• Title/Summary/Keyword: Absorption-Reduction

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Hydride Generation-Atomic Absorption Spectrophotometric Determination of Total Selenium in Atmospheric Particulate (환원기화 원자 흡광광도법에 의한 대기분진중의 총 셀렌의 정량)

  • 이용근;최건형;이동수;황규자
    • Journal of Korean Society for Atmospheric Environment
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    • v.6 no.2
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    • pp.147-154
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    • 1990
  • A sensitive method for the determination of total selenium in aerosol particles is described. The method involves dissolution of aerosol particles by $HNO_3-HClO_4$ mixed acids, pre-reduction of Se (VI) to Se (IV) by boiling hydrochloric acid, and hydride generation followed by atomic absorption detection. Dissolved Se (IV) in 4M hydrochloric acid is reacted with $NaBH_4$ to form $H_2Se$, which is subsequently collected in an U-tube cooled in liquid nitrogen. Upon the completion of $H_2Se$ generation, the collected $H_2Se$ is rapidly vaporized into a quartz cuvette burner by removing the U-tube from liquid nitrogen, atomized, and then detected by an atomic absorption spectrophotometer. The absolute sensitivity of the method is 0.49 ng/0.0044 Abs. The accuracy of the method evaluated by analyzing standard reference materials for urban aerosol is better than 10%. Analytical results for urban and rural aerosol particles are reported.

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Spectroscopic Study of the Ã1A" - X~1A' System of CHBr

  • Shin, Seung-Keun;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.905-908
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    • 2011
  • We report fluorescence excitation and emission spectra of the CHBr molecule generated via pyrolysis of $CH_3Br$ in a molecular beam experiment. The 193 nm attenuation cross sections were estimated from the reduction of the CHBr signal as a function of the excimer laser fluence. The derived 193 nm absorption cross section for CHBr [$(3.24{\pm}0.59){\times}10^{-17}\;cm^2$] is slightly higher than the absorption cross section previously determined for CHCl [$(2.6{\pm}0.8){\times}10^{-17}\;cm^2$], but the difference is within the estimated uncertainties in the measured cross section.

The Fundamental Properties of Carbon Dioxide Absorption Concrete using Photosynthetic Bacterium Added (광합성균을 첨가한 이산화탄소 흡수 콘크리트의 기초적 특성)

  • Lim, Ji-Hee;Lee, Gun-Cheol;Yoon, Seung-Joe;Jung, Jae-Ho;Kim, Young-Min
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.73-74
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    • 2013
  • In this study, we examined the properties of the concrete for the adsorption of carbon dioxide by adding in photosynthetic bacteria. As for the experimental plan, we measured slump, carbon dioxide concentration and compressive strength. The findings revealed the non-plastic cement added with photosynthetic bacteria had the greatest flexibility and showed carbon dioxide absorption and condensation delay due to the sugar constituents of photosynthetic bacteria. Giver the progress in the studies on the strength development, it is estimated to be used as CO2 reduction concrete.

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Effect of Deuterated Solvents on the Excited State Photophysical Properties of Curcumin

  • Barik, A.;Goel, N.K.;Priyadarsini, K.I.;Mohan, Hari
    • Journal of Photoscience
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    • v.11 no.3
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    • pp.95-99
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    • 2004
  • Optical absorption and emission studies have been carried out to understand the effect of deuterium on the solvent dependent photophysical properties of curcumin in deuterated solvents such as $CDCl_3,\;(CD_3)_2SO,\;(CD_3)_2CO,\;CD_3OD\;and\;CD_3CN$. Optical absorption spectral studies showed that there is no significant shift in absorption maxima compared to the non-deuterated solvent. The fluorescence maxima shows significant shift with polarity of solvent but not much affected by the deuteration. The fluorescence quantum yield of curcumin increased marginally in almost all the deuterated solvents, indicating reduction in the non-radiative pathways. The fluorescence decay was biexponential in all the solvents and the average fluorescence lifetime was not much affected with deuteration, but showed decrease with increasing solvent polarity. Based on these studies, it is concluded that intermolecular hydrogen transfer is only partially responsible for the excited state deactivation of curcumin.

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Annealing Effect on Magnetic Properties and Electromagnetic Absorption Behaviors for Fe-Cr Alloy Powder-Polymer Composites

  • Lee, Sung-Jae;Kim, Yoon-Bae;Lee, Kyung-Sub;Kim, Sang-Woo
    • Journal of Magnetics
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    • v.12 no.1
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    • pp.49-52
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    • 2007
  • We investigated annealing effect of microforged powders on magnetic properties and electromagnetic absorption behaviors for ferromagnetic Fe-Cr metal alloy powder-polymer composites. The coercive properties greatly decreased with annealing temperature and the magnetic permeability had significantly increased after microforging and subsequent annealing treatment, due to a reduction in lattice strain of the microforged powders. The power loss in the far field regime also had greatly increased after microforging and subsequent annealing treatment in frequency range from 50 MHz to 6 GHz. As a result, the electromagnetic absorption of ferromagnetic Fe-Cr alloy metal powder-polymer composites was highly improved because of the relaxation of the internal strain during annealing process.

Reduction Kinetics of Gold Nanoparticles Synthesis via Plasma Discharge in Water

  • Sung-Min Kim;Woon-Young Lee;Jiyong Park;Sang-Yul Lee
    • Journal of the Korean institute of surface engineering
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    • v.56 no.6
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    • pp.386-392
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    • 2023
  • In this work, we describe the reduction kinetics of gold nanoparticles synthesized by plasma discharge in aqueous solutions with varied voltages and precursor (HAuCl4) concentrations. The reduction rate of [AuCl4]- was determined by introducing NaBr to the gold colloidal solution synthesized by plasma discharge, serving as a catalyst in the reduction process. We observed that [AuCl4]- was completely reduced when its characteristic absorption peak at 380 nm disappeared, indicating the absence of [AuCl4]- for ligand exchange with NaBr. The reduction rate notably increased with the rise in discharge voltage, attributable to the intensified plasma generated by ionization and excitation, which in turn accelerated the reduction kinetics. Regarding precursor concentration, a lower concentration was found to retard the reduction reaction, significantly influencing the reduction kinetics due to the presence of active H+ and H radicals. Therefore, the production of strong plasma with high plasma density was observed to enhance the reduction kinetics, as evidenced by optical emission spectroscopy.

Study of Mobile Phone Antenna for SAR Reduction Concerning Absorption Material Characteristic (흡수체 매질 특성을 고려한 이동통신 단말기 SAR 저감 방안 연구)

  • 정민석;이범선
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2002.11a
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    • pp.104-108
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    • 2002
  • 본 논문에서는 전력보존에 근거하여 휴대 단말기에 의한 SAR 저감 방안을 제시한다. 흡수체 매질에서의 전파의 반사, 흡수 및 투과관계를 고찰하였으며 흡수체의 최대 흡수조건을 만족하기 위한 매질특성을 분석하였다. 정량적인 SAR 저감방식 논의를 위해 SRF(SAR Reduction Factor)를 정의한 후 다양한 흡수체의 구조에 따른 SAR 및 SRF를 분석하였다.

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A Study on Sound Attenuation of Plant Noise by Enclosure (방음실에 의한 공장설비 소음의 감쇠 효과에 관한 연구)

  • 윤세철;이해경
    • Journal of the Korean Society of Safety
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    • v.9 no.4
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    • pp.119-124
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    • 1994
  • The considerations in the noise control by enclosure are the rise of temperature and sound pressure, transmission loss, absorption coefficient of the materials, the structure of the soundproof panels, an opening and coincidence frequency. But it is very difficult that we obtain the accurate data about those in design, so, the noise reduction after enclosing does not correspond with the calculation. The difference of the noise reduction between the calculation and the measurement was 8.2dBA, and we can obtain the approximate result as the following formula which correct 10dBA, safely.

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Effects of Domperidone, Scopolamine Butylbromide and Cimetidine on Absorption and Bioavailability of Ciprofloxacin in Rats (랫트에 있어서 시프로플록사신의 흡수와 생체이용율에 미치는 돔페리돈, 스코폴라민부틸브로마이드 및 시메티딘의 영향)

  • Yim, Hye-Suk;Park, Gee-Bae;Lee, Do-Ike;Lee, Kwang-Pyo
    • Journal of Pharmaceutical Investigation
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    • v.22 no.2
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    • pp.125-131
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    • 1992
  • The effects of domperidone, scopolamine butylbromide and cimetidine on the absorption and bioavailability of ciprofloxacin were studied in female rats. Ciprofloxacin was given in a single oral dose of 30 mg/kg to control group. Ciprofloxacin was concurrently administered with domperidone $(T_1\;group)$, scopolamine butylbromide $(T_2\;group)$, and cimetidine $(T_3\;group)$ to rats, respectively. Significantly changed pharmacokinetic parameters observed in $T_2$group when compared with control group were first-order absorption rate constant, $Ka(4.43{\pm}0.85$\;versus\;2.86{\pm}0.41\;hr^{-1},\;p<0.05)$, time needed to reach peak concentration, $T_{max}\;(32.27{\pm}2.46\;versus\;51.75{\pm}5.51\;min,\;p<0.05)$, area under the plasma concentration-time curve, AUC $(332{\pm}19\;versus\;477{\pm}27\;{\mu}g{\cdot}min/ml,\;p<0.05)$ and absolute bioavailability, Fabs $(60.6{\pm}3.6\;versus\;87.0{\pm}5.0%,\;p<0.05)$. On the other hand, domperidone and cimetidine did not significantly affect the absorption of ciprofloxacin. It is suggested that when scopolamine butylbromide is selected for clinical use, there is need for awareness of the reduction in absorption rate and the enhancement in absorption extent of ciprofloxacin.

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Absorption Properties of Coarse Aggregate according to Pressurization for Development of High Fluidity Concrete under High Pressure Pumping (고압송용 고유동콘크리트 개발을 위한 가압에 따른 굵은골재의 흡수 특성)

  • Choi, Yun-Wang;Choi, Byung-Keol;Oh, Sung-Rok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.3
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    • pp.122-129
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    • 2016
  • In this study, we developed a pressing device which can reproduce the pressure of concrete inside the conveying pipe as a part of the basic study to development of high fluidity concrete under high pressure pumping. Using this pressing device, we evaluated a absorption properties of aggregate that are crushed coarse aggregate, river gravel and lightweight coarse aggregate according to pressure of coarse aggregate and aggregate inside a high fluidity concrete, focused on the reduction of unit water quantity by pressure. In addition, it was evaluated the compressive strength of high fluidity concrete about before and after of pressive. Test a result, case of condition under the high pressure of 250 bar, absorption ratio of crushed coarse aggregate and river gravel were not increased above the surface absorption, absorption ratio of lightweight coarse aggregate was increased than the surface absorption.