• Title/Summary/Keyword: Ac.I.

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A Review of Ac-impedance Models for the Analysis of the Oxygen Reduction Reaction on the Porous Cathode Electrode for Solid Oxide Fuel Cell

  • Kim, Ju-Sik;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.106-114
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    • 2005
  • This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

Ab Initio Conformational Study on Ac-Pro-$NMe_2$: a Model of Polyproline

  • Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.75-75
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    • 2003
  • We report here the results on N-acetyl-N'-dimethylamide of proline (Ac-Pro-NM $e_2$) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level with the 6-31+G(d) basis set to investigate the conformational preference of polyproline depending on the cis/trans peptide bonds and down/up puckerings along the backbone torsion angle $\square$ in the gas phase, chloroform, and water. In the gas phase, Ac-Pro-NM $e_2$ has seven local minima of tFd, tFu, cFd, cFu, cAu, tAu, and cAd conformations. In particular, polyproline conformations tFd, tFu, cFd, and cFu are found to be more stable than $\square$-helical conformations cAu, tAu, and cAd. In contrast, Ac-Pro-NHMe has seven local minima of tCd, tCu, cBd, cAu, tAu, cFd, and cFu conformations. Conformations tCd and tCu are found to be most stable, which is ascribed to the intramolecular hydrogen bond between C=O of acetyl group and $N^{~}$ H of N'-methyl amide group. The stability of the cFd conformation (i.e., the polyproline I structure) in chloroform is somewhat increased, relative to that in water, although tFd and tFu conformations (i.e., the polyproline II structure) are dominate both in chloroform and water. The population of backbone conformations feasible in chloroform and water is consistent with the experiments. This work is supported by a Korea Research Foundation Grant (KRF-2002-041-C00129).

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Improved Performance characteristics of an inverter-fed ac servo motor drives (인버어터 구동에 의한 교류(交流) 서어보 전동기(電動機)의 운전특성 개선에 관한 연구)

  • Son, Y.S.;Hong, S.I.;Park, H.S.
    • Proceedings of the KIEE Conference
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    • 1994.07a
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    • pp.287-289
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    • 1994
  • The ac servo system using an induction motor is so strong and inexpensive that it is most suitable for today's drive systems. For controlled ac motor drives, but slip frequency vector control system have been put to practical use, it is difficult to perform control of wide range, the same as de motor. A study is presented on an adaptive current control scheme for induction type ac servo motor drives using PWM inverter. An analysis of the control scheme in operations is given and the characteristics are studied by simulation. The implementation of the control scheme using a microprocessor-based system is considered.

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Development of 5[KVA] AC Power Source for Harmonics Generation (고조파 발생을 위한5[KVA]급 AC Power Source 개발)

  • Choi, M.G.;Yoo, J.G.;Lee, S.I.;Jeong, J.C.;Choe, G.H.;Mok, H.S.
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.131-133
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    • 2005
  • Recently the harmonic generation has declined electricity quality and has bad influence on the electrical installation including OA(Office Automation), FA(Factory Automation), IT(Information Telecommuni-cation) devices and so on. The study of harmonics be greatly interested in diagnosis accident with harmonics was not merely guesswork but clarify the cause by experimental data at these days. Therefore, it is necessary development of AC power source for correct experiment with reliable data. In this paper, we realized the AC power source that can produce and compose harmonics for analysis of accident with harmonics.

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AC Loss Measurement and Analysis of Ag-sheathed Bi-2223 Conductors in Terms of Eddy Currents and Flux Creep

  • Jang, Mi-Hye
    • KIEE International Transactions on Electrophysics and Applications
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    • v.3C no.6
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    • pp.211-215
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    • 2003
  • Alternating current (AC) losses of two Bi-2223 ([Bi, Pb] : Sr : Ca : Cu :O = 2:2:2:3) tapes [one untwisted (Tape I, twist-pitch of $\infty$ mm) and the other with a twist-pitch of 8mm (Tape II) ] were measured and compared. These samples, produced by the powder-in-tube (PIT) method, are multi-filamentary and have a Ag/Au and Ag matrix, respectively. Susceptibility measurements were conducted while cooling in a magnetic field. Flux loss measurements were conducted as a function of ramping rate, frequency and field direction. The AC flux loss increases as the twist-pitch of the tapes decreased, in agreement with the Norris Equation.

Current Distribution and Numerical Analysis of AC Losses on Multi-Layer HTS Cable (다층 고온 초전도 케이블의 전류 분포 및 교류손실 해석)

  • 김영석;이병성;장현만;곽민환;김상현
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.452-455
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    • 2000
  • Superconducting power cable is one of the most promising energy application of high-T$_{c}$ superconductors (HTS). A prototype HTS cable have been constructed multi-layer cable using Bi-2223 tape and tested. The AC transport losses under self field were investigated at 77K on the 19 filamentary tape and multi-layer HTS cables. And we carried out numerical analysis using bean model. The result shows that the total transport current of HTS cable in L$N_2$ was 475[A], and transport current passed through almost the outer layer (2-layer). Also, AC transport losses in outer layer of HTS cable was proportion to I$^2$ and higher than losses of inner layer. In case of Ip=Ic, calculated numerical loss density was concentrated on the edge of tape and most of loss density in cable was distributed outer layer more than inner layer. As magnetic distribution was concentrated on outer layer.r.

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An Economic Analysis of Potential Cost Savings from the Use of Low Voltage DC (LVDC) Distribution Network

  • Hur, Don;Baldick, Ross
    • Journal of Electrical Engineering and Technology
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    • v.9 no.3
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    • pp.812-819
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    • 2014
  • The proposed technical work attempts to compare the two key technologies of power distribution, i.e. direct current (DC) and alternating current (AC) in a fiscal manner. The DC versus AC debate has been around since the earliest days of electric power. Here, at least four types of a low voltage DC (LVDC) distribution are examined as an alternative to the existing medium voltage AC (MVAC) distribution with an economic assessment technique for a project investment. Besides, the sensitivity analysis will be incorporated in the overall economic analysis model to cover uncertainties of the input data. A detailed feasibility study indicates that many of the common benefits claimed for an LVDC distribution will continue to grow more profoundly as it is foreseen to arise with the increased integration of renewable energy sources and the proliferation of energy storage associated with the enhanced utilization of uninterruptible power supply (UPS) systems.

Sensorless Current Balancing and MPPT Control For Photovoltaic AC Module Type Interleaved Flyback Inverter (태양광 AC 모듈형 인터리브드 플라이백 인버터에서의 입력 단 센서를 제거한 최대 전력점 추종 및 전류 평형 제어 기법)

  • Kang, Ju-Suk;Kim, Young-Ho;Youn, Sun-Jae;Jung, Yong-Chae;Won, Chung-Yuen
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.501-502
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    • 2012
  • 본 논문에서는 입력 단 센서를 제거한 태양광 AC 모듈 인터리브드 플라이백 인버터의 최대 전력점 추종 및 전류 평형 제어 기법을 제안한다. 기존 제어 방식들의 수행을 위해서는 입력 전압 $V_{pv}$, 입력 전류 $I_{pv}$ 센서와 각 상 스위치 단의 전류 센서들이 필요하나 4개의 센서와 주변 회로는 AC 모듈의 사이즈, 부피 및 가격을 증가시킨다. 이러한 문제점들을 해결하기 위해 제안하는 방식은 각 상의 전류 센서만을 사용하여 최대 전력점 추종 및 전류 평형 제어를 동시에 수행한다. 제안한 시스템의 타당성을 이론적 분석과 시뮬레이션을 통해 검증한다.

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A Study on the Catechins Contents and Antioxidative Effect of Various Solvent Extracts of Green, Oolong and Black Tea (녹차, 우롱차 및 홍차의 용매별 추출물의 카테킨류 함량 및 항산화효과에 관한 연구)

  • 이영자;안명수;오원택
    • Journal of Food Hygiene and Safety
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    • v.13 no.4
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    • pp.370-376
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    • 1998
  • The extraction yield of MeOH extract of green teas, oolong tea and black tea were 3 to 5, 4 to 5, and 5 to 7 fold higher than those of EtOH and EtAC extract, respectively. The amount of total catechins of EtAC extract of the black tea, and of the green teas and oolong tea were three- and two-fold higher than that of EtOH or MeOH extract of the corresponding teas, respectively. The antioxidative activities of EtOH, MeOH and EtAc extract were considerably higher than that of BHT and $dl-{\alpha}-tocopherol$ at 200 ppm level. The antioxidative activities of EtOH and MeOH extract at 200 and 500 ppm level, and of EtAc extract at 200 ppm level varied depending on the type of tea as follows : green tea I > green tea II > green tea III > oo-long tea> black tea. The antioxidative activity increased as the content of EGC increased. But the antioxidative activity of MeOH extract at 1000 ppm level, and of EtAc extract at 500 and 1000 ppm level were not affected by the content of EGC and EGCG.

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Anti-allergic Effect of Eckolona cava Ethyl Acetate Fraction of on IgE/BSA-stimulated Bone Marrow-derived Cultured Mast Cells (IgE/BSA가 자극한 골수유래 비만 세포에 대한 감태 Ethyl Acetate 분획물의 항알러지 효능)

  • Han, Eui Jeong;Kim, Hyun Soo;Shin, Eun Ji;Kim, Min Ju;Han, Hee-Jin;Jeon, You-Jin;Jee, Youngheun;Ahn, Ginnae
    • Journal of Chitin and Chitosan
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    • v.23 no.4
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    • pp.277-284
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    • 2018
  • In this study, we investigated the anti-allergic effect of the ethyl acetate fraction of Ecklonia cava (EC-EtoAc) on the immunoglobulin E (IgE)/bovine serum albumin (BSA)-mediated activation of bone marrow-derived cultured mast cells (BMCMCs). We revealed that the $62.5{\mu}g/ml$ of EC-fractions ($EC-CHCl_3$, EC-Hexane and EC-EtoAc) inhibited IgE/BSA-activated ${\beta}$-hexosaminidase release from BMCMCs without cytotoxicity. Especially, EC-EtoAc showed the higher ${\beta}$-hexosaminidase release than the others. Also, EC-EtoAc reduced the expression levels of cytokines such as interleukin (IL)-$1{\beta}$, IL-4, IL-5, IL-6, IL-10, IL-13, interferon (IFN)-${\gamma}$ and tumor necrosis factor (TNF)-${\alpha}$ and a chemokine, thymus- and activation-regulated chemokine (TARC), compared to the only IgE/BSA-treated BMCMCs. Furthermore, EC-EtoAc significantly prevented the binding of IgE to Fc epsilon receptor $(Fc{\varepsilon}R)I$ and reduced the $Fc{\varepsilon}RI$ expression on the sensitized BMCMCs. Taken together, these results suggest that E. cava may be the natural agent with beneficial potentials for the treatment of type I allergic diseases induced by mast cell activation.