• Title/Summary/Keyword: ATH(Alumina trihydrate)

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Effect of Eco-friendly Inorganic Flame Retardants on Mechanical and Flame-Retardant Properties of EPDM Compound

  • Do, Jong Hwan;Kim, Do Young;Seo, Kwan Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.40-45
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    • 2020
  • In this study, the mechanical and flame-retardant properties of ethylene-propylene-diene-termonomer (EPDM) based rubber compounds and various other environmentally friendly inorganic flame retardants were investigated. Alumina trihydrate (ATH) and magnesium hydroxide (MDH) were used as inorganic flame retardants. The mechanical properties after thermal oxidation aging and the flame-retardant properties of the EPDM compounds were measured using a moving die rheometer, a universal testing machine, a compression set, and a UL 94 V flammability test. We focused on how the properties were affected by the type and amount of flame retardants. The results demonstrated that the optimal mechanical and flame-retardant V-0 grade properties were obtained at an ATH content of 200 phr.

Synthesis and Properties of High Voltage Silicone Rubber by Platinum-based Flame Retardant

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.6
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    • pp.283-292
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    • 2006
  • So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

The change of surface degradation properties of silicone rubber for salt fog (염무-열 반복 열화에 따른 실리콘 고무의 표면열화특성변화)

  • Oh, Tae-Seung;Lee, Chung;Park, Soo-Gil;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.886-889
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    • 2001
  • Silicone rubber is being used for the housing material of outdoor high voltage insulators such as composite insulator, bushing, surge arrestor and cable terminator because of good tracking and erosion resistance, good hydrophobicity and recovery of hydrophobicity and chemical stability. But, the leakge current occurs on surface of the composite polymeric insulation materials when the insulator is used for a long time with severe contaminative condition and it can lead the contamination flashover. So the leakage current is important to estimate the condition of the silicone rubber surface. In this paper, aging characteristics of silicone rubber used for outdoor insulation have been hydrophobicity of silicone rubber in salt fog chamber with average leakage current monitoring for observing the transformation of surface degradation properties of silicone rubber with different ATH(alumina trihydrate, A1$_2$O$_3$$.$3H$_2$O) filler contents. The experimental results show that a higher peak leakage current and to raise a long time for tracking with increasing amount of ATH by the salt fog and heat recycle ageing.

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The influence of filler for silicone rubber tracking (실리콘 고무의 트래킹에 미치는 충전재의 영향)

  • 허창수;장기순;조한구
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.344-350
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    • 1996
  • Tracking is one of the biggist problems to be overcome in polymeric materials for outdoor insulators. But It can be decreased with the addition of filler such as alumina trihydrate (ATH). In this paper, the tracking of surface and evaluation of insulating ability at silicone rubber is investigated, using the salt fog test. At initial state, the peak leakage current and numbers by dry band arcing is increasing with increasing the filler level, but at aged state decreasing at high concentration filler samples. This is because the roughness of the surface may contribute to the increase in peak leakage cur-rent and numbers. As increasing the filler level, the insulating ability of materials is higher and weight loss is decreased. The mechanism of insulating failure is occurred by the erosion than the tracking and the erosion caused weight loss of 2 g.

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The Surface Treatment of Fillers and Tracking Performance of Silicone Rubber (충진재의 표면처리와 실리콘 고무의 트래킹특성)

  • Lee, Soo-Boo;Ji, Won-Yeong;Lee, Chir-Kuy;Lee, June-Ho
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2364-2367
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    • 1999
  • Polymer insulating materials are widely used in power distribution and transmission systems for their good dielectric properties, light weight, low cost, and good contamination performance. Tracking is one of the biggest problems to be overcome in polymer insulating materials. The alumina trihydrate(ATH) is widely used as a filler for improve the tracking performance of silicone rubber. In this paper, we have investigated the influence of surface treatment of fillers on the tracking performance of silicone insulator using the IEC 587 tracking test method.

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Partial Discharge Characteristics in LLDPE-Natural Rubber Blends: Correlating Electrical Quantities with Surface Degradation

  • Aulia, Aulia;Ahmad, Mohd Hafizi;Abdul-Malek, Zulkurnain;Arief, Yanuar Z.;Lau, KwanYiew;Novizon, Novizon
    • Journal of Electrical Engineering and Technology
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    • v.11 no.3
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    • pp.699-706
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    • 2016
  • Partial discharges (PD) lead to the degradation of high voltage cables and accessories. PD activities occur due to the existence of impurities, voids, contaminants, defects and protrusions during the manufacture and installation of power cables. Commonly, insulation failures occur at cable joints and terminations, caused by inhomogeneous electric field distributions. In this work, a blend of natural rubber (NR) and linear low density polyethylene (LLDPE) was investigated, and the optimal formulation of the blend that could resist PD was discussed. The experiments were conducted under a constant high voltage stress test of 6.5 kV AC and the magnitude of partial discharge activities was recorded using the CIGRE method II. Pattern analysis of PD signals was performed along with the interpretation of morphological changes. The results showed that the addition of 10 wt% of NR and 5 wt% of Alumina Trihydrate (ATH) provided promising results in resisting PD activities. However, as the NR content increased, more micropores existed, thus resulting in increased PD activities within the samples.

Relation between Surface degradation and Anti-pollution Characteristics in RTV Silicone Rubber (RTV 실리콘 고무의 표면열화와 내오손 특성과의 상관관계)

  • 연복희;이태호;허창수;이상엽
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.7
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    • pp.598-606
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    • 2000
  • In this paper we investigated the relation between the surface degradations and anti-pollution characteristics of Room Temperature Vulcanized(RTV) silicone rubber coating that has different roughness through immersing into saline water. We utilized several analytic techniques such as atomic force microscopy(AFM) scaning electron microscopy(SEM) contact angle Salt Deposit Density(SDD) and average leakage current under the condition of salt fog. It is found that the surface roughness of treated RTV silicone rubber increased and the hydrophobicity of sample surface decreased with increasing the duration o immersion into water due to the erosion of base polymer the melting down alumina trihydrate(ATH) and the diffusion of Low Molecular weight(LMW) fluid. Despite the roughness of surface had been increased by water immersion excellant anti-pollution and recovery characteristics were maintained and SDD saturated to 0.1~0.14mg/cm$^2$. The average leakage current under salt fog increased with surface roughness. Measurement of average leakage current will be helpful to investigate surface degradation and lifetime expectation of RTV silicone coating.

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