• Title/Summary/Keyword: Absorption wavelength

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Measurements of the Benzene Absorption Cross Section in the Range of Ultra Violet (UV) (UV 영역에서 벤젠의 흡수 단면적의 측정)

  • Lee, J.S.;Ryu, S.Y.;Kim, H.H.;Woo, J.C.;Kim, K.B.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.922-928
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    • 2006
  • An absolute absorption cross section of benzene was measured with a spectrometer system including a mono-chrometer and a grating in the wavelength region of $240{\sim}280nm$ under the atmospheric pressure and room temperature in the laboratory. A certificated reference benzene gas ($98{\mu}mol/mol$ in $N_2$) was used to measure its absorption cross section. A 710 mm cell with a quartz window and a 150 W Xe arc lamp were employed. The magnitude of absorption cross section of $1.41{\times}10^{-18}cm^2$ was lower than that of the reference spectra ($2.5{\times}10^{-18}cm^2$) of high resolution spectrometer, Total measurement uncertainty was estimated to be 4.0%.

Graphite Furnace Atomic Absorption Spectrophotometric Determination of Trace Horseradish Peroxidase Using Nanosilver

  • Jiang, Zhi-Liang;Tang, Ya-Fang;Wei, Lin;Liang, Ai-Hui
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2732-2736
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    • 2011
  • In pH 4.2 HAc-NaAc buffer solution, horseradish peroxidase (HRP) catalyzed $H_2O_2$ oxidation of nanosilver to form $Ag^+$. After centrifugation, $Ag^+$ in the supernatant can be measured by graphite furnace atomic absorption spectrophotometry (GFAAS) at the silver absorption wavelength of 328.1 nm. When HRP concentration increased, the $Ag^+$ concentration in the supernatant increased, and the absorption value enhanced. The HRP concentration in the range of 0.84-50 $ng{\cdot}mL^{-1}$ was linear to the enhanced absorption value (${\Delta}A$), with a regression equation of ${\Delta}A$=0.012C+0.11, correlation coefficient of 0.9988, and detection limit of 0.41 $ng{\cdot}mL^{-1}$ HRP. The proposed GFAAS method was used to detect HRP in waste water samples, with satisfactory results.

Species Concentration Measurement Using Diode Laser Absorption Spectroscopy (I) (다이오드 레이저를 이용한 광흡수 농도 계측 기법 (I))

  • Ahn, Jae-Hyun;Kim, Yong-Mo;Kim, Se-Won
    • Journal of the Korean Society of Combustion
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    • v.9 no.3
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    • pp.27-35
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    • 2004
  • Diode laser absorption sensors are advantageous because they may provide fast, sensitive, absolute, and selective measurements of species concentration. These systems are very attractive for practical applications owing to its compactness, resonable cost, robustness, and ease of use. In addition, diode lasers are fiber-optic compatible and thus enable simultaneous measurements of multiple species along a line-of-sight. Recent advances of room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications make it possible to be applied for combustion diagnostics based on diode laser absorption spectroscopy. Therefore, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor systems are now appearing for variety of applications. The objectives of this research are to develope a new gas sensing system and to verify feasibility of this system. Wavelength and power characteristics as a function of injection current and temperature are experimentally found out. Direct absorption spectroscopy has been demonstrated in these experiments and has a bright prospect to this diode laser system.

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The Optical Properties of Monocationic Zeolite Suspensions (Monocationic Zeolite 현탁액(懸濁液)의 광학적(光學的) 특성(特性))

  • Kang, Shin-Jyung;Choi, Jyung
    • Applied Biological Chemistry
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    • v.29 no.2
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    • pp.159-163
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    • 1986
  • The optical properties of monocationic zeolite suspension adsorbed with each of $Na^+$, $NH_4^+$, $Ca^{2+}$, and $Al^{3+}$ were studied in the wavelength range $200{\sim}800nm$. The results were as follows. 1. The optical density of zeolite suspension seemed to be affected by the light absorption of zeolite particles at the wavelength range of $200{\sim}300nm$ and by the light scattering of zeolite particles at wavelength of $300{\sim}800nm$. 2. At the wavelength range of $380{\sim}800nm$, the optical densities of monocationic zeoliteg differed mutually according to adsorbed cations and increased in the order of $Al-\;>\;Ca-\;>\;NH_4->\;Na-zeolite$ suspension. 3. It was convenient that at the wavelength range of $380{\sim}800nm$, the diluted suspension of zeolite was measured in the short wavelength and the concentrated suspension of zeolite was measured in the long wavelength. 4. Zeolite particles in zeolite suspension were aggregated and the size of aggregation size was larger in the order of $Al-\;>\;Ca-\;>\;Na-\;>\;NH_4-zeolite$.

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Wavelength Calibration Solution of VPH Grating Slitless Spectroscopy Image

  • O, Seong A;Shin, Suhyun;Im, Myungshin;Yoon, Yongmin;Kim, Yongjung
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.68.2-68.2
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    • 2018
  • Spectroscopic observations commonly use a slit or fiber; however, non-slit spectroscopy enables us to observe a larger number of targets in one frame of image. Hence, it has been adopted as an observational mode for observatories like HST and JWST. Slitless spectroscopy requires wavelength calibration solutions in order to distinguish and measure the absorption / emission lines from the spectra with high accuracy. We installed the Volume Phase Holographic (VPH) grating to SQUEAN camera on the McDonald 2.1m telescope and obtained images with spectral resolutions of ~ 100 and 200. In order to derive the wavelength calibration, we measured the distances between the 0th order images and spectral features of various quasars. The distances are converted to wavelengths using the known wavelengths of the emission lines. We tested several different methods of spectral extraction and peak estimation of emission lines. We will present the results for the wavelength calibration and suggest the reliable methods to find the solution.

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Development of Minimally Invasive Mid-infrared Lipolysis Laser System for Effective Fat Reduction

  • Lee, Ji-Young;Ryu, Han Young;Seo, Young-Seok
    • Medical Lasers
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    • v.10 no.2
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    • pp.82-89
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    • 2021
  • Background and Objectives Due to changes in diet and lifestyle, the number of obese people worldwide is steadily increasing. Obesity has an adverse effect on a healthy life, so it needs treatment and improvement. Research related to this is continuously being conducted. Materials and Methods The laser system to compact designed using 808 nm laser diode and Neodymium Yttrium orthovanadate generates a 1064 nm wavelength, the periodically polarized nonlinear crystal pumping laser beam. The pulsed 1064 nm wavelength beam passing through the AO Q-switch is used as the pumping light of the nonlinear optical crystal and is irradiated to the periodic polarized nonlinear optical crystal with a quasi-phase matching period. Nonlinear optical crystals use an oven to control the temperature to generate the desired 1980 nm and 2300 nm wavelengths. Results The 1980 nm and 2300 nm wavelengths generated by temperature control of nonlinear optical crystals are effective for lipolysis. A fiber catheter was used so that the laser could be directly irradiated to the fat cells. In particular, the new wavelength (1980 nm, 2300 nm) can increase the fat reduction effect with low energy (1.3 W). When a laser with a combination wavelength of 1980 nm and 2300 nm was used, an average lipolysis effect of 20% was obtained. Conclusion A mid-infrared lipolysis laser system with excellent absorption of fat and water has been developed. We conducted a princlinical study to confirm the efficacy and safety of the lipolysis laser system, and obtained good results for lipolysis with low energy.

Composite Gas Measurement System using NDIR Method (NDIR 방법을 이용한 복합 가스 측정 시스템)

  • Eo, Ik-soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.624-629
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    • 2018
  • The current study was conducted to develop a portable composite gas detector allowing the detection of both $CO_2$ and $CH_4$ gases by means of the Non Dispersive Infra-Red (NDIR) method. The gas detector is configured to radiate infrared waves using infrared lamps, where the wavelength of the infrared light is reduced due to absorption throughout the chamber, and this reduction (absorption) is detected by the absorption detector, before being converted and amplified to a 3.5V~6V electrical signal, providing as accurate a measurement as possible. The conventional singe sensor method measures the relative measurement by absorbing only specified wavelengths of infrared radiation, which in the case of gas detection leads to problems with accuracy due to the lack of a reference sensor when detecting light with a wavelength of only $4.26{\mu}m$. The dual sensor employed in this study provides a comparative measurement between the reference value derived from the wavelength of $3.91{\mu}m$, which is not influenced by other gas sources, and the measurement value derived from the wavelength of $4.26{\mu}m$, in order to reduce the errors and enhance the reliability, thereby allowing low power consumption for portable devices and multi-gas detection for both $CO_2$ and $CH_4$ gases. The portable composite gas detector developed herein provides a measurement rage of 0ppm~5,000ppm for $CO_2$ gas, and 0.5%vol for $CH_4$, which allows the determination of whether the $CO_2$ and $CH_4$ contents in indoor air are less than 1,000ppm or not. The current study established that the composite gas detector can be interlinked with firefighting appliances through portable devices or home automation, and is anticipated to be very effective in fire prevention.

Studies on the complex compounds and their analytical methods of barbiturates by means of $\alpha$-picoline-copper (II) ($\alpha$-picoline동(II)에 의한 barbital 류의 착화합물및 그의 약품분석화학적 연구)

  • 김수억
    • YAKHAK HOEJI
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    • v.13 no.1
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    • pp.1-15
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    • 1969
  • A new method of qualitative and quantitative determination of barbiturates in the pharmaceuticals by means of $\alpha$-picoline-copper (II) was studied. Barbiturates in the pharmaceuticals were dissolved in the mixed solvent of 33% $\alpha$-picoline-Carbontetrachloride to yield Complex Compounds of barbiturates-copper (II)-$\alpha$-picoline. Complex Compounds of barbiturates show uniformly maximum absorption at the wavelength of 540m.mu. and wre to be identified at the concentration of 1 X 10$^{-4}$ Mole, and also was to be quantitatively determined at the concentration of 1 X 10$^{-3}$ Mole. By this method barbiturates in the pharmaceuticals could be determined in the presence of various compounds such as sulpyrine, isopropylantipyrine, antipyrine, phenacetin and etc. But Barbiturates could be also determined by this method after seperation with aminopyrine, acetaminophen, acetylsalicylic acid and etc. by column chromatography. And barbiturates and acetylsalicylic acid could be also determined by simultaneous equation while their complex compounds show uniformly each maximum absorption at the Wavelength of 540 m${\mu}$ and 620 m${\mu}$. I.R. spectra of these complex compounds show identification of Barbiturates derivatives. The composition ratio of these complex compounds were : barbiturates : Cu : ${\alpha}$-picoline=2:1:2.

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Influence of Diverse Atmospheric Conditions on Optical Properties of a Pulse Laser in a Time-of-Flight Laser Range Finder

  • Shim, Young Bo;Kwon, Oh-Jang;Choi, Hyun-Yong;Han, Young-Geun
    • Journal of the Optical Society of Korea
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    • v.19 no.1
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    • pp.1-6
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    • 2015
  • We investigate the propagation characteristics of a pulse laser in a time-of-flight laser range finder (TOF-LRF) system with variations in atmospheric conditions, such as temperature, pressure, relative humidity, and the concentration of $CO_2$. The measurement error of distance related with the group velocity change in the TOF-LRF system is analyzed by considering the refractive index of the standard atmosphere with variations in atmospheric conditions. The dependence of the pulse width broadening induced by chromatic dispersion of the standard atmosphere on the operating wavelength and the initial pulse width of the light sources is discussed. The transmission of air with variations in the relative humidity or the concentration of $CO_2$ is analyzed by using different values of absorption coefficients depending on the operation wavelength of the light source in the TOF-LRF system.

The optical characteristics of amorphous $Se_{75}Ge_{25}$ thin film by the low-energy lon beam exposure (저 에너지 이온빔 조사에 따른 비정질 $Se_{75}Ge_{25}$ 박막의 광학적 특성)

  • 이현용;오연한;정홍배
    • Electrical & Electronic Materials
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    • v.7 no.2
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    • pp.100-106
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    • 1994
  • A bilayer film consisting of a layer of a-Se$_{75}$ Ge$_{25}$ with a surface layer of silver -100[.angs.] thick and a monolayer film of a-Se$_{75}$ Ge$_{25}$ are irradiated with 9[keV] Ga$^{+}$ ion beam. The Ga$^{+}$ ion (10$^{16}$ [ions/cm$^{2}$] exposed a-Se$_{75}$ Ge$_{25}$ and Ag/a-Se$_{75}$ Ge$_{25}$ thin films show an increase in optical absorption, and the absorption edge on irradiation with shifts toward longer wavelength. The shift toward longer wavelength called a "darkening effect" is observed also in film exposure to optical radiation(4.5*10$^{20}$ [photons/cm$^{2}$]). The 0.3[eV] edge shift for ion irradiation films is about twice to that obtained on irradiation with photons. These large changes are primarily due to structural changes, which lead to high etch selectivity and high sensitivity.

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