• Journal of the Korean Society of Marine Environment & Safety
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• v.16 no.4
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• pp.361-367
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• 2010

The use of antifouling(AF) paints is the effective method for the protection of underwater structures from the development of marine fouling organisms. The ban on harmful substances in antifouling paints requires the development of new antifouling strategies although Tributyitin (TBT) compound had been used extensively as an active ingredient Alternatives should be as effective as conventional paints but have lower toxicity. In the present study, a TBT-free self-polishing (Cu SPC) AF paint containing $Cu_2O$, a Cu free SPC AF paint, and a Foul-release silicone AF paint, which were commercially available, were examined to investigate environmental erects of leakage waters employing Sebastes shlegeli and Artemia. Survival rates were inversely proportional to the concentration of leakage waters from AF paints and the acute toxicity of SPC AF paints was relatively higher than that of foul release AF paints.

• Polymer(Korea)
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• v.39 no.1
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• pp.122-129
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• 2015

Recently, the development of a new class of anti-fouling paint resin which has excellent anti-fouling performance and no persistence in the marine ecology is necessary. In this study, we first polymerized polyurethanes (PUs) as the other type of matrix which have carboxylic acid groups by using poly(ethylene glycol) (PEG), 4,4'-diphenylmethane diisocyanate (MDI), and 2,2'-bis(hydroxyl methyl)-propionic acid (DMPA). And next, we synthesized final resins having quaternary ammonium salts on pendant acid groups of PUs. After synthesis, the physical self-polishing property of resin by the measurement of reduced thickness in sea water was tested. The mechanical property of antifouling paint resin was good when the molecular weight of PEG was 600 or less. It was confirmed that the adhesion of PU resin was deteriorated when the content of quaternary ammonium salt was incorporated over specific value.

• Proceedings of the Korean Society of Fisheries Technology Conference
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• 2000.05a
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• pp.147-148
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• 2000

Marine algae는 주된 fouling organism으로 전세계에 널리 분포되어 있고, 경제적 손실을 가져온다. 특히나 container ships와 large tanker에서 자라는 algae는 마찰력의 증가로 인한 speed 감소와 연료비의 증가와 같은 문제점을 가진다. 그래서 현재 antifouling paint로 TBT화합물을 사용하고 있지만, 이것은 해양생물에 나쁜 영향을 미치는 것으로 나타나 TBT 화합물 사용에 대해 제한하고 있다. 따라서 본 연구에서는 해조류 추출물을 이용하여 무독성 천연 방오물질의 탐색을 목적으로 우선 선박이나 양식장 그물등에 많이 부착 성장하는 가시파래를 대상으로하여 이의 antifouling 효과를 나타내는 물질을 찾고자 한다. (중략)

• Journal of the Korean Institute of Navigation
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• v.18 no.2
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• pp.159-171
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• 1994

Hull roughness due to corrosions of outer hull and had applications on outer hull paints was analyzed theoretically. It's value which was gainable practically, was studied, and estimated power penalty formular correspon-ding to that value were reviewed. Local roughness penalty and roughness texture penalty that paint manahers in ship yard can easily were compared and studied by dotting actual ships in the issued curves. Losses and benifits of hull roughness & the specification choise of A/F paint which managers of ship maintenance were much interested in have been calculated through actual ships. The paper is illustrating that how much the specification choise and managing of A/F paint have effects on fuel consumption of ship in program. It is urgently required that recent developed antifouling paints of new A/F generation should be adopted to new ship building by big shipping companies in view of the environmental protection and the economical maintenance of ships.

• Korean Journal of Environment and Ecology
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• v.29 no.5
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• pp.736-742
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• 2015

Cosmopolitan green macroalga, Ulva pertusa is a widely spread species in most coastal waters. This benthic alga is appearing on marine objectives causes significantly economical and social problems. To prevent fouling organisms, new antifouling (AF) agents, such as ziram, diruon, zinc pyrithione, copper pyrithione, DBNPA and triclosan are used. However, the evaluations of new antifouling system of those agents strongly need more information on algae species for considering environment effect. Therefore, the purpose of this study was to evaluate the activity of antifouling system using Ulva spores and Nitzschia pungens. In addition, new AFS were evaluated the toxicity of microalga, Nitzschia pungens. In the motility of Ulva spores, ziram and zinc pyrithione were shown 50% higher inhibition motility than diuron, copper pyritione, DBNPA and triclosan. Ziram was appered the highest AFS of Ulva sore attachment. Copper pyrithione at the concentration of $100{\mu}g/L$ was inhibited 80% growth rate comparison of control. In conclusion, each new AF agents showed their specific AF activities against marine organisms based on this work.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.3 no.4
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• pp.249-260
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• 1998

To understand the attachment of micro algae and their subsequent growths on artificial surfaces immersed in seawater, the relationship between attachment of diatoms on the immersed artificial substrates and species pool in the surrounding water was investigated. We used acryl slides for the study of diatom attachment and examined the surrounding water samples collected in Incheon Harbour from July 1995 to February 1997. Variations of species composition and abundances by exposure time in seawater were investigated during the early phase of biofilm formation on various substrates, e.g. glass, acryl, titanium, copper and antifouling paint-treated slides. Immigration rates of diatoms to acryl slides during spring and winter were significantly correlated with the abundance of benthic diatoms in surrounding water ($r^2$=0.78, p<0.01, n=42), suggesting that immigration rates were affected by variations of benthic diatom abundances in surrounding water. Immigration coefficient of monoraphid diatoms was 5 times higher than that of biraphid diatoms, but relative abundance of monoraphid diatoms was 3 times lower than that of biraphid diatoms on acryl slides in spring. In winter, immigration coefficient and relative abundance of centric diatoms were higher compared to other raphe forms. These results suggest that the attachment of diatoms seems to be caused by the abundance and immigration coefficients of benthic diatoms in surrounding water. Pennate diatoms predominantly attached to all artificial surfaces throughout all experimental periods. Interestingly, centric diatoms predominantly attached to all artificial surfaces in winter. Hantzschia virgata, Licmophora abbreviata and Melosira nummuloides appeared dominantly on antifouling paint-treated slides, probably being tolerant of the antifouling paint. During incubations, the abundance of attached diatoms increased exponentially on glass, titanium and acryl slides with exposure time. The maximum abundance was highest on glass slide, followed by acryl, titanium, copper and antifouling paint-treated slides. The growth rates of attached diatom community on all artificial surfaces were higher at temperature of $24-25^{\circ}C$ than that of $2-3^{\circ}C$. The growth rate of attached diatoms on glass slide was generally higher compared to other slides during the study period. Dominant morphotypes of observed species with exposure time in seawater were prostrate form Amphora coffeaeformis, fan shape Synedra tabulata, stalk type Licmophora paradoxa and chain type M. nummuloides. A micro-succession in the attached microalgal community was observed. The composition of dominant species seems to be the result of species-specific response to gradually limited space with development of microalgal film.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.2
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• pp.253-258
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• 2016

The $MnO_x-WO_3-TiO_2$ nanoscale powders were synthesized by sol-gel method in order to prevent the biological fouling on the ships and offshore structures. Powder characteristics and antifouling performance were investigated with respect to the crystalline, microstructure and surface property for application in self-polishing copolymer resins. The high antifouling activity of $TiO_2$-system biocide was attributed to its redox potential and soluble metal ions originating from tungsten oxides according to the improvements in the powder characteristics. Based on their physio-chemical characterizations, the specific surface areas of powders were about $90m^2/g$ and the grain size was in the region 100 ~ 150 nm. Powder characteristics and surface properties were improved by the addition of $WO_3$. Antifouling performance were analyzed according to their surface properties and static immersion tests to determine the effects of the $TiO_2$-system compounds. The surface of 2 wt. % added sample was clean for 5 month. This may be attributed to the ability of $MnO_x-WO_3-TiO_2$ powders to act as a promoter in antifouling agents.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2002.11a
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• pp.39-44
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• 2002

Bans on TBT based antifouling paints have been drafted since 1999 by meetings 42, 43, 45 and 46 for the MEPC (Marine Environmental Protection Committee) of the International Marine Organization, and decided finally at a Diplomatic Conference of the IMO in October 2001. It was a key issue that there should be a global prohibition on the application of organo-tin compounds as biocides in Anti-fouling systems by Jan. 2003, and a complete prohibition on te presence of organo-tin compounds on ships by 1 Jan. 2008. This paper suggests a method to design International Anfi-fouling system cretificate, Record of anti-fouling system, Endorsement of the Records, Declaration on Anti-fouling System, Port State Control and reform(legislative) associated a law.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2003.05a
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• pp.206-211
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• 2003

Bans on TBT based antifouling paints have been drafted since 1998 by meeting 42, 43, 45 and 46 for the MEPC(Marine Environmental Protection Committee) of the International Marine Organization, and decided finally at a Diplomatic Conference of the IMO in October 2001. It was a key issue that there should be a global prohibition on the presence of organo-tin compounds in ships by 1 Jan. 2008. TBT Paint Waste from ship happens by vast quantity since 2003. This paper suggests a method to design Treatment System for TBT Paint Waste from Ship. The result of measurement in pyrolysis system were removal rate on 99％. at hight temperature in 1000$^{\circ}C$ and reaction time 1hr. TBT removal was more that 99％.

• Journal of Navigation and Port Research
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• v.27 no.4
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• pp.449-454
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• 2003

Bans on TBT based antifouling paints have been drafted since 1998 by meetings 42, 43, 45 and 46 for the MEPC(Marine Environmental Protection Committee) of the international Maritime Organization, and decided finally at a Diplomatic Conference of the IMO in October 2001. It was a key issue that there should be a global prohibition on the presence of organo-tin compounds in ships by 1 Jan. 2008. TBT Paint Wastes from ship have been produced by vast quantity since 2003. This paper suggests a method to design Treatment System for TBT Paint Waste from Ship. The organotion compound was dissolved by heating, and the organic matters was oxidized and turned into inorganotins, then they were stabilized in the end. At 500^{\circ}C$, the organotin compound which heated for one hour was removed by 58%, and in 1000^{\circ}C$ the organotin compound was treated by 99.9% after and hour of heating treatment.