• Title/Summary/Keyword: A_F Ratio

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19F NMR investigation on the ratio of amorphous to crystal for the binder PVdF in Li ion battery

  • Im, Jong-san;Park, Junghwan;Kim, Kyoung Soo;Jung, Hyunok
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.1
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    • pp.1-5
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    • 2019
  • $^{19}F$ NMR experiments were carried out to observe the change of the characteristics of the PVdF binder which is an auxiliary material of the lithium ion battery. PVdF has various crystalline or amorphous phases by thermal treatment. A mixture of cathode and auxiliary materials including PVdF was coated on aluminum foil as an electron collector and then subjected to thermal treatment at various temperatures. The overlapped $^{19}F$ NMR signals obtained from the various phases were separately convoluted into the respective phases, and it was found that there was a relative ratio change of these phases. In addition, the crystal and amorphous phase of PVdF was changed during the vacuum drying, which is the last step of the actual electrode manufacturing. It was observed that the relative amount of amorphous phase, which may affect the flexibility of the electrode or the wettability of the electrolyte, abruptly changes after a certain temperature.

A Fatigue Life Prediction by Growth Characteristics of a Small Surface Crack (작은 표면균열의 성장특성에 의한 수명예측)

  • Suh, Chang-Min;Lim, Chang-Soon;Gang, Yong-Gu
    • Journal of Ocean Engineering and Technology
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    • v.3 no.2
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    • pp.617-617
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    • 1989
  • This paper deals with a fatigue life prediction of a surface crack based on the experimentally obtained relationship between surface crack length ratio $a/a_{f}$ and cycle ratio $N/N_{f}$ using micro computer. Firstly $a/a_{f}$-$N/N_{f}$ curves obtained from experimental tests, were assumed as three curves UC(the upper limit curve), LC(the lower limit curve) and MC(the middle curve), and these were utilized to predict the fatigue life. Comparing the calculated values which represent the characteristics of crack growth behaviors from the three assumed curves with the experimental ones, it has been found that in the stable crack growth region, they coincide reasonably well each other. And the differences between the fatigue lives obtained from the assumed curves and the experimental fatigue life did not exceed 20%. Using the characteristics of $a/a_{f}$-$N/N_{f}$ curves, it is possible to predict the da/dN-Kmax curves and the S-$N_{f}$ curves.

A Fatigue Life Prediction by Growth Characteristics of a Small Surface Crack (작은 표면균열의 성장특성에 의한 수명예측)

  • Suh, Chang-Min;Lim, Chang-Soon;Gang, Yong-Gu
    • Journal of Ocean Engineering and Technology
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    • v.3 no.2
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    • pp.108-117
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    • 1989
  • This paper deals with a fatigue life prediction of a surface crack based on the experimentally obtained relationship between surface crack length ratio $a/a_{f}$ and cycle ratio $N/N_{f}$ using micro computer. Firstly $a/a_{f}$-$N/N_{f}$ curves obtained from experimental tests, were assumed as three curves UC(the upper limit curve), LC(the lower limit curve) and MC(the middle curve), and these were utilized to predict the fatigue life. Comparing the calculated values which represent the characteristics of crack growth behaviors from the three assumed curves with the experimental ones, it has been found that in the stable crack growth region, they coincide reasonably well each other. And the differences between the fatigue lives obtained from the assumed curves and the experimental fatigue life did not exceed 20%. Using the characteristics of $a/a_{f}$-$N/N_{f}$ curves, it is possible to predict the da/dN-Kmax curves and the S-$N_{f}$ curves.

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Front-to-Back Ratio Improvement of a Microstrip Patch Antenna Loaded with Soft Surface Structure in a Partially Removed Ground Plane

  • Lee, Hong-Min
    • Journal of electromagnetic engineering and science
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    • v.12 no.4
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    • pp.247-253
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    • 2012
  • This study presents a new, simple method for improving the front-to-back (F/B) ratio of a microstrip patch antenna. The back radiation of the microstrip patch antenna is reduced by removing some metallic parts around the ground plane and placing a new soft-surface configuration, consisting of an array of stand-up split-ring resonators on a bare dielectric substrate near the two ground plane edges. Compared to the F/B ratio of a conventional microstrip patch antenna with a full ground plane of the same size, our proposed microstrip patch antenna experimentally achieves an improved F/B ratio of 9.6 dB.

The effects of LEDs and duty ratio on the growth and physiological responses of Silene capitata Kom., endangered plant, in a plant factory

  • Park, Jae-Hoon;Lee, Eung-Pill;Han, Young-Sub;Lee, Soo-In;Cho, Kyu-Tae;Hong, Yong-Sik;You, Young-Han
    • Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.174-182
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    • 2018
  • Background: In this study, we observed their growth and physiological responses using a variety of duty ratio under the mixed light using red, blue, and white lights. The red+blue mixed light was treated with 95%, 90%, 85%, 80%, and 75% duty ratios and red+blue+white mixed light with 85% and 70% duty ratios. We examined the width and length of leaves, total number of leaves, and number of shoots to examine their growth responses. The physiological responses were studied by measuring their photosynthetic rate, transpiration rate, stomatal conductance, water use efficiency, chlorophyll content, and fluorescence ($F_o$, $F_m$, and $F_v/F_m$). Results: We found that lower duty ratio caused the length and width of the leaves to grow longer under red+blue mixed light but that it did not cause any difference in the red+blue+white mixed light condition. In addition, there was no difference in the number of leaves and shoots among all treatments. In the red+blue mixed light condition, the photosynthetic rate was no difference, but both transpiration rate and stomatal conductance were the highest at 95% duty ratio than in other ratios. Water use efficiency pattern was similar to that of photosynthetic rate; water use efficiency was no difference. Chlorophyll content was the highest at 95% duty ratios, and it was the least at 90%, 85%, and 75% duty ratio. $F_o$ and $F_m$ values were relatively high at 85% and 80% duty ratio and low at 90% duty ratio while $F_v/F_m$ showed no difference. Conclusions: Under the red+blue+white mixed light, all physiological items showed no difference between 70 and 85% treatments. But, photosynthetic rate, water use efficiency, chlorophyll content, and $F_v/F_m$ were relatively greater in the red+blue+white mixed light than in the red+blue mixed light. Therefore, red+blue+white mixed light treated with 70% duty ratio could lessen the environmental stress and save more power when cultivating Silene capitata in a plant factory.

13C-NMR Spectroscopy of Urea-Formaldehyde Resin Adhesives with Different Formaldehyde/Urea Mole Ratios

  • Park, Byung-Dae;Lee, Sang M.;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.2
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    • pp.63-72
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    • 2008
  • As a part of abating formaldehyde emission of urea-formaldehyde (UF) resin adhesive, this study was conducted to investigate chemical structures of UF resin adhesives with different formaldehyde/urea (F/U) mole ratios, using carbon-13 nuclear magnetic resonance ($^{13}C$-NMR) spectroscopy. UF resin adhesives were synthesized at four different F/U mole ratios such as 1.6, 1.4, 1.2, and 1.0 for the analysis. The analysis $^{13}C$-NMR spectroscopy showed that UF resin adhesives with higher F/U mole ratios (i.e., 1.6 and 1.4) had two distinctive peaks, indicating the presence of dimethylene ether linkages and methylene glycols, a dissolved form of free formaldehyde. But, these peaks were not detected at the UF resins with lower F/U mole ratios (i.e., 1.2 and 1.0). These chemical structures present at the UF resins with higher F/U mole ratios indicated that UF resin adhesive with higher F/U mole ratio had a greater contribution to the formaldehyde emission than that of lower F/U mole ratio. Uronic species were detected for all UF resins regardless of F/U mole ratios.

Experimental Study on Flow Structure of Wake Behind a Rotationally Oscillating Circular Cylinder (주기적으로 회전진동하는 원주 후류의 유동구조에 관한 실험적 연구)

  • Lee Jung-Yeop;Lee Sang-Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.4 s.247
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    • pp.298-305
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    • 2006
  • The flow around a circular cylinder which oscillates rotationally with a relatively high forcing frequency has been investigated experimentally using flow visualization and hot-wire measurements. Dominant parameters are Reynolds number (Re), oscillation amplitude $({\theta}_A)$, and frequency ratio $F_R=f_f/f_n$, where $f_f$ is the forcing frequency and $f_n$ is the natural frequency of vortex shedding. Experiments were carried out under the conditions of $Re=4.14{\times}10^3,\;{\theta}_A={\pi}/6$, and $0{\leq}F_R{\leq}2$. The effect of frequency ratio $F_R$ on the flow structure of wake was evaluated by measuring wake velocity profile and spectral analysis of hot-wire signal. Depending on the frequency ratio $F_R$, the cylinder wake has 5 different flow regimes. The vortex formation length and vortex shedding frequency are changed significantly before and after the lock-on regime. The drag coefficient was reduced under the condition of $F_R<1.0$ and the maximum drag reduction is about 33% at $F_R=0.8$. However, the drag is increased as $F_R$ increases beyond $F_R=1.0$. This active flow control method can be effective in aerodynamic applications, if the forcing parameters are selected optimally.

A Study on Spray and Mixing Characteristics of Unlike Impinging Triplet Injector (F-O-F, O-F-O) (충돌형(F-O-F, O-F-O) 실물형 분사기의 분무특성 및 혼합특성에 관한 연구)

  • 김종규;김승한;문일윤;이광진;서성현;한영민
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.195-203
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    • 2003
  • Spray and Mixing characteristics of the unlike impinging triplet injectors (F-O-F, O-F-O) were investigated with the variation of the momentum ratio of oxidizer to fuel. The spray pattern was measured using a backlit stroboscopic photography technique, and mixing efficiency was measured using a mechanical patternator. Kerosene/water were used as a propellant simulant. From the experimental results, it is found that a O-F-O type injector has a good atomization. And as the momentum ratio increases, the mixing efficiency decreases rapidly.

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A Study on Optimum Mating Ratio of Broiler Breeders to Maximize Fertility and Hatchability of Eggs (수정ㆍ부화율 향상을 위한 적정 배웅비 결정 연구)

  • 이봉덕;박창식;장애무;이경우
    • Korean Journal of Poultry Science
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    • v.30 no.2
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    • pp.95-99
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    • 2003
  • A total of 112 male and 1208 female Ross broiler breeders (30-wk-old) were used in this study to investigate whether a male to female (M/F) ratio of broiler breeder chickens may influence fertility and hatchability of hatching eggs. There were three treatments, each consisting of four pens with a size of 3.2 m ${\times}$ 6.4 m. Each pen housed approx. 100 females and 10 males to give the M/F ratio as follows: T1, 1/9; T2, 1/11; and T3, 1/13, respectively. The fertility of broiler breeder eggs ranged between 93 to 94% at 30 wk of age. At 35 wk of age, breeder eggs from T3 tended to be less fertile (P>0.05) than those from T1 and T2. The low fertility observed in T3 at 35 wk of age further reduced to reach a statistical significance at 46 wk of age (P<0.05) when compared to those of T1 and T2. Hatchability of breeder eggs among treatments tended to follow a similar trend as shown in fertility, keeping hatchability of breeder eggs from T3 low when compared to the groups of T1 and T2. Our results indicated that the M/F ratio influenced fertility and consequently hatchability of breeder eggs. Furthermore, our study suggests that either 1/9 or 1/11 M/F ratio, but not 1/13 M/F ratio, seems suitable to sustain reproductive performance of broiler breeders throughout the laying periods.

A Characteristic of Nitrogen and Phosphorus Removal in Anoxic/Oxic Basins combined with Iron Electrolysis (철 전기분해장치와 무산소/호기공정을 결합한 질소, 인제거 특성에 관한 연구)

  • Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.43 no.6
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    • pp.525-531
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    • 2017
  • Objectives: The purpose of this experiment is to better understand the nitrogen and phosphorus removal ratio according to operating conditions in an iron electrolysis system consisting of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis consists of an iron precipitation reactor composed of iron plates in oxic and anoxic basins. We studied the interrelation coefficient between T-N and T-P removal rates and F/M ratio, and the C/N ratio and BOD removal rate. Results: The F/M ratio and the T-N and T-P removal rate per unit area have interrelation coefficients of 0.362 and 0.603, respectively. The removal rate per MLVSS and the T-N and T-P removal rate per unit area have respective interrelation coefficients of 0.49 and 0.59. Conclusions: The removal rate of T-N and T-P increased with the increasing F/M ratio in the influent, and they also linearly increased in proportion to the C/N ratio of influent and BOD removal rate of the reactor.