• Bulletin of the Korean Chemical Society
• /
• v.21 no.6
• /
• pp.588-594
• /
• 2000

Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.26 no.4
• /
• pp.395-401
• /
• 2017

Energy absorption capabilities and failure modes of circular tubes made of glass/epoxy with two trigger mechanisms were evaluated. Three types of glass/epoxy tubes were fabricated using a hand lay-up method with unidirectional and woven fabric prepregs tapes, and a filament winding method. The one end of the fabricated tubes was machined for the bevel trigger and tulip trigger. Then, crush tests were conducted at 10 mm/min loading speed, wherein the glass/epoxy tubes were crushed by a brittle fracturing mode combined with fragmentation and lamina-splaying modes. The UD glass/epoxy tubes with a bevel trigger and the filament winded tubes with a tulip trigger showed the maximum and minimum specific energy absorptions, respectively, with a difference of 9.3%. The tube with a tulip trigger exhibited a maximum reduction of 5.7% in the initial peak load; the tube with a bevel trigger showed a maximum increase of 2.9% in the specific energy absorption.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.1
• /
• pp.26-33
• /
• 2004

In general, an absorption chiller or heat pump is operated under the constant cooling water flow rate condition even though the system works with a partial load. The objective of this paper is to study the effect of the cooling water flow rates and the temperature of cooling water on the system performance to find the energy saving methode for the partial load operation of the double effect $H_2O$/LiBr absorption chiller. It is found that the performance of the system is sensitive to the temperature of cooling water than the cooling water flow rate, so the decrease of the performance due to reducing the cooling water flow rate can be overcome with the reduction of the cooling water temperature by 1$^{\circ}C$. The flow rate of the cooling water flow rate ranges from 50％ to 100％ of the flow rate at normal conditions with a partial load. It is also found that the operation cost of the cooling water pump and the cooling tower can be reduced by 23％.

• Journal of Korean Physical Therapy Science
• /
• v.9 no.4
• /
• pp.185-192
• /
• 2002

Ultrasound has been found useful as a therapeutic modality for the reduction of muscular and tendinous spasm. It has also been utilized for pain and other pathologic conditions through the ability of soundwaves to introduce molecules of chemical substances through the skin by a process. Choice of the transmission medium is very important for effective ultrasound treatment in clinical field. The purpose of this study was to analyze the effects of various ultrasound conduction media in regard to ultrasound conductivity and degree of absorption, evaporation and of skin irritation. The media used in this study were Antiphlamine, Sacch lotion, Stereogel, Trastgel, Antiphlamine S lotion, and Mentholatum lotion that have been used in clinical medicine. The study revealed that Antiphlamine was not compatible with a good ultrasound transmitter. Other media excluding Antiphlamine were compatible with a good ultrasound conductor, but they had some drawback with their nature of higher absorption, evaporation and skin irritation. The medium that was prepared by mixing of Antiphlamine with Gel in 1 to 10 ratio was a good ultrasound transmitter and extents of absorption and evaporation and of skin irritation of it were less than the other media.

• Textile Coloration and Finishing
• /
• v.33 no.1
• /
• pp.24-30
• /
• 2021

In this study, PET containing 3% silver ion-exchange zeolite was mixed with cotton in a ratio of 6:4 to prepare a spun yarn to evaluate the tensile strength, absorption speed, absorption rate, antibacterial property, and the efficiency of deodorization. As a result, the following conclusions were obtained. First, it can be confirmed that silver ion exchange zeolite is evenly distributed inside and on the surface of the antimicrobial PET-SF through SEM. It was found that the tensile strength between the CVC sample mixed with silver ion zeolite PET and cotton and the normal cotton 100% sample was slightly lower in the CVC sample. Although the absorption speed and water absorption rate were measured to find out the moisture characteristics, it was confirmed that there was no significant difference. The contact angle was slightly larger in the antimicrobial CVC sample, but the time it took for the moisture to completely penetrate into the knit fabric was 0.85 seconds. In addition, it was found that out of the total mixing ratio, 40% of antibacterial PET was spun with regular cotton to produce yarn, which had an excellent bacteria reduction rate of 99.9% and a deodorization efficiency of 85%.

• Korean Journal of Metals and Materials
• /
• v.47 no.12
• /
• pp.866-872
• /
• 2009

The effects of magnetic powder thickness on electromagnetic wave absorption characteristics in Fe-6.5Si-0.9Cr (wt%) alloy flakes/polymer composite sheets available for quasi-microwave band have been investigated. The atomized FeSiCr powders were milled by using attritor for 12, 24, and 36 h, powder thickness changed from $40{\mu}m$ to $3{\mu}m$ upon 36 h milling. The composite sheet, including thinned magnetic flakes, exhibited higher power loss in the GHz frequency range as compared with the sheets having thick flakes. Moreover, both the complex permeability and the loss factor increased with the decrease in thickness of the alloy flakes. Therefore, the enhanced power loss property of the sheets containing thin alloy flakes was attributed to the flakes of high complex permeability, especially their imaginary part. Additionally, the complex permittivity was also increased with the reduction of flake thickness, and this behavior was considered to be helpful for improvement of the electromagnetic wave absorption characteristics in the composite sheets, including thin alloy flakes.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.9 no.3
• /
• pp.401-409
• /
• 1997

The long term drag reduction characteristics of Habon-G solution were investigated in the KIER pilot-scaled district heating simulation system. Test runs were implemented for 30 days without interruption. Pressure drop, flow rate and power consumption of surfactant (Habon-G) solution were regularly observed and compared with those of plain water. The experimental results suggest that the surfactant can be effectively applied to the DH transmission system for considerably long period wthout significant loss of its drag reduction capability even though the concentration of the additive may gradually decrease in the first stage of the experiment because of absorption.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.11
• /
• pp.2669-2674
• /
• 2009

Controlled reduction of silver alkylcarbamate complexes with hydrogen gas was investigated as a facile synthetic method for high concentrations of silver nanocolloids in organic solvent. Polyvinylpyrrolidone (PVP) was used to stabilize the silver colloids obtained from the chemical reduction. To determine optimum conditions for preparation of the stable and controlled silver colloids with the narrowest particle size and distribution, a large number of experiments were carried out involving variations in the concentrations of the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, and 2-propanol. The initial colloid had a mean particle diameter between 5$\sim$50 nm, as measured by transmission electron microscopy, and exhibited a sharp absorption band in the UV region with a maximum size near 420 nm. After treatment with a reducing agent, the colloids were characterized by ultraviolet-visible spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy.

• Journal of Electrical Engineering and Technology
• /
• v.9 no.2
• /
• pp.622-627
• /
• 2014

A method to reduce the specific absorption rate(SAR) of the antenna for WiMAX mobile communication is proposed in this paper. The SAR reduction is achieved by miniaturizing the physical size of the antenna for the given resonance frequency by devising a metamaterial-composite right- and left-handed(CRLH) configuration-based radiator much smaller than the quarter-guided wavelength adopted a lot in the conventional planar inverted F antenna(PIFA) or modified monopole antenna. The proposed antenna is placed near the head-phantom and its SAR is evaluated by the full-wave simulations(SEMCAD X), where the metamaterial-inspired antenna is shown to have the lower value than a modified monopole as the reference in terms of the SAR.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2003.04a
• /
• pp.117-123
• /
• 2003

This paper deals with pressure ripple and noise reduction characteristics for a hydrostatic transmission(HST) consisting of a variable axial piston pump connected in an open loop to a fixed displacement axial piston motor. Pressure ripples in HST is major source of vibration, which can lead to fatigue failure of components and cause noise. In order to reduce the pressure ripple, an annular tube type hydraulic filter proposes to absorb pressure ripples with the high frequencies components to achieve better noise attenuation in HST. The basic principle tube is applied to propagation of pressure wave, reflection, absorption in cross section of discontinuity and resonance in the hydraulic pipeline. It is experimently confirmed that a hydraulic filter is absorbed to be about 30∼40dB of pressure ripple with high frequencies. These results will assist in modeling and design of noise reduction in hydraulic control systems, and here, should provide a means of designing a quieter HST.