• Corrosion Science and Technology
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• v.13 no.6
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• pp.214-223
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• 2014

Interest in the durability assessment and structural performance has increased according to an increase of concrete structures in salt damage environment recent years. Reliable way ensuring the most accelerated corrosion test is a method of performing the rebar corrosion monitoring as exposed directly to the marine test site exposure. However, long-term exposure test has a disadvantage because of a long period of time. Therefore, many studies on reinforced concrete in salt damage environments have been developed as alternatives to replace this. However, accelerated corrosion test is appropriate to evaluate the critical chlorine concentration in the short term, but only accelerated test method, is not easy to get correct answer. Accuracy of correlation acceleration test depends on the period of the degree of exposure environments. Therefore, in this study, depending on the concrete mix material, by the test was performed on the basis of the composite degradation of the salt damage, and investigate the difference of corrosion initiation time of the rebar, and indoor corrosion time of the structure, of the marine environment of the actual environments were inuestigated. The correlation coefficient was derived in the experiment. Long-term exposure test was actually conducted in consideration of the exposure conditions submerged zone, splash zone and tidal zone. The accelerated corrosion tests were carried out by immersion conditions, and by the combined deterioration due to the carbonation and accelerated corrosion due to wet and dry condition.

• Journal of the Korea Institute of Building Construction
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• v.3 no.4
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• pp.103-109
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• 2003

Reinforced concrete structures under sever conditions such as marine structures, bridges and structural constructed with aggregated(dredged front sea). can be deteriorated from corrosion of the reinforcing bars. The purpose of this study is to evaluate the corrosion reflectance of coated steel using polymer dispersion and polymer cement slurry. Polymer dispersion and polymer cement slurry with various polymer types were coated to the surface of bars and steel plate, and tested for accelerated corrosion tests. Tests include adhesion in tension, bending test, chloride ion spray, penetration of NaCl 10％ solution and carbonation. From the test results, the corrosive resistance of steel is considerably improved by using polymer dispersion and polymer cement flurry at surface of steel. The difference of the corrosive resistance is hardly recognized according to types of polymer dispersion. The coated steel using polymer dispersion and polymer foment slurry will be improved to a great extent compared to those of plain steel when increasing content of chloride ion in cement concrete.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.1-6
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• 2016

In this year, Koreans have a shortage in agricultural and drinking water due to severe algal blooms generated in major lakes. Waste oyster shells were obtained from temporary storage near the workplace at which oysters were separated from their shells. Heating ($1000^{\circ}C$ for 1 h in air) was employed to convert raw oyster shell powders into calcium oxide powders that reacted efficiently with phosphorus and nitrogen to remove algal blooms from eutrophicated wastewater. As the dispersed amount of heated oyster shell powders was increased, water clarity and visual light penetration were improved. Coagulation, precipitation and carbonation process of the heated oyster shell powders in a water purifier facilitated removal of eutrophication nutrient such as phosphorus and nitrogen, which is both beneficial and economically viable. $CO_2$ implantation by carbonation treatment not only produced thermodynamically stable CaO in oyster shells to derive precipitated calcium carbonate (PCC) but also accelerated algal removal by activation of coagulation and precipitation process. The use of oyster shell powders led to a mean reduction of 97% in total phosphate (T-P), a mean reduction of 91% in total nitrogen (T-N) and a maximum reduction of 51% in chemical oxygen demand (COD), compared with the total pollutant load of raw algal solution. Remarkable water quality improvement of algal removal by heated oyster shell powders and PCC carbonation treatment will allow utilization as water resources to agricultural or industrial use.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.2
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• pp.125-132
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• 2015

This paper presents an experimental investigation in order to evaluate fresh and hardened properties of LP (Limestone Powder) blended cement concrete. The cement contents of the mixtures are replaced by LP in the range of 10%, 15%, 25%, and 35%, while a control mixture is prepared with only OPC (Ordinary Portland Cement). The fresh concrete properties like slump and air content are similar to those of control mixture up to 35% of replacement ratio of LP, however a delay in setting time is evaluated. The hardened properties including compressive strength, flexural strength, and rapid freezing and thawing resistance shows similar results of control mixture up to 15% of replacement. Relatively lower strength development is evaluated over 25% replacement of LP. For accelerated carbonation test, resistance to carbonation rapidly decreases with increasing LP replacement ratio due to the limited amount of $Ca(OH)_2$. From the study, LP replacement under 15% can be adopted considering reduction of strength and resistance to carbonation.

• Journal of the Korea Concrete Institute
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• v.18 no.5 s.95
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• pp.667-675
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• 2006

Concrete is much more easily damaged by various parameters than by the only one and performance reducing mechanism grows more complicated in that condition. In addition, the factors which really act in concrete structure tend to be activated in turn and the degradation of concrete is very rapidly progressed. The purpose of this study is to evaluate the properties of polymer cement mortars under combined cures. The polymer cement mortars are prepared with various polymer types, polymer-cement ratios and cement-fine aggregate ratio, and tested for compressive and flexural strengths, accelerated carbonation, chloride ion penetration and acid resistance test, and freezing-thawing test. The properties of polymer cement mortars under combined cures is discussed. From the test results, polymer cement mortars have superior strengths compared with plain cement mortar under combined cures. The strengths of polymer cement mortars are markedly increased at curing condition II and V, however strengths are not improved at curing condition I and IV irregardless of polymer types. The carbonation and chloride ion penetration depths of polymer cement mortars tend to decrease in curing conditions, III-C, IV-B, V-A order, and decrease with increasing polymer cement ratios. It is concluded that polymer cement ratio of 10 to 15% are considered optimum for the preparation of such polymer cement mortars.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.34 no.3
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• pp.86-91
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• 2024

In this study, the characteristics of mortar using carbondioxide conversion capture materials (CCMs), fabricated by reacting CO₂ with desulfurization gypsum (DG) by-produced from a oil refinery, as a cement mixture. Based on the chemical component and particle size analysis results, it estimated that desulfurized gypsum reacted with carbon dioxide to produce carbonate crystals such as CaCO₃. Using CCMs as a cement mixture, physical property and durability analysis were conducted by measuring such as workability, compressive strength, compressive strength ratio after freezing-thawing and accelerated carbonation depth. The experimental results showed that as the content of the admixture increased, workability and compressive strength characteristics decreased. Compressive strength after freezing-thawing and accelerated carbonation depth also showed similar characteristics to the physical property measurement results. In addition, compared to desulfurized gypsum, using CCMs showed better physical properties and durability. This was assumed to be due to differences in the crystal phases of the mixed materials such as free-CaO and CaCO₃.

• Proceedings of the KSR Conference
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• 2006.11b
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• pp.1385-1390
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• 2006

Concrete structure can be deteriorated by ingress of moisture and aggressive agents. To maintain the sound performance of concrete structure during the service life, it needs to protect concrete from ingress of moisture and aggressive agents before arising deterioration of concrete. Protection of concrete is possible by surface treatment. In this study, durability of the functional nano composite inorganic activated carbon based coatings which can provide a barrier against the ingress of moisture or aggressive ions to concrete is discussed. For the durability evaluation of the coatings, fine void structure evaluation test, chloride penetration acceleration test, accelerated carbonation test, freezing and thawing test, and the accelerated test of chemical erosion are conducted. As the result of this study, the functional nano composite inorganic activated carbon based coatings which became one formed complex compound with adsorption and porosity on concrete surface, had an effect on the function of far infrared radiation, antimicrobial action, air cleaning, airing assurance, and the interception of moisture of deterioration factor, chloride ion, carbon dioxide, sulfate, and so on.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.549-554
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• 2001

It is possible for concrete using sea sand to contain chloride ion as well as cation such as Na$^{+}$and $K^{+}$ during mixing process. It is known that some cations such as Na$^{+}$and $K^{+}$ remain in pore solution without binding In this study, therefore, we intend to inspect the behavior of cations in cement paste as well as NaCl, CaCl$_2$ and KCI through analysis of pore solution extracted from cement paste with high pressure vessel. As a result, increase of alkali ions by adding sea sand and admixtures to the fresh concrete means use of the cement contained high alkali contents. In this case, alkali ions in pore solution can decrease durability of cement products causing alkali-aggregate reaction or accelerated carbonation. So it needs to be studied.studied.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.725-730
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• 2002

The durability of concrete involves resistance to freeze-thaw action, corrosion, permeation, carbonation, chemical attack and so on. Generally, properties of concrete have been well understood under the separate action of these deterioration mechanisms. However, in practice, the degradation of concrete usually is the result of combined action of physical and chemical attack and can be accelerated by the combined action of several deterioration mechanisms. In the present study, to evaluate the combined deterioration by freeze-thaw action and seawater attack, ground granulated blast-furnace slag or silica fume concrete with water or seawater as mixing water was exposed to 210 cycles of freeze-thaw action. Tests were conducted to determined the relative dynamic modulus of elasticity and compressive strength. Furthermore, The XRD, SEM and EDS analysis were performed on the deteriorated part of concrete due to freeze-thaw action and seawater attack.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.285-291
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• 1998

During recent years, the durability of concrete structures has been considered in concret practice and material research. To preserve the brittleness of concrete as well as energy absorption and impact resistance, amount of fiber usage has greatly increased in the field of public works. Ultra fine powder, silica fume, mixed into concrete, it reduce void of concrete structure. Especially, there's a great effect for strength improvement of concrete by initial pozzolanic reactions. For these reasons, if silica fume mixed into concrete, it decrease the total void by microfilter effect . Pozzolan reaction, between cement particle and silica powder, can elaborate the micro structure of matrix. And so, in this paper, we deal SFRC for the purpose of efficiently using of industrial by-products(silica fume). Also we performed the test for durability such as freeze-thaw resistance and accelerated carbonation of SFRC using silica fume.