• Title/Summary/Keyword: Accelerated weathering test

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Thermal Degradation Behavior and Reliability Analysis of Plastic Materials for Household Electric Appliances (가전제품용 플라스틱 재료의 열분해 거동 및 신뢰성 평가)

  • Im, Chang-Gyu;Kim, Jun-Young;Kim, Seong-Hun
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.508-517
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    • 2005
  • The thermal degradation behavior and reliability analysis were investigated using dynamic thermogravimetric analysis (TGA) and accelerated degradation test (ADT) to characterize the dynamic parameters related to thermal degradation of plastic meterials for household electric appliances. In addition, the weathering of the plastic were performed by ADT using Xenon uc, and the color difference of the samples after ADT were measured with Color Eye 3010 specoophotometer. he activation energy for thermal degradation of the samples increased with increasing the rate of weight loss. The Kim-Park method was found to be more effective analysis in describing thermal degradation of plastic meterials. Plastic materials were very sensitive to ultra-violet rays in faster degradation.

Research on Ultraviolet Light Degradation According to Types of Encapsulants for PV Modules (태양광 모듈용 봉지재 종류에 따른 자외선 광열화 연구)

  • Seungah Ur;RakHyun Jeong;JuHwi Kim;Chanyong Lee;Lee Jaehyeong
    • Current Photovoltaic Research
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    • v.11 no.4
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    • pp.108-113
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    • 2023
  • Pressure to reduce costs in the current solar market is driving the development and implementation of new module designs and prompting the use of new materials and components. In order to utilize the variability of each material that makes up the module, it is essential to understand the basic characteristics of the material. In this article, we evaluate light degradation after UV irradiation as an encapsulation material. Measure and analyze the results of various characteristic tests for discoloration, optical and electrical property degradation before and after UV accelerated testing. To evaluate weathering stability, UV tests were performed comparing existing EVA and UVT-EVA, POE and improved low-cost POE. Even in the weather resistance test with a total UV exposure of 60 kW/m2, the properties of the encapsulants were mostly stable. EVA and POE-based encapsulants showed slight differences, and these slight differences are believed to pose a threat to long-term stability. This study is a basic analysis of encapsulation research for PV modules and will be helpful in understanding future development and encapsulant properties.

Experimental Evaluation of Weathering Performance for Duplex Coating Systems Combining Thermal Spraying Metals and Painting (금속용사와 도장의 복합피복방식법에 대한 실험적 내후성능평가)

  • Kim, In Tae;Jun, Je Hyong;Cha, Ki Hyuk;Jeong, Young Soo;Ahn, Jin Hee
    • Journal of Korean Society of Steel Construction
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    • v.28 no.5
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    • pp.373-382
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    • 2016
  • Painting or thermally sprayed metal coating is often used in corrosion protection of steel structures. In recently, duplex coating system which combines thermally sprayed metals with paint is selected as a new generic type of coatings on steel structures under the highly corrosive environments. In this study, the structural steel specimens were surface treated, thermally sprayed with zinc, zinc-15%aluminum alloy, aluminum and aluminum-5%magnesium alloy, and finally sealing or painted with acrylic urethane. And as a reference specimens, steel specimens were painted with acrylic urethane after surface treatment. Circular defects with 1.0, 3.0 and 5.0 mm in diameters and line defect with 2.0 mm width, which reach the steel substrate were created on all specimens. The specimens were exposed into an environmental testing chamber controlled by the ISO 20340, which is a laboratory cyclic accelerated exposure test condition of spraying/UV/low temperature, for up to 175 days. Based on the corrosion tests, corrosion deterioration from the initial defects were evaluated and weathering performance of the specimens are compared.

Color revelation characteristics of color mortar using iron oxide and carbon black (산화철과 카본블랙을 사용한 컬러 모르터르의 색상발현 특성)

  • Seok, Hwa-Song;Hong, Chang-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.156-161
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    • 2020
  • Recently, as there has been growing demand for aesthetic quality in structural materials, the development of excellent color cement concrete having good coloration properties has become a requirement. This study is designed to analyze the basic physical properties of mortar and the properties of keeping the coloration under an ultraviolet ray accelerated weathering test environment according to changes in the mixing ratio between carbon black and iron oxide used as colorants. The test results show that the use of carbon black and iron oxide reduces the initial flow by 6.3~17.2 % and the air content by 3.5~31.5 % but increases the unit volume weight by 3.4~5.5 %, compared to ordinary Portland cement (OPC). In addition, the study shows that the addition of iron oxide increases the self drying shrinkage. So, caution needs to be taken on the workability of the concrete. The brightness value L represented by black showed the most excellent black colour when carbon black 3 % and iron oxide 5 % are added. According to UV accelerated weatherproof test, the brightness value L was found to increase in all experiment specimens by 4.28~11.97 %, and the color change by UV was found to be higher for the case where carbon black colorant was not used. Therefore, in terms of color revelation characteristics, the case using carbon black 3 % and iron oxide 5 % was found to show the best black color.

Characteristics Evaluation of Hobun Pigments according to Shell Types and Calcination (패각의 종류 및 소성 여부에 따른 호분안료의 특성 평가)

  • Ju Hyun Park;Sun Myung Lee;Myoung Nam Kim;Jin Young Hong
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.899-909
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    • 2023
  • In this study, the material scientific characteristics of Hobun pigments used as white inorganic pigment for traditional cultural heritage were identified according to the type of shell and calcination and evaluated the stability of the preservation environment. For the purpose of this, we collected 2 different types of Hobun pigments made by oyster and clam shell and its calcined products(at 1,150℃). Hobun pigments before calcined identified calcium carbonate such as calcite, aragonite but calcination derived changing main composition to portlandite and calcite. Results of FE-SEM showed characteristics microstructure for each shell but pigments after calcined observed porous structure. Porous granule highly caused oil adsorption according to increase specific surface area of pigments. In addition, the whiteness improved after calcined pigments compared to non-calcined pigments, and the color improvement rate of Hobun pigment (CS) which made of clam shell was higher. As a result of the accelerated weathering test, the Hobun pigment-colored specimen had a color difference value of less than 2 after the test, which was difficult to recognize with the naked eye. In particular, the color stability has improved as the color difference value of the Hobun pigment is smaller after calcined compared to before non-calcined pigment. However, it was confirmed that the stability of the painting layer was lower in the specimen after calcined pigment. For antifungal activity test, Aspergillus niger, Tyromyces palustris and Trametes versicolor were used as test fungi, and all pigments were found to have preventive and protective effects against fungi. Especially, the antifungal effect of the calcined pigment was excellent, which is due to the stronger basicity of the pigment.

Modeling Study on Deterioration of Stone Monuments in the Gyeongju Namsan Mountain by Acid Rain (산성비에 의한 경주남산지역 석조문화재의 손상 임상연구)

  • Do, Jin-Young;Choi, Gi-Joo;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.1
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    • pp.35-47
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    • 2009
  • The deteriorations of stone monuments located in Gyeongju area are predicted in a modeling study. Artificial rain and accelerated weathering test are here applied to the Gyeongju Namsan granite and cement mortar. They are reacted with pH 4.0, pH 8.0 and pH 5.6 rain, respectively. The two former values are the limited acidity values in the Gyeongju (the acidity of rain of the Gyeongju were pH $4.93{\sim}6.39$ in 2005) and the latter is the limited acidity of acid rain. The rains of pH 5.6 and pH 8.0 reach close to a value of pH 7.0 after the reaction with the Gyeongju Namsan granite. After application of the artificial rain and weathering test, the weight of specimens were reduced and the contents of soluble ions in the specimens were increased. These results are attributable to solution of minerals in the specimens. At first, the microlithic have dissolved in ground from the reaction with acid rain. And then mainly quartz, plagioclase and orthoclase bound by the microlithic are disintegrated. The cement mortars are dissolved after the reaction with not only acid but alkali rain. The concentrations of ions in the dissolved cement mortar are higher than those in granite.

Basic Characteristics and Application of Modern Dancheong Pigment Jangdanyuksaek (Incarnadine) (현대 단청용 장단육색의 기본 특성 및 사용 기준 연구)

  • Kim, Eun Ji;Chung, Kwang Yong
    • Journal of Conservation Science
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    • v.31 no.4
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    • pp.457-476
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    • 2015
  • This study is expected to present instructions and analysis of Modern Dancheong pigments by its physical characteristics. Search pigments currently used and experiments proper mixing ratio of Jangdanyuksaek(Incarnadine). Samples are made by based on presented a mixture ratio which is less exfoliation, cracks and color change. And put into accelerated weathering test and ultraviolet ray degradation test. As a result in case of Jidang($TiO_2$) Rutile type is superior in discoloration and durability. Rutile type makes color difference remarkably because of oil absorption difference while mixing with Jangdan. Water paints which are used as a alternative present yellowness which means water paints lack in durability. whiting should be taken carefully as it has high brightness after degradation.

Durability and Bioassay of a Sulfur Polymer Surface Protecting Agent for Concrete Structures (콘크리트 구조물용 유황폴리머 표면보호재의 내구성능 및 생물독성)

  • Seok, Byoung-Yoon;Lee, Byung-Jae;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.29-36
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    • 2015
  • In this study, to examine the use of sulfur polymer as a coating agent for concrete, durability and hazard evaluations were performed. The result of the evaluation indicated that the chemical resistance of the coating agent for concrete was outstanding against acidic, base, and alkaline solutions. The evaluation of the bond strength after an accelerated weathering test depending on the mixing condition indicated that the most outstanding strength characteristic was obtained when silica powder and fly ash were mixed at the same time. The bond strength exceeded 1 MPa in every mixing condition even after the repeated hot and cold treatment of the coating agent specimen for concrete, and the SFS mix proportion showed the highest bond strength. The examination of the accelerated carbonation and chloride ion penetration resistance of the concrete coated with the coating agent indicated that the specimen coated with the coating agent using silica powder as a filler showed the most outstanding durability. When a fish toxicity test was performed to examine the hazard of the use of the functional polymer as a coating agent for concrete, the functional polymer was found to have no effect on the organisms. When the chemical resistance, freezing and thawing resistance, carbonation, and chloride ion penetration resistance of the coating agent were considered, substituting silica powder and fly ash as the fillers of the functional polymer by 20%, respectively, was the optimal level in the range of this study.

A Study on Comparison of Outdoor Wind Pressure Performance According to Outdoor Exposure and Acceleration Deterioration Methods of Structural Sealants Applied to Curtain Wall (커튼월에 적용된 구조용 실링재의 옥외폭로와 실내복합열화 처리방법에 따른 내풍압성능 비교연구)

  • Jang, Pil Sung;Hong, Soon Gu;Kim, Sung Rae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.279-287
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    • 2018
  • Sealants are an important element of modern architecture and serve as a building protection against weathering by providing barriers against ingress of moisture, air, and other materials. Exposure to a variety of environments often reduces lifespan due to changes in physical, chemical and mechanical characteristics, and UV, humidity, and temperature expansion are important issues that are directly related to durability. In this study, a combined deterioration test chamber was developed to simulate the environment of the open air as an instrument for verifying the durability of structural sealing materials indoors. In order to replicate special weather conditions, such as yellow dust, acid rain, and contamination by microorganisms, it was deemed impossible to replicate the outdoor environment by 100 %, and the results of the results of the results of the external exposure test of the structural sealant and the combined deterioration testing device. As a result of the displacement test of the outdoor exposure test, it was determined that the sealant was breaking apart and that it would be smooth, and the displacement would be up to three times greater than the initial material value of 1 year. The displacement test results of the combined deterioration test device show the tendency to deteriorate, decreasing the elasticity and tensile characteristics. In the case of denatured silicon, the current 400 cycles have been completed to confirm 12 months of degradation of the external exposure. The deformation of the test specimen cannot be verified with the naked eye, so it is considered that the conditions of the specimen are more stable than the silicon sealant. As a result of the outdoor exposure test, if the combined deterioration test device is structured and proposed in the relevant guidance or specification, the anticipated lifespan of 12 months in the actual use environment can be verified indoors and below 3 months later, economically.

Color Change of Major Wood Species Planted in Indonesia by Ultraviolet Radiation (자외선 조사에 의한 인도네시아 주요 조림수종 목재의 재색변화)

  • Park, Se-Hwi;Jang, Jae-Hyuk;Qi, Yue;Hidayat, Wahyu;Hwang, Won-Joong;Febrianto, Fauzi;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.9-18
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    • 2016
  • This study was performed to understand wood durability to climate deterioration of planted Indonesian wood specie such as Albizia, Gmelina, Mangium and Mindi. Wood samples were exposed to indoor and outdoor condition. $L^*a^*b^*$ and Color changes (${\Delta}E*ab$) were determined by a spectrophotometer. As a result, color of all samples was changed more markedly by ultraviolet radiation. In indoor test with UV, brightness of wood specimens from four species was not changed and all samples were changed into more reddish and yellowish. In accelerated weathering test, all samples were bleached and changed into more greenish and blueish. In outdoor test, brightness of wood specimens decreased in Albizia and Gmelina and increased in Mangium and Mindi. All wood specimens in outdoor test were changed into more greenish and blueish. Albizia and Gmleina woods showed greater color change than those of Mangium and Mindi. Especially, color change of wood samples might be influenced greatly by moisture. In conclusion, wood color changed into more clearly by UV radiation. Therefore, exposing woods to UV radiation could be one of reasonable methods to improve wood quality on visual characteristic.