• 제목/요약/키워드: Absorption Factor

검색결과 586건 처리시간 0.026초

Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제16권1호
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    • pp.35-45
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    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

Double Resonance Perfect Absorption in a Dielectric Nanoparticle Array

  • Hong, Seokhyeon;Lee, Young Jin;Moon, Kihwan;Kwon, Soon-Hong
    • Current Optics and Photonics
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    • 제1권3호
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    • pp.228-232
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    • 2017
  • We propose a reflector-type perfect absorber with double absorption lines using electric and magnetic dipoles of Mie resonances in an array of silicon nanospheres on a silver substrate. In the visible range, hundreds of nanometer-sized nanospheres show strong absorption lines up to 99%, which are enhanced by the interference between Mie scattering and reflections from the silver substrate. The air gap distance between the silicon particles and silver substrate controls this interference, and the absorption wavelengths can be controlled by adjusting the diameter of the silicon particles over the entire range of visible wavelengths. Additionally, our structure has a filling factor of 0.322 when the absorbance is nearly 100%.

Effect of PEO viscoelasticity on carbon dioxide absorption in aqueous PEO solution of AMP

  • Park Sang-Wook;Choi Byoung-Sik;Lee Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제17권4호
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    • pp.199-205
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    • 2005
  • Carbon dioxide was absorbed into aqueous polyethylene oxide (PEO) solution containing AMP in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior of PEO on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP was assumed to be a first-order reaction with respect to the molar concentration of $CO_2$ and AMP respectively. The liquid-side mass transfer coefficient, which was obtained from the dimensionless empirical equation containing the properties of viscoelasticity of the non-Newtonian liquid, was used to estimate the enhancement factor due to chemical reaction. PEO with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid based on the same viscosity of the solution.

Fiber Ring Laser Intra-cavity Absorption Spectroscopy for Gas Sensing: Analysis and Experiment

  • Li, Mo;Liu, Kun;Jing, Wencai;Peng, Gang-Ding
    • Journal of the Optical Society of Korea
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    • 제14권1호
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    • pp.14-21
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    • 2010
  • Fiber ring laser based intra-cavity absorption spectroscopic sensor has great potential for high sensitivity gas detection. Using the rate equations and propagation equations, we investigated theoretically factors that affect the sensitivity of such fiber ring laser sensors and determined the optimal design parameters and conditions for significant enhancement of the system sensitivity. Experiments have been conducted to determine the sensitivity enhancement performance. The results showed a factor of 25 ~ 30 in sensitivity enhancement in the experimental system, agreeing well with the theoretical expectations. Experiments on acetylene detection have also been carried out and the results showed that the ring cavity significantly increases the signal absorption and that high sensitivity can be obtained for gas detection.

화학흡수법에 의한 연소폐가스 중 지구온난화 가스 $CO_2$분리에 관한 연구 (A Study on the Separation of $CO_2$from Flue Gas by Chemical Absorption)

  • 안성우;김영국;송호철;박진원
    • 에너지공학
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    • 제6권2호
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    • pp.203-211
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    • 1997
  • 본 연구에서는 지구 온난화 연소폐가스를 모델로 한 $CO_2$-$N_2$혼합 기체의 화학흡수법에 의한 기체 분리 실험을 행하였다. 반회분식 기포부상 반응 장치를 이용하여 최적흡수액의 조건을 탐색하였고, 충진 흡수탑을 이용하여 흡수 속도를 측정, 실험 결과를 이론적 예측값과 비교.분석하여 흡수현상에 대한 적절한 해석을 하고자 하였다. 본 실험에 사용한 흡수제는 Monoethanolamine(MEA)이었고, 대상 기체는 화력발전소의 연소배가스의 주요성분이 $N_2$79%, $CO_2$15%, $O_2$4%인바, $N_2$: $CO_2$가 몰비 85:15의 비율인 모델가스를 혼합기체로 사용하였다. 실험조건하에서 $CO_2$loading과 $CO_2$제거율을 측정하였고, 흡수속도를 구하기 위하여 Enhancement factor를 도입하고 Film 모델과 Higbie 모델을 적용하였다. 흡수액의 최적농도는 4-5 M인 것으로 나타났으며. Higbie model에 의한 흡수속도 예측은 실측치와 잘 일치하여 연소폐가스 중의 고농도 $CO_2$가스의 흡수에 적용이 가능한 것으로 나타났다.

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200kJ 대용량 에너지 흡수용 변형튜브 설계에 관한 연구 (Study on the Design of Deformation Tube for 200kJ Large Energy Absorption)

  • 김진모;이종길;김기남
    • 한국철도학회논문집
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    • 제19권2호
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    • pp.109-116
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    • 2016
  • 고속철도 차량의 시장 점유율은 전 세계적으로 확대되고 있다. 고성능 충격 에너지 흡수 요소는 철도차량의 안전 기준을 충족하는 것이 필수 요소이다. 변형 튜브 조립체는 철도 차량에 대한 전형적인 에너지 흡수 요소이다. 그것은 변형 튜브와 압입 펀치로 구성되어 있으며 튜브 조립체의 성능은 튜브의 소성 영역에서 흡수 에너지 특성에 의존한다. 본 논문의 변형 튜브에서 흡수하는 소성변형 에너지는 200kJ의 철도차량 충돌 에너지를 흡수하도록 설계되어 있다. 슬래브 법과 유한 요소해석을 사용하여 초기 단계에서 펀치의 반력은 예측되며 설계된 튜브 조립체의 성능은 실험으로 확인되었다.

부직포 충전재의 구조적 특성이 수분전달 특성에 미치는 영향-단층구조와 이층구조 부직포의 비교- (The Effect of Geometrical Structure on the Moisture Transport Properties of Nonwoven Batting Materials)

  • 김희숙;나미희
    • 한국의류학회지
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    • 제24권6호
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    • pp.810-818
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    • 2000
  • The purpose of this study was to analyze the effect of geometrical structure on the moisture transport properties of nonwoven batting materials. Two types of nonwovens were used such as single and double layered nonwovens. Steady and dynamic state water vapor transport properties were measured by absorption, evaporation and cobaltous chloride method respectively. The results of this study were as follows: 1) Geometrical structure affected water vapor evaporation, but there were no differences between single and double layered nonwovens in moisture absorption. Thickness and air permeability were influencing factor on water vapor transport rate. 2) Directionality of double layered nonwoven was observed both in steady and dynamic state moisture transport. There were differences between upper and lower layer of double layered nonwoven both in moisture absorption rate and color change by cobaltous chloride method. 3) In dynamic state of water vapor transport rate, single layered nonwoven reached more rapidly at the established relative humidity. It was confirmed that geometrical structure affected water vapor evaporation and hydrophilicity of fiber affected moisture absorption because there were much more water vapor transport rate by evaporation than absorption within the same period of time.

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Consideration of Temperature and Slip Correction for Photothermal Spectrometry

  • Lee, Jeonghoon
    • Asian Journal of Atmospheric Environment
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    • 제9권1호
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    • pp.86-90
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    • 2015
  • Temperature was considered to estimate the minimum detectable absorption coefficient of aerosol particles from photothermal spectroscopy. Light energy absorbed by subsequent emission from the aerosol results in the heating of the aerosol sample and consequently causes a temperature change as well as changes in thermodynamic parameters of the sample. This thermal effect is the basis of photothermal spectroscopy. Photothermal spectroscopy has several types of techniques depending on how the photothermal effects are detected. Photothermal interferometry traces the photothermal effect, refractive index, using an interferometer. Photoacoustic spectroscopy detects the photothermal effect, sound wave, using a microphone. In this study, it is suggested that the detection limit for photothermal spectroscopy can be influenced by the introduction of a slip correction factor when the light absorption is determined in a high temperature environment. The minimum detectable absorption coefficient depends on the density, the specific heat and the temperature, which are thermodynamic properties. Without considering the slip correction, when the temperature of the environment is 400 K, the minimum detectable absorption coefficient for photothermal interferometry increases approximately 0.3% compared to the case of 300 K. The minimum detectable absorption coefficient for photoacoustic spectroscopy decreases only 0.2% compared to the case of 300 K. Photothermal interferometry differs only 0.5% point from photoacoustic spectroscopy. Thus, it is believed that photothermal interferometry is reliably comparable to photoacoustic spectroscopy under 400 K.

Steatite 자기의 전기적 특성에 미치는 알칼리 토금속 산화물의 영향 (Effects of Alkaline Earth Oxides on Electrical Characteristics of Steatite Porcelain)

  • 이종근;이병하;전승관
    • 한국세라믹학회지
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    • 제16권1호
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    • pp.31-37
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    • 1979
  • The middle point of composition within the system $MgO-Al_2O_3-SiO_2$ has been studied for applicability as ceramics dielectrics. A Kyul Sung Tale of high purity, magnesia clinker of Sam-wha chemical company, C.P. aluminium oxide, calcium carbonate, red lead, barium carbonate which was made into frit were used the raw materials. A number of steatite ceramics were prepared under carefully controlled condition and the water absorption, linear shrinkage, power factor, dielectric constant and dielectric loss were measured at elevated temperature. When we used magnesia clinker as flux, the quantity of this flux was 0.05mole, sintering temperature was continued for 2 hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose power factor was 0.142%, water absorption was zero, linear shrinkage was 8.76%, dielectric constant was 5.63, dielectric loss was 0.00799. When we used red lead as flux, the quantity of this flux was 0.033mole and 0.066mole, sintering temperature was continued for 2hrs. at 1, 26$0^{\circ}C$. From this conditions, we could get the data whose water absorption was zero, linear shrinkage was 8.03%, and 8.48%, power factor was 0.136% and 0.062%, dielectric loss was 0.0072 and 0.0037. When we used barium carbonate made into frit as flux, the quantity of this flux was 0.02mole, sintering temperature was continued for 2hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose water absoption was zero, linear shrinkage was 8.44%, power factor was 0.138%, dielectric constant was 5.69, dielectric loss was 0.0074.

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AERONET 선포토미터 데이터를 이용한 에어로졸 조성 및 광흡수 특성 인자 도출 (Deduction of Aerosol Composition and Absorption factors using AERONET sun/sky radiometer)

  • 노영민;이철규;최성철
    • 대한원격탐사학회지
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    • 제29권4호
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    • pp.407-413
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    • 2013
  • 본 연구에서는 에어로졸의 종류에 따른 광흡수 특성을 표시할 수 있는 새로운 에어로졸 파라미터인 Modified Aerosol Factor(MAF)를 산출하였다. MAF는 AERONET의 선포토미터로부터 산출되는 4 파장(440, 675, 870 그리고 1020 nm)의 단산란알베도로부터 도출되었다. 에어로졸 종류에 단산란알베도 값이 파장 증가에 따라 다른 형태를 보이는 점으로부터 4파장의 단산란알베도를 이용하여 선형회귀분석을 수행하고 분석값의 기울기 값을 산출하였다. 먼지입자는 기울기 값이 양의 값을 보이고, 순수한 먼지입자 일수록 높은 값을 보였다. 다른 종류의 에어로졸이 혼합됨에 따라 기울기 값은 감소하였다. 먼지입자를 제외한 오염입자와 smoke 입자는 음의 값을 보였다. 광흡수 특성의 차이를 파악하기 위하여 1020 nm에서의 단산란알베도 값을 보정하였다. 보정된 단산란알베도와 기울기 값을 합하여 MAF를 도출하였다. MAF는 오염입자와 smoke 입자는 -1, 먼지입자는 1.5의 값을 보였으며, 서로 다른 에어로졸 종류별로 광흡수 특성이 높을수록 낮은 값의 분포를 보였다.