• Title/Summary/Keyword: Absorption wavelength

Search Result 690, Processing Time 0.025 seconds

Preparation and Characterization of Zinc Oxide Prepared by Spray Pyrolysis Method (열분무법으로 제조된 산화아연의 제법과 확인(I))

  • Jin, Eui;Kim, Young Soon
    • Journal of the Korean Chemical Society
    • /
    • v.42 no.6
    • /
    • pp.638-645
    • /
    • 1998
  • By using the spray pyrolysis method, zinc oxide(ZnO) was produced from zinc acetate, the surface morphology of the prepared films was investigated by using scanning electron microscopy. The thickness of ZnO thin film was increased up to 460$^{\circ}C$ and it was 833 nm. The maximum wavelength of absorption was obtained at 365 nm, and the maximum peak of fluorescence at 475 nm and 505 nm. ZnO film have been characterized by XPS, XRD, and SEM. XRD results show that all the films are preferred orientation along the (002) plane which is depend on the substrate temperature. The optimal temperature to produce ZnO was determined at around 460$^{\circ}C$ from measurements of XPS, XRD and photocurrent. It was also shown that the homogeneous particles had the higher photocurrent.

  • PDF

Near Infrared Shielding Properties of Quaternary Tungsten Bronze Nanoparticle Na0.11Cs0.22WO3

  • Moon, Kyunghwan;Cho, Jin-Ju;Lee, Ye-Bin;Yoo, Pil J.;Bark, Chung Wung;Park, Juhyun
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.3
    • /
    • pp.731-734
    • /
    • 2013
  • Reduced tungsten bronze nanoparticles of ternary and quaternary compounds were prepared by adding sodium and cesium to crystal structures of tungsten trioxides ($Na_xCs_{0.33-x}WO_3$, x = 0, 0.11) while maintaining the overall alkali metal fraction at 0.33, in an attempt to control near infrared (NIR) shielding property in the particular wavelength range of 780 to 1200 nm. The structure and composition analysis of the quaternary compound, $Na_{0.11}Cs_{0.22}WO_3$, revealed that 93.1% of the hexagonal phase was formed, suggesting that both alkali metals were mainly inserted in hexagonal channel. The NIR shielding property for $Na_{0.11}Cs_{0.22}WO_3$ was remarkable, as this material demonstrated efficient transmittance of visible light up to 780 nm and enhancement in NIR shielding because of the blue-shifted absorption maximum in comparison to $Cs_{0.33}WO_3$.

DEEP-South: A New Taxonomic Classification of Asteroids

  • Roh, Dong-Goo;Moon, Hong-Kyu;Shin, Min-Su;Lee, Hee-Jae;Kim, Myung-Jin
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.41 no.2
    • /
    • pp.49.1-49.1
    • /
    • 2016
  • Asteroid taxonomy dates back to the mid-1970's and is based mostly on broadband photometric and spectroscopic observations in the visible wavelength. Different taxonomic classes have long been characterized by spectral slope shortward of 0.75 microns and the absorption band in 1 micron, the principal components. In this way, taxonomic classes are grouped and divided into four broad complexes; silicates (S), carbonaceous (C), featureless (X), Vestoids (V), and the end-members that do not fit well within the S, C, X and V complexes. The past decade witnessed an explosion of data due to the advent of large-scale asteroid surveys such as SDSS. The classification scheme has recently been expanded with the analysis of the SDSS 4th Moving Object Catalog (MOC 4) data. However, the boundaries of each complex and subclass are rather ambiguously defined by hand. Furthermore, there are only few studies on asteroid taxonomy using Johnson-Cousins filters, and those were conducted on a small number of objects, with significant uncertainties. In this paper, we present our preliminary results for a new taxonomic classification of asteroids using SMASS, Bus and DeMeo (2014) and the SDSS MOC 4 datasets. This classification scheme is simply represented by a triplet of photometric colors, either in SDSS or in Johnson-Cousins photometric systems.

  • PDF

Photocurrent characteristics of close-packed HgTe nanoparticles in the infrared-wavelength range (적외선 영역에서의 HgTe 나노입자 광전류 특성)

  • Kim, Hyun-Suk;Park, Byung-Jun;Kim, Jin-Hyoung;Lee, Jun-Woo;Kim, Dong-Won;Cho, Kyoung-Ah;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.11a
    • /
    • pp.25-28
    • /
    • 2004
  • Photocurrent spectrum, photoresponse, and I-V measurements were made for close-packed HgTe nanoparticles without organic capping materials to investigate their photocurrent characteristics in the infrared range. In absorption and photoluminescence (PL) spectra taken for the close-packed nanoparticles film, the wavelengths of exciton peaks was red-shifted, compared with organic capped HgTe nanoparticles dispersed in solution. This red-shift is caused by the lessening of the exciton binding energy. The I-V curves and photoresponse for the close-packed nanoparticles film reveal their dark current and fast photoresponse with no current decay, respectively. The observation suggests that the HgTe nanoparticles are a very prospect material applicable for photodetectors in the whole IR range.

  • PDF

Amorphous-to-Crystalline Phase Transition of (InTe)x(GeTe) Thin Films ((InTe)x(GeTe) 박막의 비정질-결정질 상변화)

  • Song, Ki-Ho;Beak, Seung-Cheol;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.3
    • /
    • pp.199-205
    • /
    • 2010
  • The crystallization speed (v) of amorphous (InTe)$_x$(GeTe) (x = 0.1, 0.3 and 0.5) films and their thermal, optical and electrical behaviors have been investigated using nano-pulse scanner (wavelength = 658 nm, laser beam diameter < 2 ${\mu}m$), X-ray diffraction (XRD), 4-point probe and UV-vis-IR spectrophotometer. These results were compared with those of $Ge_2Sb_2Te_5$ (GST) film, comprehensively utilized for phase-change random access memory (PRAM). Both v-value and thermal stability of (InTe)$_{0.1}$(GeTe) and (InTe)$_{0.3}$(GeTe) films could be enhanced in comparison with those of the GST. Contrarily, the v-value in the (InTe)$_{0.5}$(GeTe) film was so drastically deteriorated that we could not quantitatively evaluate it. This deterioration is thought because amorphous (InTe)$_{0.5}$(GeTe) film has relatively high reflectance, resulting in too low absorption to cause the crystallization. Conclusively, it could be thought that a proper compositional (InTe)$_x$(GeTe) films (e.g., x < 0.3) may be good candidates with both high crystallization speed and thermal stability for PRAM application.

Enhanced Efficiency of Nanoporous-layer-covered TiO2 NanotubeArrays for Front Illuminated Dye-sensitized Solar Cells

  • Kang, Soon-Hyung;Lee, Soo-Yong;Kim, Jae-Hong;Choi, Chel-Jong;Kim, Hyunsoo;Ahn, Kwang-Soon
    • Journal of Electrochemical Science and Technology
    • /
    • v.7 no.1
    • /
    • pp.52-57
    • /
    • 2016
  • Nanoporous-layer-covered TiO2 nanotube arrays (Type II TNTs) were fabricated by two-step electrochemical anodization. For comparison, conventional TiO2 nanotube arrays (Type I TNTs) were also prepared by one-step electrochemical anodization. Types I and II TNTs were detached by selective etching and then transferred successfully to a transparent F-doped SnO2 (FTO) substrate by a sol-gel process. Both FTO/Types I and II TNTs allowed front side illumination to exhibit incident photon-to-current efficiencies (IPCEs) in the long wavelength region of 300 to 750 nm without the absorption of light by the iodine-containing electrolyte. The Type II TNT exhibited longer electron lifetime and faster charge transfer than the Type I TNT because of its relatively fewer defect states. These beneficial effects lead to a high overall energy conversion efficiency (5.32 %) of the resulting dye-sensitized solar cell.

Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
    • /
    • v.14 no.3
    • /
    • pp.478-485
    • /
    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

Dyeing properties and colorimetric characteristics for cellulose fabrics dyed with indigo by different reducing conditions (쪽 염료의 환원조건에 따른 섬유소 직물의 염색성과 색채특성)

  • Shin, Judong;Choi, Jongmyoung
    • The Research Journal of the Costume Culture
    • /
    • v.24 no.6
    • /
    • pp.777-787
    • /
    • 2016
  • This study was carried out in order to provide useful data for planning fabrics of summer eco-friendly fashion products. The fabrics used in this study were four cellulose fibers: cotton, cotton/mulberry blended, flax, and flax/lyocell blended. Dyeing with natural indigo was carried out under three different reducing conditions (i.e., general, eclectic, and eco-friendly) that have different reducing agent and pH levels, and hydrosulfite and glucose were used as a reducing agent. The dye uptake (K/S value) of fabrics dyed with natural indigo by a reducing condition was the highest at 660nm. Regardless of the fabrics, dye uptake was the highest under the general reducing condition and the lowest under the eco-friendly reducing condition. Under different reducing conditions, the dye uptake of natural indigo fabrics with the maximum absorption wavelength indicated a difference. The colorfastness of cellulose fabrics that were dyed with natural indigo had a rate of 4 to 5 except for rubbing fastness, which indicated good colorfastness. Additionally, natural indigo-dyed cotton and flax fabrics had good antibiosis. When the color characteristics of fabrics dyed with natural indigo were measured, all of the three reducing conditions created purple blue (PB) colors, and the color characteristics of dyed fabrics by reducing condition and fabric showed significant differences.

Linearity of All Optical Dual EA Modulator for Narrow-band Microwave Optical Transmissions (협대역 마이크로파 광전송을 위한 전광 이중 전계흡수 광변조기의 선형특성)

  • Lee, Gyu-Woong;Han, Sang-Kook
    • Journal of the Korean Institute of Telematics and Electronics D
    • /
    • v.36D no.6
    • /
    • pp.87-96
    • /
    • 1999
  • For analog optical transmission of narrow-band microwave signal, a novel all-optical linearization technique of electro-absorption (EA) optical modulator by using dual modulation scheme is proposed and theoretically investigated. By using the dual modulation scheme where the sub-modulator has a different length, DC bias and band-gap wavelength, the DC bias operation point where the third-order intermodulation products of ~30dB and the following increase of spurious free dynamic range (SFDR) of ~20dB wave achieved in sub-octave narrow band operation.

  • PDF

Mid-infrared Continuous-wave Optical Parametric Oscillator with a Fan-out Grating MgO:PPLN Operating Up to 5.3 ㎛

  • Bae, In-Ho;Yoo, Jae-Keun;Lim, Sun Do;Kim, Seung Kwan;Lee, Dong-Hoon
    • Current Optics and Photonics
    • /
    • v.3 no.6
    • /
    • pp.577-582
    • /
    • 2019
  • We report on a continuous-wave (cw) optical parametric oscillator (OPO) optimized for mid-infrared emission above 5.0 ㎛. The OPO is based on a magnesium-oxide-doped periodically poled LiNbO3(MgO:PPLN) crystal with a fan-out grating design. A linear two-mirror cavity resonating both at the pump and signal wavelengths is stabilized to the pump laser by using the modified Pound-Drever-Hall (PDH) method. The idler wavelength is continuously tunable from 4.7 ㎛ up to 5.3 ㎛ by varying the poling period of the fan-out grating crystal. Pumped by a diode-pumped solid state (DPSS) laser with a power of 1.1 W at 1064 nm, the maximum idler output power is measured to be 5.3 mW at 4.8 ㎛. The output power above 5.0 ㎛ is reduced to the hundreds of ㎼ level due to increased absorption in the crystal, but is stable and strong enough to be measured with a conventional detector.