• Title/Summary/Keyword: AEM

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Power Density Enhancement of Anion-Exchange Membrane-Installed Microbial Fuel Cell Under Bicarbonate-Buffered Cathode Condition

  • Piao, Jingmei;An, Junyeong;Ha, Phuc Thi;Kim, Taeyoung;Jang, Jae Kyung;Moon3, Hyunsoo;Chang, In Seop
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.36-39
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    • 2013
  • We introduce a high-performance microbial fuel cell (MFC) that was operated using a 0.1M bicarbonate buffer as the cathodic electrolyte. The MFC had a 136.42 $mW/m^2$ maximum power density under continuous feeding of 5 mM acetate as fuel. Results of the electrode potential measurements showed that the cathode potential of the bicarbonate-buffered condition was higher than the phosphate-buffered condition, although the phosphate condition had less interfacial resistance between the membrane and electrolyte. Therefore, we posit here that the increased power of the bicarbonate-buffered MFC may be caused by the higher cathode potential rather than by the interfacial membrane-electrolyte resistance.

Plating of Cu layer with the aid of organic film on Si-wafer (유기박막을 이용한 Si기판상의 구리피복층 형성에 관한 연구)

  • Park Ji-hwan;Park So-yeon;Lee Jong-kwon;Song Tae-hwan;Ryoo Kun-kul;Lee Yoon-bae
    • Proceedings of the KAIS Fall Conference
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    • 2004.06a
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    • pp.50-53
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    • 2004
  • 본 논문에서는 Si wafer와 Cu사이의 밀착력을 증가시키기 위해 Si wafer전처리 후 plasma와 SAMs처리 방법에 의한 Cu도금의 형성에 관한 방법을 설명하였다. Si wafer를 Piranha solution과 $0.5\%$ HF처리 후 유기박막인 SAMs과 plasma를 이용하는 방법으로 wafer와 Cu층 사이의 밀착력을 증가시켰다. 도금층의 밀착력은 scratch test 로 측정하였으며, AEM을 이용해 시편에 형성된 패턴의 형태를 관찰하고 SEM과 EDS를 이용해 시편의 조직을 관찰하였다. 그 결과 Si wafer를 O2, He, SAMs를 혼합처리 했을 때 밀착성이 가장 우수하였다.

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Structural performance of an electricity tower under extreme loading using the applied element method- A case study

  • Chin, Jason Ah;Garcia, Mauricio;Cote, Jeffrey;Mulcahy, Ellen;Clarke, Jonathan;Elshaer, Ahmed
    • Wind and Structures
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    • v.34 no.3
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    • pp.313-319
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    • 2022
  • The resiliency of electricity transmission and distribution lines towards natural and man-made hazards is critical to the operation of cities and businesses. The extension of these lines throughout the country increases their risk of extreme loading conditions. This paper investigates a unique extreme loading condition of a 100-year old distribution line segment that passes across a river and got entangled with a boom of a ship. The study adopts the Applied Elements Method (AEM) for simulating 54 cases of the highly deformable structural behaviour of the tower. The most significant effects on the tower's structural integrity were found to occur when applying the load with components in all three of the cartesian directions (i.e., X, Y and Z) with the full capacities of the four cables. The studied extreme loading condition was determined to be within the tower's structural capacity, attributed to the shear failure of the anchor bolts, which acted as a sacrificing element that fails to protect the transfer of tensioning load to the supporting tower.

Evaluating the Modular Facility of Non-point Source Pollution Management for Improving Lake Water Quality (상수원 수질개선을 위한 비점관리 모듈화 시설의 적용성 평가)

  • Park, Jong-Yoon;Rhee, Han-Pil;Son, Jang-Won;Lee, Seung-Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.48-48
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    • 2022
  • 본 연구에서는 상수원 수질개선을 위한 물환경관리 종합대책의 일환으로 장치형과 자연형 물환경관리시설을 복합 구성하여 강우 및 비강우 시 비점오염물질을 집중 저감 할 수 있는 맞춤형 비점관리 모듈화 시설을 제안하고, 그 적용성을 평가하고자 하였다. 이는 습지, 생태수로, 저류지 등으로 정형화된 기존의 수질개선 대책에서 탈피하여 대규모 댐유역에서 구조적 대책의 실효성과 효과성을 도모하기 위한 목적성을 지니고 있다. 이를 위해, 영천댐 유역을 대상으로 수질모형(HSPF, AEM3D)을 구축하고 목표수질 설정에 따른 수질개선 대책을 마련하였다. 여기서 수질개선 대책은 호내와 유역으로 공간적 범위를 구분하여 효과분석을 위한 단일 및 복합 모의 시나리오를 작성했으며, 평년 강우량과 가장 유사한 최근(2017년)의 영천호 수질과 비교하여 개선 효과를 평가하였다. 맞춤형 비점관리 모듈화 시설은 영천호 유입부에 기 조성된 인공습지(평시)와 연계하여 강우 시에는 모듈형(다기능 저류조, 스크린, 고효율여과) 장치를 통해 침강지로 최종 방류하는 것으로 구성하였다. 모듈화 시설의 연중 삭감량 추정 결과는 T-P 유달부하량을 기준으로 평시 32%, 강우 시 11%로 분석되었다. 자세한 모듈화 시설의 구성과 저감효율, 수질개선 대책 시나리오 적용에 따른 영천호 수질변화 분석 결과 등은 발표를 통해 제시될 예정이다.

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Investigating adsorption ion characteristics on cobalt oxides catalyst in electrolysis of waste alkaline solutions using ab-initio study (제일원리 전산모사법을 이용한 폐양액 수전해용 코발트 산화물 촉매의 흡착 이온 특성 연구)

  • Juwan Woo;Jong Min Lee;MinHo Seo
    • Journal of the Korean institute of surface engineering
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    • v.56 no.6
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    • pp.427-436
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    • 2023
  • In the industry, it is recognized that human activities significantly lead to a large amount of wastewater, mainly due to the increased use of water and energy. As a result, the growing field of wastewater resource technology is getting more attention. The common technology for hydrogen production, water electrolysis, requires purified water, leading to the need for desalination and reprocessing. However, producing hydrogen directly from wastewater could be a more cost-effective option compared to traditional methods. To achieve this, a series of first-principle computational simulations were conducted to assess how waste nutrient ions affect standard electrolysis catalysts. This study focused on understanding the adsorption mechanisms of byproducts related to the oxygen evolution reaction (OER) in anion exchange membrane (AEM) electrolysis, using Co3O4 as a typical non-precious metal catalyst. At the same time, efforts were made to develop a comprehensive free energy prediction model for more accurate predictions of OER results.

Recent Trends and Future Perspectives of the Magnesium Recovery based on Electrolysis (전해 기반 마그네슘 회수 기술의 관련 동향 및 향후 전망)

  • Sang-hun Lee
    • Resources Recycling
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    • v.33 no.2
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    • pp.16-23
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    • 2024
  • The electrolysis for extracting magnesium from seawater or brine primarily involves recovery of magnesium via precipitation as the form of magnesium hydroxide. The technology is classified into cation-exchange membranes (CEM), anion-exchange (AEM) membranes, electrodialysis, and membraneless methods. Recent research has focused on enhancing the efficiency and selectivity of magnesium recovery from seawater or brine containing magnesium, with expectations of effective magnesium recovery even with normal seawater. In a future, the optimization of the selective and efficient recovery of magnesium and various valuable substances through long-term operation of scaled-up systems is crucial with enhancing economic and environmental viability. It is essential to realistically estimate operational costs considering the membrane's lifespan and replacement cycle. Also, detailed and practical process models should be developed based on monitoring data on various factors.

Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process (사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석)

  • 박병흥;강대승;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.268-277
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    • 2004
  • process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

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A Review on Membranes and Catalysts for Anion Exchange Membrane Water Electrolysis Single Cells

  • Cho, Min Kyung;Lim, Ahyoun;Lee, So Young;Kim, Hyoung-Juhn;Yoo, Sung Jong;Sung, Yung-Eun;Park, Hyun S.;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.183-196
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    • 2017
  • The research efforts directed at advancing water electrolysis technology continue to intensify together with the increasing interest in hydrogen as an alternative source of energy to fossil fuels. Among the various water electrolysis systems reported to date, systems employing a solid polymer electrolyte membrane are known to display both improved safety and efficiency as a result of enhanced separation of products: hydrogen and oxygen. Conducting water electrolysis in an alkaline medium lowers the system cost by allowing non-platinum group metals to be used as catalysts for the complex multi-electron transfer reactions involved in water electrolysis, namely the hydrogen and oxygen evolution reactions (HER and OER, respectively). We briefly review the anion exchange membranes (AEMs) and electrocatalysts developed and applied thus far in alkaline AEM water electrolysis (AEMWE) devices. Testing the developed components in AEMWE cells is a key step in maximizing the device performance since cell performance depends strongly on the structure of the electrodes containing the HER and OER catalysts and the polymer membrane under specific cell operating conditions. In this review, we discuss the properties of reported AEMs that have been used to fabricate membrane-electrode assemblies for AEMWE cells, including membranes based on polysulfone, poly(2,6-dimethyl-p-phylene) oxide, polybenzimidazole, and inorganic composite materials. The activities and stabilities of tertiary metal oxides, metal carbon composites, and ultra-low Pt-loading electrodes toward OER and HER in AEMWE cells are also described.

Effects of Breathing Methods on Neck Muscle Activation in Subjects with a Forward Head Posture (호흡방법에 따른 전방머리자세의 목근육 활성도 변화)

  • Bae, Won-Sik;Lee, Hyun-Ok;Park, Du-Jin
    • PNF and Movement
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    • v.15 no.2
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    • pp.159-166
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    • 2017
  • Purpose: This study attempts to determine the effects of applying three kinds of breathing exercises for four weeks on the neck muscle activation of subjects with a forward head posture. Methods: A total of 30 adults aged in their twenties (15 men and 15 women) with a forward head posture who voluntarily agreed to participate after listening to the purpose and procedure of this research were chosen as the subjects of this study. The subjects were randomly divided into either the diaphragmatic breathing exercise (DBE) group, the abdominal drawing-in maneuver (ADIM) group, or the abdominal expansion method (AEM) group according to the breathing intervention scheme. Each group included ten subjects. The muscle activity of the sternocleidomastoid, scalenus anterior, and splenius capitis was measured in all the groups prior to the intervention, two weeks after the intervention, and four weeks after the intervention. All the interventions were implemented for 30 minutes a day, three times a week, for a total of four weeks. Results: No significant between-group difference was observed in terms of the change in neck muscle activity according to the four-week intervention scheme. Further, there was no interaction between the intervention period and the intervention scheme in relation to the change in neck muscle activity. Conclusion: The results of this study suggest that abdominal expansion exercise is as effective as other breathing exercise methods for subjects with a forward head posture. We therefore expect that abdominal expansion exercise can be used as a scheme for the prevention of symptoms as well as therapy for patients with a forward head posture.

Preparation of $Yb_2O_3$ Film by MOCVD Method (MOCVD 공정을 이용한 $Yb_2O_3$ 박막 제조)

  • Jung, Woo-Young;Jun, Byung-Hyuk;Park, Hai-Woong;Hong, Gye-Won;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.75-80
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    • 2006
  • [ $Yb_2O_3$ ] films were successfully deposited on a cube-textured Ni and(100) $SrTiO_3$(STO) single crystal substrates by metal organic chemical vapor deposition(MOCVD) method using $H_2O$ vapor as an oxidant. $H_2O$ vapor was used in order to avoid the oxidation of Ni substrate. The working pressure and Ar flow rate were 10 Ton and 600 sccm, respectively. $Yb_2O_3$ films on STO were formed at high temperatures above $900^{\circ}C$. While XRD peaks from $Yb_2O_3$ were hardly detected at $900^{\circ}C$, the $Yb_2O_3$(400) texture was developed fur the films grown at deposition temperatures above $950^{\circ}C$. The AEM surface roughness of $Yb_2O_3$ film, grown on STO, was in the range of $6{\sim}10nm$ for the film deposited at $950^{\circ}C$ with a $H_2O$ vapor partial pressure of 5.5 Ton and deposition times of 3 and 5 mins. For cube-textured Ni substrate, both $Yb_2O_3$(222) and $Yb_2O_3$ (400) textures were developed textures at deposition temperatures above $850^{\circ}C$.

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