• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.694-702
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• 1995

When a small absorbing particle is exposed to a strong thermal radiation incidence, it moves towards or away from the radiation source due to the nonuniform internal absorption of the radiation. It is called the photophoretic phenomena and governed by the asymmetry factor. An asymmetry factor for the total wavelength range is calculated to estimate the photophoretic phenomena of a particle in a combustor or in the atmosphere and compared to that for a single wavelength. The samples are soot particulates, water droplets, ice particles, silicon particles, $SiO_2$ particles, aluminium oxide particles, whose spectral complex refractive index are available. Although differences between total and monochromatic asymmertry factors are not much for relatively uniform distribution of the spectral refractive index, they are great in general. Therefore the use of the monochromatic factor will considerably deteriorate the accuracy of the calculation of the photophoresis.

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1235-1241
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• 2012

Aluminium (Al)-doped zinc oxide (AZO) thin films with different Al concentrations were prepared by the solgel spin-coating method. Optical parameters such as the optical band gap, absorption coefficient, refractive index, dispersion parameter, and optical conductivity were studied in order to investigate the effects of the Al concentration on the optical properties of AZO thin films. The dispersion energy, single-oscillator energy, average oscillator wavelength, average oscillator strength, and refractive index at infinite wavelength of the AZO thin films were found to be affected by Al incorporation. The optical conductivity of the AZO thin films also increases with increasing photon energy.

• Textile Coloration and Finishing
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• v.12 no.6
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• pp.353-360
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• 2000

In this article, arrowroot is extracted in distilled water, and its dyeing properties on wool, nylon, and silk were investigated. Also the effect of mordanting (Al, Cu, Sn, Fe and Cr compounds) on the wash fastness are measured. The wavelength of maximum absorption of the arrowroot extract appears at 250 and 300nm below pH 7, but they shifted to longer wavelength at higher pH values. It appears that the optimum condition of the dyeing of wool, nylon, and silk fabric with arrowroot extract is $60^\circ{C}$, 60 min, and pH 4.0. Mordant treatments are effective in improving wash fastness of polyamide fabrics.

• Bulletin of the Korean Chemical Society
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• v.16 no.10
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• pp.972-976
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• 1995

A trace amount of 4-biphenylcarboxylate having a pre-twisted biphenyl moiety was attached to a poly(methyl methacrylate) side chain and the fluorescence properties of the chromophore were investigated in various solvents such as ethyl acetate and butyl chloride. At room temperature, the polymer exhibited a distinct red shift of the short wavelength emission (325 nm) and an enhanced emission intensity around 430 nm upon excitation at the absorption red edge. The temperature dependence of the intensity ratio (R) of the 325 nm emission to the 430 nm emission was observed when exciting at the red edge over the temperature range between -20 and 60 ℃. However, the temperature dependence was not observed when exciting at the shorter wavelength. The Arrhenius plot of the R value shows the activation energy of 6.0 kJ/mol which is in good agreement with the energy required for the twist of the biphenyl moiety. Together with the results of red edge excitation effects it was concluded that the pre-twisted geometry of the biphenyl moiety is preserved by the restriction of the polymer chain to facilitate the formation of the twisted intramolecular charge transfer (TICT) state upon excitation.

• Journal of Integrative Natural Science
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• v.2 no.4
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• pp.289-292
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• 2009

Perchlorosilanes are useful precursors for the synthesis of hydrosilanes for the fabrication of electronic devices such as silicon thin-film transistors and silicon nanoparticles. For this solution process, requirements of precursors applicable to solution process are relatively low volatile and soluble in common organic solvents. In this work, the decaphenylcyclopentasilane has been obtained from the reaction of the lithium wire and dichlorodiphenylsilane. The reaction of decaphenylcyclopentasilane with lewis acid catalyst, HCl/$AlCl_3$, gives the perchlorocyclopentasilane. Decaphenylcyclopentasilane exhibits an unusual optical property. Its optical property was characterized by UV-vis and fluorescence spectroscopy. Absorption wavelength maxima for the decaphenylcyclopentasilane was 272 nm. Decaphenylcyclopentasilane displayed an emission band at 741 nm with excitation wavelength of 272 nm.

• Journal of the Optical Society of Korea
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• v.17 no.6
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• pp.481-485
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• 2013

A method for the measurement of the concentration of methane is experimentally demonstrated. The wavelength filter and gas cell are combined by using one Fabry-Perot etalon, which is filmed with the reflectivity of 96%. The optical broadband source is not only filtered to match the absorption wavelength of methane, but also absorbed by the methane in the same Fabry-Perot etalon. The concentration of the methane can be detected directly by measuring the transmission intensity. Compared with the conventional method, the proposed method possesses low costand high stability.

• Korean Journal of Remote Sensing
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• v.38 no.2
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• pp.215-222
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• 2022

In this study, the effect of wavelength range and absorption cross-section used to retrieve nitrogen dioxide (NO₂) vertical column density (VCD) from Pandora was analyzed using Differential Optical Absorption Spectroscopy (DOAS). During the GEMS Map of the Air Pollution (GMAP) 2020 campaign, data from direct sunlight observation with Pandora instrument in Seosan was used, and NO₂ VCD was retrieved under four conditions. The average NO₂ VCD under the four conditions ranged from 1.22×10¹⁶~1.38×10¹⁶ molec. cm^-2, with a maximum difference of 0.16×10¹⁶ molec. cm^-2 between each condition. The fitting error averaged 3.19~9.59%, showing an error within 10% in all cases, and the RMS was 5.11×10^-3~7.16×10^-3 molec. cm^-2. The retrieved NO₂ VCD using 4 conditions shows a slope in the range of 0.98 to 1.09 and correlation of 0.96 to 0.98 in comparison with Pandonia Global Network (PGN).

• Economic and Environmental Geology
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• v.50 no.1
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• pp.15-26
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• 2017

Advanced argillic, argillic, and phyllic zones are the most important alteration patterns to predict the hidden ore body during exploration of hydrothermal deposits. We examined the quantitative relationship between the spectral absorption characteristics and the mineral content of the synthetic mixtures such as alunite-kaolinite and illite-kaolinite using short wavelength infrared (SWIR) spectroscopy. In the alunite-kaolinite mixtures, the spectral absorption characteristics of the alunite was highly correlated with the Hull quotient reflectance(0.99) and the kaolinite had the highest correlation with the Gaussian peak(0.92). Illite-kaolinite mixtures are essential for Gaussian deconvolution because of the overlap of absorption region. Illite and kaolinite mixtures indicate the high correlation of 0.93 and 0.98, respectively. The error ranges in the alunite-kaolinite(8%) and illite-kaolinite mixtures(5%) derived from SWIR were smaller than the ones(29% and 26%) obtained from X-ray diffraction(Rietveld) analysis. These results show that SWIR spectroscopic analysis is more reliable than XRD Rietveld analysis in terms of quantification of allowed minerals.

• Journal of the Optical Society of Korea
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• v.19 no.4
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• pp.371-375
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• 2015

The impact of equivalent optical bandwidth on the performance of a system using a reflective electroabsorption modulator (R-EAM) based optical source has been experimentally evaluated with signals operating at 2.5 Gb/s and beyond. The equivalent optical bandwidth of our source with a broadband seed light was simply adjusted by using a bandwidth tunable optical filter. From the measurements, we have estimated the required equivalent optical bandwidth of our source for an error-free transmission (@ bit-error-rate of $10^{-12}$) and a forward error correction (FEC) threshold of $2{\times}10^{-4}$.

• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.150-151
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• 2002

파장 분할 다중화(Wavelength division multiplexing ： WDM) 광전송 장치의 용량확대를 위한 방안으로 여러 가지 방법들이 연구 개발되고 있으며, 최근 들어 테라 급(Tb/s) 광전송 연구 결과들이 발표되고 있다. 이러한 장거리 광전송 장치의 광송신기는 LiNbO$_3$ 마하-젠더(Mach-Zehnder) 간섭계형 외부 변조기를 주로 사용하고 있다. 한편 반도체 레이저 집적된 전계 흡수형 변조기(Electro-absorption modulator integrated laser ： EML)를 이용한 외부 변조 방식 적용을 위해서 여러 연구소 및 기업체에서는 40Gb/s의 성능을 지닌 EML의 개발 결과들을 발표하고 있다. (중략)