Density Functional Theory(DFT) calculations are performed to estimate the hydrogen bonding interaction energies in pyridine-water and amino-substituted pyridine-water complexes. Some equilibrium properties are also obtained for these complexes at B3LYP/aug-cc-pVDZ level. It is shown that the amino substitution increases the proton affinity of pyridine and stabilizes the hydrogen bond. The degree of stabilization upon formation of the complex varies with the number and the position of the amino groups.
Journal of The Institute of Information and Telecommunication Facilities Engineering
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v.10
no.1
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pp.14-26
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2011
In this paper, we've studied Optical Fiber Subscribe Transmit system. After receiving the ATM cell passing through the FIFO of the Asynchronous Transfer Method from the ATM Layer images to the VC4 signal payload passing through scrambling of the cell payload, HEC computation of the cell and inserting the Idle/Unassigned cell. At this time formed VC4 signal passing through the generating and inserting POH overhead at the same time indicating the start point of the cell by the H4 byte on the VC4 POH. This ATM cell transmits 155Mbps speed changing the optical signal after outputting the frame format at the STM-1 signal generation block through the AUG bus after generating J1 of the VC4 start point at the AU4 pointer generation block.
School food service must be operated as the part of the education. But it seems that it is not to be considered as an important educational field from the perspective of educational administration. This study was conducted to suggest the effective plan to improve the quality of the school food service system. Questionaries were distributed to 51 administrators and 85 dieticians of primary schools in Incheon area from Aug 7th to Aug 31st 2000. Drawbacks of school food service system cited from the survey results were insufficient support from the authorities both in policy and in budget and shortage of specialists for food service administration. Both dieticians and administrators acknowledged that available facilities required for the school food service were insufficient. 85.9% of dietition and 51.0% of administrators thought dietition of school food service to be suitable for nutrition education. For effective nutrition education, they suggest to have teachers taking in charge of nutrition education, to have teaching system related with school food service and to develope visual auditorial teaching material. For improvement of the quality of school food service, it is necessary to acquire sufficient budget and political support from the government and to have specialists for food service administration. And regulations promoting dieticians to be teachers of nutrition education is required to be introduced in the near future.
Journal of Korean Academy of Nursing Administration
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v.10
no.4
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pp.459-472
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2004
This study was designed to investigate perception of job rotation and an organizational commitment of staff nurses working at K hospital and find the way of increasing an organizational commitment for the groundwork for efficient changes in the nursing staff. Data were collected from Aug. 20 to Aug. 28, 2004 through self reporting questionnaires taken by 318 nurses working at a hospital. The three structured instruments were used for collecting the data; Questionnaires for measuring the perception of job rotation, Questionnaires for measuring the utility and the problem of job rotation, and Mowday's Organizational Commitment Questionnaires. The Results were as follows : 1. 66.0% of 318 staff nurses approved of regular job rotation; 34.0% of them disapproved 34.3% of them wanted to get transferred to another department; 65.7% of them didn't. 2. Of general characteristics, age(F=17.469, P=.000), marital status(F=-2.781, P=.006), religion(F=5.688, P=.001), education level(F=8.816, P=.000), position(F=15.591, P=.000), a total clinical career(F=11.606 p=.000) and field in practice(F=4.206, P=.000) were significantly related to an organizational commitment. 3. There is relatively positive correlation between the perception of job rotation and an organizational commitment. In conclusion, the utility of on the job rotation and organizational commitment showed the positive correlation.
The annual decomposition of cellulose and hemicellulose by microorganism and distribution of soil microbial flora were investigated in the humus horizon of a Pinus rigida stand in Mt. Kwanak. The cellulase activity was the lowest, 142$\mu$g glucose/g/hr from Dec. 1985 to Mar. 1986 and the highest, 760~1, 072$\mu$g glucose/g/hr in Jul. and Aug. 1985. The xylanase activity was 47% higher than the cellulase activity and was the lowest, 211~275$\mu$g xylose /g/hr from Feb. to Mar. 1986 and the highest as 799~1, 322$\mu$g xylose/g/hr from Jun. to Aug. 1986. The vertical distribution of the enzyme activity was decreased with the order of F, H, L, and A1 in both enzymes and the activities were exponentially decreased below L horizon, which suggests that most decomposition be done in F and H horizons with lots of organic matters. The SEM study slowed that the main decomposers of litters were fungi and initial attack into litters was also made by them. The enzyme activities of soil had strong correlations with the temperature and the precipitation. The correlation coefficients were 0.813 and 0.886 in the cellulase, and 0.673 and 0.626 in the xylanase for the temperature and the precipitation, respectively.
This paper contains the results obtained by the ecological investigation in Bijin island. The investigation was conducted during 3 dyas from Aug. 3 to Aug. 5, 1981. The results are followings. The tracheophyta of this island was recoreded as 64 families, 128 genera, 142 species, 21 varieties and 2 forma. Twenty eight species of ever-green broad-leaved trees comprising Gardenia jasminoides for. grandiflora, Castanopsis cuspidata var. thunbergii, Camellia japonica, etc. wad distributed in the southern area of the island. And there was the wind-break forest mainly consisting of aged Machilus thunbergii, Celtis sinensis and Zelkova serrata in the northern area. The northern area dominated by the second forest of Pinus thunbergii, where the whole residents lead their lives, shows the high population density and pure farming rate, so the natural degree is low. The other hand, there was the well-preserved forest of broad-leaved trees containing Zelkoba serrata. Acer palmatum and Quercus serrata, etc. in southern area having a steep peak, Seonyudai, and no resident. So, the potential vegetation of this island is assumed as the forest of ever-green broad-leaved trees which belongs to the forest of subtropics.
Three embankments, namely Changpo, Bokkil and Guil, in Chunggye Bay were investigated to assess the influence of environmental changes to phytoplankton size structure, distribution of species and standing crops. Three stations was sampled near at each embankment in Nov. 2006, Feb. 2007, May 2007 and Aug. Phytoplankton were classified into net-size (>20${\mu}m$) and nano-size (<20${\mu}m$). In summer, the freshwater discharge seemed to have influence in the decrease of salinity and in the increase of turbidity, ammonium and phosphorus concentrations. Chl a concentration and phytoplankton abundance in Feb. 2007 were observed to be generally higher in all stations compared to other periods. Net-size phytoplankton was observed to be higher in Feb. 2007 and May 2007 compared to nano-sized phytoplankton. However, there was shift in phytoplankton composition in Nov. 2006 and Aug. 2007. Phytoplankton under seven class (Bacillariophyceae, Chlorophyceae, Chrysophyceae, Cryptophyceae, Cyanophyceae, Dinophyceae, Euglenophyceae) was identified during the study period. It was found out that the major phytoplankton class was Bacillariophyceae. Phytoplankton was more diverse in autumn compared to any other season. Cyanophyceae was increased in summer. In rainy season, change in physical factors (salinity, transparency) seemed to have more influence on phytoplankton growth compared to inorganic nutrients.
In this study, the H2O reaction with SiO clusters was investigated using ab initio Monte Carlo simulations and density functional theory calculations. Three chemistry models, PBE1/DGDZVP (Model 1), PBE1/DGDZVP (Si atom), and aug-cc-pVDZ (O and H atoms), (Model 2) and PBE1/aug-cc-pVDZ (Model 3), were used. The average bond lengths, as well as the relative and reaction energies, were calculated using Models 1, 2, and 3. The average bond lengths of Si-O and O-H are 1.67-1.75 Å and 0.96-0.97 Å, respectively, using Models 1, 2, and 3. The most stable structures were formed by the H transfer from an H2O molecule except for Si3O3-H2O-1 cluster. The Si3O3 cluster with H2O exhibited the lowest reaction energy. In addition, the Bader charge distributions of the SinOn and (SiO)n-H2O clusters with n = 1-7 were calculated using Model 1. We determined that the reaction sites between H2O and the SiO clusters possessed the highest fraction of electrons.
In order to develop a cropping system that can produce garlic in the period of short supply from March to April, effects of low temperature treatment of seed bulbs and planting dates, starting date of low temperature treatment, days of low temperature treatment on plant growth, maturity and yield were studied in Southern strain, 'Namhae' and in Northern strain, 'Euiseong' of garlic (Allium sativum). The results obtained were as follows. In Sorthern strain, sprouting was significantly enhanced by low temperature treatment only in Sep. 14, and Sep. 29 plantings. Days to sprout were least in 30 days of low temperature treatment of Sep. 14 planting and in 45 days treatment of Sep. 29 planting. When considering on the beginning date of low temperature treatment, a marked difference was observed between treatments started before July 31 and after Aug. 15. Sprouting was most enhanced in 45 days low temperature treatment of Aug. 15 and Aug. 30 plantings. In Northern strain, sprouting was en hanced by low temperature treatment in planting from Sep. 29 to Nov. 13 and low temperature treatment for 60 days was most effective. Effect of low temperature treatment on early plant growth was observed in Sep. 14 and Sep. 29 plantings, but the effect on plant growth at intermediate stage or thereafter was observed in up to Oct. 29 plantings. Optimun days for low temperature treatment on growth enhancement was 45 and 60 days in Southern strain and 60 days in Northern strain in each planting dates. In Southern strain, the longer the low temperature treatment and the later the planting date the less the number of leaves developed. In Northern strain, normal leaves were not developed in plantings from Sep. 14 to Nov. 13. In Southern strain, clove differentiation and bulbing were earlist in 45 and 60 days treatment of Sep. 14, Sep. 29, and Oct. 14 planting initiated on July 31 and Aug. 15. In Northern strain, clove differentiation and bulbing were earlist in 60 days treatment of Oct. 14 planting initiated on Aug. 15 and Aug. 30. In treatment initiated later than above, longer the low temperature treatment the earlier the clove differentiation and bulbing in both Southern and Northern strains. The earlier the initiation date and the longer of low temperature treatment, the earlier bolting in southern strain. In Northern strain, bolting was most enhanced in 45 and 60 days of low temperature treatment initiated on Aug. 15 and Aug. 30. The longer the low temperature treatment in plantings thereafter, the earlier the bolting. The earlier the planting date garlic bulbs. Harvest date was earliest in 45 and 60 days low temperature treatment started from July 31 to Aug. 30 in Southern strain, and it was in 60 and 90 days low temperature treatment initiated from July 31 to Aug. 30 in Northern strain. Bulb weight was heaviest in 45 days low temperature treatment of Oct. 14 planting and next was in 45 days treatment of Sep. 29 planting in Southern strain. In Northern strain, bulb weight was heaviest in 60 days treatment of Oct. 14 planting and next was in 45 days treatment of Oct. 14 planting. When considered in the aspect of the beginning date of low temperature treatment, bulb weight was heaviest in 45 days treatment started on Aug. 30 in Southern strain and in 60 days treatment started on Aug. 15 in Northern strain. A high negative correlation between days to harvest and plant height on January 12, and a high positive correlation between days to harvest and days clove differentiation were observed. This indicates that enhanced plant growth and clove differentiation induced by low temperature treatment advanced the harvest date. A high negative correlation between bulb weight and days to clove differentiation, days to harvest suggests that the enhanced clove differentiation result and in heavier bulb weight. From the above results, it suggested that early crop of garlic can be harvested by planting at the period of Sep. 29 to Oct. 14 after 45 days of low temperature treatment of seed bulbs of Southern strain. Then harvest date can be shortened by 30 days compared to control and garlic can be harvested in early April.
The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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v.9
no.1
/
pp.40-49
/
2004
An ecological study on a sea urchin population, Strongylocentrotus nudus, a key role species in recovery of macroalgal bed, was conducted in Hosan, Samcheok area on the east coast of Korea. Three experimental plots, namely, AMB (artificially-restored macroalgal bed), BG (barren grounds) and NMB (natural macroalgal bed) were established after a pilot survey in June 2002. Distribution and abundance, grazing rates, predation pressure and predator guilds on S. nudus were estimated in three plots bimonthly from Aug. to Dec., 2002. Abundance of S. nudus was lowest, but median test diameter of the urchin was highest (Kruskal-Wallis test, p-value, p<0.001 in Aug. and p=0.003 in Oct.) in NMB In-situ grazing rate of S. nudus estimated by enclosure cage experiment in NMB was about 12 times higher in Aug. (160.0 mg seaweed/g sea urchin/day) than in Oct. (13.8). Predation intensity measured by tethering experiment was higher in NMB. Most of the predators on S. nudus were invertebrates and no fish predators were found. Predator guilds identified by the fish trap experiment using live or dead sea urchins included who]ks Neptunea arthritica, starfish Asterina pectinifera, hermit crabs Pagurus of. samuelis, Paguristes barbatus, brown shawl crabs Atergatis integerrimus and crabs Actaea subglobosa. High predation pressure on S. nudus in natural macroalgal beds was the likely cause of its low density. Elevated sea urchin density and the consequent lasting deforestation of macroalgae in barren grounds demonstrate the importance of predation pressure on sea urchins.
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