
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    • 2006
  • 미생물 합성 고분자인 poly(hydroxylalkanoate)s (PHAs)의 초기효소분해는 표면침식의 메커니즘으로 진행하므로 이들의 분해거동은 표면특성을 개질로서 조절할 수 있다. 본 연구에서는 효소분해속도를 조절하기 위하여 플라즈마 기법을 PHAs 표면특성의 개질에 적용하였다. $CF_3H$$O_2$ 플라즈마를 사용하여 재료 표면에 각각 소수성 및 친수성을 부여하였다. 효소분해 실험은 pH 7.4의 0.1 M potassium phosphate 완충용액에서 Alcaligenes facalis T1에서 정제된 poly(hydroxybutyrate) 분해효소를 첨가하여 행하였다. $CF_3H$ 플라즈마 처리된 시편의 경우 표면 층의 불소화에 따른 소수성의 증가와 분해 효소에 대한 비활성으로 초기분해 속도가 상당히 지연됨을 관찰하였으나 $O_2$ 플라즈마 처리에 의한 표면 친수성은 분해속도의 촉진 등에 큰 영향을 미치지 않았다.

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입자크기와 마찰효과가 용융 과정에 미치는 영향 Part I : 회분식 혼련기 (A Study of Size and Frictional Effects on the Evolution of Melting Part I : Batch Mixer)

  • Kim, Dong-Sung;Park, Yung-Jin;Lee, Bong-Kyu;Kim, Hyung-Su;Lee, Jae-Wook
    • 유변학
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    • 제11권1호
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    • pp.44-49
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    • 1999
  • 폴리프로필렌(PP)수지의 회분식 혼련기에서의 용융 거동을 입자들의 크기와 첨가제들의 마찰특성과 연관지어 연구하였다. 사용된 PP는 파우더와 펠렛 두 가지 형태였고 각각의 수지에 폴리에틸렌(PE) 왁스와 클레이(clay)를 첨가하였다. 작은 크기를 가지는 PP 파우더의 경우가 펠렛 형태의 PP보다 용융 속도가 빨랐으며 마찰효과가 큰 클레이는 PP수지의 용융속도를 효과적으로 촉진시키는 것으로 확인되었다. 한편 PE왁스의 경우는 펠렛 형태의 PP의 용융 속도를 지연시키는 작용을 하였으나 파우더 형태의 PP의 경우에는 오히려 그 속도를 촉진시키는 것으로 나타났다.

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석고에 고용된 $P_2O_5$$C_3A$의 초기수화에 미치는 영향 (Effect of the $P_2O_5$ Substituted Gypsum on the Early Hydration of $C_3A$)

  • 한기성;김용국
    • 한국세라믹학회지
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    • 제21권4호
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    • pp.355-360
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    • 1984
  • The effect of 2% of $P_2O_5$ substituted in gypsum(5 mol% as $HPO_3$) on the early hydration characteristics of $C_3A$ were investigated and then gypsum only and gypsum mixed with $Ca(H_2PO_4)_2$.$H_2O$(2% as $P_2O_5$) were studied separately for comparison. The early hydration reaction of $C_3A$ with each gypsum were examined by measuring the rate of heat libera-tion of hydration with calorimeter and by analysing the hydration products with X-ray diffractometer and differential thermal analyser. It was shown that phosphogypsum substituted with $P_2O_6$ in the crystal lattice accelerated exceedingly the formation of the ettrignite and following hydrated products. However the other gypsum especially gypsum without any phosphate delayed the formation of various hydration products, It was consequently suggested that when phosphogypsum are used as the retarder of cement setting its reta-rding effect for setting of cement is not ascribed to the retardation of ettringite formation.

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The role of autophagy in the placenta as a regulator of cell death

  • Gong, Jin-Sung;Kim, Gi Jin
    • Clinical and Experimental Reproductive Medicine
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    • 제41권3호
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    • pp.97-107
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    • 2014
  • The placenta is a temporary fetomaternal organ capable of supporting fetal growth and development during pregnancy. In particular, abnormal development and dysfunction of the placenta due to cha nges in the proliferation, differentiation, cell death, and invasion of trophoblasts induce several gynecological diseases as well as abnormal fetal development. Autophagy is a catalytic process that maintains cellular structures by recycling building blocks derived from damaged microorganelles or proteins resulting from digestion in lysosomes. Additionally, autophagy is necessary to maintain homeostasis during cellular growth, development, and differentiation, and to protect cells from nutritional deficiencies or factors related to metabolism inhibition. Induced autophagy by various environmental factors has a dual role: it facilitates cellular survival in normal conditions, but the cascade of cellular death is accelerated by over-activated autophagy. Therefore, cellular death by autophagy has been known as programmed cell death type II. Autophagy causes or inhibits cellular death via the other mechanism, apoptosis, which is programmed cell death type I. Recently, it has been reported that autophagy increases in placenta-related obstetrical diseases such as preeclampsia and intrauterine growth retardation, although the mechanisms are still unclear. In particular, abnormal autophagic mechanisms prevent trophoblast invasion and inhibit trophoblast functions. Therefore, the objectives of this review are to examine the characteristics and functions of autophagy and to investigate the role of autophagy in the placenta and the trophoblast as a regulator of cell death.