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Indium doping induced defect structure evolution and photocatalytic activity of hydrothermally grown small SnO2 nanoparticles

  • Zeferino, Raul Sanchez;Pal, Umapada;Reues, Ma Eunice De Anda;Rosas, Efrain Rubio
    • Advances in nano research
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    • v.7 no.1
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    • pp.13-24
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    • 2019
  • Well-crystalline $SnO_2$ nanoparticles of 4-5 nm size with different In contents were synthesized by hydrothermal process at relatively low temperature and characterized by transmission electron microscopy (TEM), microRaman spectroscopy and photoluminescence (PL) spectroscopy. Indium incorporation in $SnO_2$ lattice is seen to cause a lattice expansion, increasing the average size of the nanoparticles. The fundamental phonon vibration modes of $SnO_2$ lattice suffer a broadening, and surface modes associated to particle size shift gradually with the increase of In content. Incorporation of In drastically enhances the PL emission of $SnO_2$ nanoparticles associated to deep electronic defect levels. Although In incorporation reduces the band gap energy of $SnO_2$ crystallites only marginally, it affects drastically their dye degradation behaviors under UV illumination. While the UV degradation of methylene blue (MB) by undoped $SnO_2$ nanoparticles occurs through the production of intermediate byproducts such as azure A, azure B, and azure C, direct mineralization of MB takes place for In-doped $SnO_2$ nanoparticles.

Analysis of Stress Behavior on Field Welded Joints of U-rib in Steel Bridge (U리브 현장용접이음부 응력거동에 관한 연구)

  • Kang, Chang Ib;Choi, Seong Min;Kook, Seung Kyu;Lee, Dong Uk
    • Journal of Korean Society of Steel Construction
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    • v.16 no.3 s.70
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    • pp.387-396
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    • 2004
  • In this paper, stress analysis anda 3-point bending fatigue test were conducted on the full-scale specimen to investigate the effects of misalignment at the U-rib welded joint due to misfitting in the steel deck bridge. In addition, the researchers investigated the direction and starting point of fatigue cracks by SEM (Scanning Electron Microscope) and beach mark. The results of the stress analysis show that maximum stress occurred at the bottom corner of the U-rib, and that the stress was large when the magnitude of the misalignment was large. On the other hand, the results of the static loading test of the full-scale specimen show that stress was large at the bottom corner of the U-rib. In addition, fatigue life was short when the misalignment was large and fatigue life was short when the misalignment was large and fatigue life was short when the misalignment was large and fatigue life was large when the misalignment was small, as indicated by the results of both the static loading test and the fatigue test. From the observation of the failure surface, fatigue cracks began manifesting at the root of the base metal and proceeded to the bead surface (weld toe).

The Interpreggtation of the Indian Stupa as Origin of Korean Pagoda (탑의 원조 인도 스투파의 형태 해석 - 인도 전역의 현장 답사를 바탕으로 -)

  • Lee, Hee-Bong
    • Journal of architectural history
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    • v.18 no.6
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    • pp.103-126
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    • 2009
  • This study aims to discover historical trends and change of form of all stupas in India with observation of field study that is as direct as possible, by classifying, analyzing, and synthesizing the stupas. Study of Indian stupa in Korea has a number of shortcomings since only introductory partial approach has been made in order to seek the origin of Korean pagoda. This study also aims to correct errors of stupa terminology in Chinese character committed by misinterpretation of Hindi language which was established by precedent Japanese scholars several decades ago. Piled-up stupas were totally destroyed by pagans, therefore their remains tell us only of structure, material, sizeand disposition. However remains of carved stone at torana and drum give us clues as to the original form of stupa and worshipping activity, as well as change to a more luxurious form. Many rock cave stupas of India show us both simple forms matching the ascetic age of early Buddhism and luxurious changes in Mahayanan era introducing us to statues of Buddha. Indians recovered the spheric form of 'anda,' a Hindi term meaning cosmic egg, from the hemispheric form of the piled-up stupa. Therefore we might discard the erratic term of 'bokbal', which means an upset vessel. Railings and parasols became main factors of stupa design. Carved railings around stupa became a sign of divinity. Serious worshipping activity made drums long or high and created multi-embossed stripes. Bases of circular drums of some cave stupas changed their shapes to rectangular or octagonal. Single parasols became multiparasols of affluent flowerlike curved stems on carved stupa. Multistoried, elongated and high parasols of Gandhara stupas are closely related to such factors as diverse changes of form in Indian subcontinent. Four-sided torana gate and ayaka column of the circular form of original stupas suggest the rectangular form of subsequent East Asian pagoda, and higher and wider base of Indian stupas became the origin of East Asian rectangular pagoda.

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An XML Access Control Method through Filtering XPath Expressions (XPath 표현식의 필터링을 통한 XML 접근 제어 기법)

  • Jeon Jae-myeong;Chung Yon Dohn;Kim Myoung Ho;Lee Yoon Joon
    • Journal of KIISE:Databases
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    • v.32 no.2
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    • pp.193-203
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    • 2005
  • XML (extensible Markup Language) is recognized as a standard of data representation and transmission on Internet. XPath is a standard for specifying parts of XML documents anda suitable language for both query processing and access control of XML. In this paper, we use the XPath expression for representing user queries and access control for XML. And we propose an access control method for XML, where we control accesses to XML documents by filtering query XPath expressions through access control XPath expressions. In the proposed method, we directly search XACT (XML Access Control Tree) for a query XPath expression and extract the access-granted parts. The XACT is our proposedstructure, where the edges are structural summary of XML elements and the nodes contain access-control information. We show the query XPath expressions are successfully filtered through the XACT by our proposed method, and also show the performance improvement by comparing the proposed method with the previous work.

A Study of Design of Hollow Fiber Membrane Modules for using in Artificial Lung by the PZT Actuator

  • Kim, Gi-Beum;Kim, Seong-Jong;Hong, Chul-Un;Lee, Yong-Chul;Kim, Min-Ho
    • Journal of Biomedical Engineering Research
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    • v.27 no.4
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    • pp.143-153
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    • 2006
  • The purpose of this work was to assess and quantify the beneficial effects of gas exchange, while testingto the various frequencies of the sinusoidal wave that was excited by the PZT actuator, for patients suffering from acute respiratory distress syndrome (ARDS) or chronic respiratory problems. Also, this paper considered a simulator to design a hollow type artificial lung, and a mathematical model was used to predict a behavior of blood. This simulation was carried out according to the Montecarno's simulation method, anda fourth order Runge-Kutta method was used to solve the equation. The experimental design and procedure are then applied to the construction of a new device to assess the effectiveness of the membrane vibrations. As a result, the vibration method is very effective in the increase of gas transport. The gas exchange efficiency for the vibrating intravascular lung assist device can be increased by emphasizing the following design features: consistent and reproducible fiber geometry, and most importantly, an active means of enhancing convective mixing of water around the hollow fiber membranes. The experimental results showed the effective performance of the vibrating intravascular lung assist device. Also, we concluded that important design parameters were blood flow rates, fiber outer diameter and oxygen pressure drop. Based on the present results, it was believed that the optimal level of blood flow rates was 200$cm^3$/min.

Monitoring of Main Tower of a Suspension bridge by GPS and IMU (GPS와 IMU에 의한 현수교 주탑 모니터링에 관한 연구)

  • Lee, Jae-one
    • Journal of the Korean Geophysical Society
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    • v.9 no.2
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    • pp.77-86
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    • 2006
  • Aplications of the real-time kinematic GPS surveying and inertial measurement unit have been beingRTK GPS allows the use of a static base station and remote rover unit to allow for data collectionwithin several seconds and in real time. It is useful for monitoring the behaviors of massive structureslike bridges. And this study purposed to implement a method of deciding the acurate dynaimc attitudeof structures by IMU. In this study, among GPS methods, we used RTK GPS to analyze the precisionof monitoring and then on the basis of it, we developed a monitoring system using RTK GPS anda deviation betwen observation values, X axis was 1mm, Y axis was 1mm and Z axis 2.2mm. I tturned out that it was possible to monitor and measure structures by RTK GPS and IMU.

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Dentinal defects induced by 6 different endodontic files when used for oval root canals: an in vitro comparative study

  • Pawar, Ajinkya M;Thakur, Bhagyashree;Kfir, Anda;Kim, Hyeon-Cheol
    • Restorative Dentistry and Endodontics
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    • v.44 no.3
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    • pp.31.1-31.9
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    • 2019
  • Objectives: To compare the formation of dentinal defects using stainless-steel hand K-files (HFs), rotary files, reciprocating files, and Self-Adjusting File (SAF), when used for oval root canals. Materials and Methods: One hundred and forty extracted human mandibular premolar with single root and oval canal were selected for this study. Oval canals were confirmed by exposing to mesio-distal and bucco-lingual radiographs. Teeth with open apices or anatomic irregularities were excluded. All selected teeth were de-coronated perpendicular to the long axis of the tooth, leaving roots segments approximately of 16 mm in length. Twenty teeth were left unprepared (control), and the remaining 120 teeth were divided into 6 groups (n = 20) and instrumented using HF (size 40/0.02), Revo-S (RS; size 40/0.06), ProTaper NEXT (PTN; size 40/0.06), WaveOne (WO; size 40/0.09), RECIPROC (RC; size 40/0.06), and the SAF (2 mm). Roots were then sectioned 3, 6, and 9 mm from the apex, and observed under stereomicroscope, for presence of dentinal defects. "No defect" was defined as root dentin that presented with no visible microcracks or fractures. "Defect" was defined by microcracks or fractures in the root dentin. Results: The control, HF, and SAF did not exhibit any dentinal defects. In roots instrumented by RS, PTN, WO, and RC files exhibited microcracks (incomplete or complete) in 40%, 30%, 55%, and 50%, respectively. Conclusions: The motor-driven root canal instrumentation with rotary and reciprocating files may create microcracks in radicular dentine, whereas the stainless-steel hand file instrumentation, and the SAF produce minimal or less cracks.

Study for the restoration of Gyeongcheonsa Pagoda - top of pagoda - (경천사(敬天寺) 10층석탑(層石塔) 복원(復原)에 관한 고찰 I - 상륜부(相輪部)를 중심으로 -)

  • Yi, Eun-Hui;Kim, Sa-Dug;Shin, Eun-Jeong
    • Korean Journal of Heritage: History & Science
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    • v.35
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    • pp.100-118
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    • 2002
  • Originally, Gyeongcheonsa pagoda was located in Busosan, Jungyeon-ri, Gwangdeok-myeon, Gaepung-gun, Gyeonggi-do,but it has suffered from being taken out to Japan illegally in 1907 and being returned to Korea in 1918. After returned to Korea, Gyeoncheonsa Pagoda had been neglected and restored in 1960. It had been exhibited outside the Gyeingbokgung Palace after restoration, but many problems were raised. It was taken to pieces in 1995 and it is conservation and restoring today. However, the top of pagoda is necessary to be researched about its archetype because the shapes of stupa in 1902 and in 1960(the shape of pagoda after restoration) are all different from its archetype. According to picture datum in 1902, the top of pagoda was a Korean building type on a 10 layered roof stone. On the other hand, when it was restored in 1960, cement suspected as a anda was taken place between Korean building type and a 10 layered roof stone. Therefore, I am going to examine Restoration of Gyeongcheonsa pagoda in this thesis. When we examine historical records of Geongcheonsa and datum of parts, we can know that the pagoda was established in 1348(Goryeo Dynasty) but it is difficult to know the truth of its establishment and demolition of Gyeongcheonsa-temple. Three ways to restore the top of the pagoda of Gyeoncheonsa Pagoda can be c o n s i d e r e d . First, Korean building type made by metals is located on a 10 layered roof stone, which is same to picture datum in 1902. Second, the shape of and a type, which is similar to the shape when it was restored in 1960's. Also it is similar to Lamapagoda type. Third, to restore the top of pagoda of gabled roof type, which is similar to the top of pagoda of Wongaksagi P agoda. However it is necessaray to exmamine functions about circle grooves hollowed out in a 10 layered roof stone in restoration. Also we need to find out the archetype of dragon sculpture through the dragon claws left on an edge of a 10 layered roof stone.

Unilateral approach for bilateral clipping of posterior communicating artery aneurysms in a hybrid operating room: A technical note

  • Juan Luis Gomez-Amador;Pablo David Guerrero-Suarez;Jaime Jesus Martinez-Anda;Jorge Fernando Aragon-Arreola;Andrea Castillo-Matus;Ricardo Marian-Magana;Marcos V Sangrador-Deitos;Alan Hernandez-Hernandez;Ernesto Javier Delgado-Jurado;Ricardo Santiago Villagrana-Sanchez;Abraham Gallegos-Pedraza;Jorge Luis Diaz-Espinoza
    • Journal of Cerebrovascular and Endovascular Neurosurgery
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    • v.25 no.4
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    • pp.468-472
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    • 2023
  • Bilateral posterior communicating (pComm) artery aneurysms represent only 2% of mirror intracranial aneurysms. Usually, these are surgically approached through bilateral craniotomies for clipping. We present the case of a 50-year-old female presenting with headache and horizontal diplopia. Neurological examination revealed a left oculomotor palsy, with no other neurological deficits. Imaging studies revealed bilateral aneurysmatic lesions in both internal carotid arteries (ICA). A conventional left pterional approach was planned in order to treat the symptomatic aneurysm, and, if deemed feasible, a contralateral clipping through the same approach. The procedure was performed in a hybrid operating room (HOR), performing an intraoperative digital subtraction angiography (DSA) and roadmapping assistance during dissection and clipping. Transoperatively, a post-fixed optic chiasm was identified, with a wide interoptic space, which allowed us to perform the contralateral clipping through a unilateral approach. This technique for clipping bilateral pComm aneurysms can be performed when the proper anatomical features are met.

Comparison of the Hydration, Gelatinization and Saccharification Properties of Processing Type Rice for Beverage Development (음료 개발을 위한 가공용 쌀의 수화, 호화 및 당화특성 비교)

  • Shin, Dong-Sun;Choi, Ye-Ji;Sim, Eun-Yeong;Oh, Sea-Kwan;Kim, Si-Ju;Lee, Seuk Ki;Woo, Koan Sik;Kim, Hyun-Joo;Park, Hye-Young
    • The Korean Journal of Food And Nutrition
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    • v.29 no.5
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    • pp.618-627
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    • 2016
  • This study evaluated the hydration, gelatinization, and saccharification properties of rice processing for beverage development. The properties of rice were studied on 10 rice cultivars (Samkwang, Ilpum, Seolgaeng, Anda, Dasan-1, Goami-4, Danmi, American rice, Chinese rice, and Thai rice) and employing four kinds of pre-treatment methods (dry grain, wet grain, dry flour, and wet flour). The results showed that moisture content of rice was between 11.88~15.26%. Increase in soaking time along with highest water absorption was noted in American rice cultivar (46.81%). The water binding capacity of Thai rice was higher when compared to that of other rice flours. In addition, solubility and swelling power of rice were 4.52~26.65% and 0.19~2.05%, respectively. The amylose content of Goami-4 was higher in rice processing. Using a rapid visco analyzer (RVA), the initial pasting temperature of Danmi cultivar was found to be the highest; the peak viscosities of Anda cultivar and Dasan-1 cultivar, and Chinese rice were higher than of those of other rice flours. After saccharification, the pH, soluble solids content, and reducing sugar content of rice processed through different pre-treatment methods were in the range of 6.22~7.08, $4.67{\sim}16.07^{\circ}Brix$, and 0.35~11.67% (w/w), respectively. In terms of color values, the L-value of dry grain, a-value of wet (grain, flour), and b-value of dry sample (grain, flour) were found to be the highest. Assessment of various factors and cultivars characteristics of the raw grains are of importance in the development of rice beverage.