• Title/Summary/Keyword: AC corrosion

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The Pitting Inhibition of Fe-Cu Alloy in Weakly Alkaline Solution under Wet-Dry Condition

  • Kim, Je-Kyoung;Kang, Tae-Young;Moon, Kyung-Man
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.175-178
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    • 2007
  • Pure iron, Fe-0.4, and 1.2 wt.%Cu alloys were examined by conducting the electrochemical techniques in the weakly alkaline solution, pH9, controlled by $Ca(OH)_2$, solution added with 0.02M NaCl. The $R_P$ measured from ac impedance, selected 10 kHz and 10mHz, in weakly alkaline solutions containing chloride ions indicated that the addition of copper up to 1.2wt.% into the pure iron significantly improved the pitting resistance of iron. In contrast to alloy, the pure iron showed the rapid pitting occurrences in drying period. During the drying period, the corrosion potential of pure iron was shifted to less noble value, pitting initiation.

A Study on the Squeeze Casting of Al-7.0Si-0.4Mg Alloy for Fuel System Parts (Al-7.0Si-0.4Mg 합금 자동차 연료계 부품의 스퀴즈 캐스팅에 관한 연구)

  • 김순호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.12
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    • pp.48-54
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg (AC4C) alloy fabricated by squeeze casting process for development of Fuel system Parts (Fuel rail). The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2$Si precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg ahoy revealed 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy have good corrosion resistance in electrochemical polarization test.

Anti-Corrosion Behaviour of Rebar in Cement Mortar by Electrochemical Chloride Extraction (전기화학적 염소 추출법에 의한 시멘트 모르터내의 철근 방식)

  • Nam Sang Cheol;Lim Young Chang;Cho Won-Il;Cho Byung Won;Chun Hai Soo;Yun Kyung Suk
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.31-38
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    • 2000
  • Anti-corrosion behaviour of rebar embedded in cement mortar containing chloride ions was investigated by electrochemical chloride extraction(ECE). $43\%$ of the initial chloride ions of the cement mortar was fixed to Friedel salts and the soluble chloride ions were successfully extracted by ECE method. Concentration profiles of the chloride ions were estimated by Fick's 2nd law with time and depth, and it was close to the real value. The corrosion potential increased to anodic direction after ECE test, and the corrosion of rebar was reduced as a result of AC impedance spectroscopy.

The Study on the AC Interference of High Power Cable on Underground Gas Pipeline (전력케이블과 가스배관의 병행구간에 대한 교류부식 영향 검토 연구)

  • Bae, J.H.;Kim, D.K.;Ha, T.H.;Lee, H.G.;Kwak, B.M.;Lim, C.J.
    • Proceedings of the KIEE Conference
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    • 2000.07a
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    • pp.470-473
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    • 2000
  • Because of the continuous growth of energy consumption, and also the tendency to site power lines and pipelines along the same routes, the close proximity of high voltage structures and metallic pipelines has become more and more frequent. Moreover, normal steady state and fault currents become higher as electric networks increase in size and power. Therefore, there has been and still is a growing concern (safety of people marking contact with pipeline, risk of damage to the pipeline coating, the metal and equipment connected to pipeline. especially cathodic protection system) about possible hazards resulting from the influence of high voltage power system on metallic structures(gas pipeline, oil pipeline and water pipeline etc.). Therefore, we analyze the interference problems when the gas pipeline is buried with power cable in the same submarine tunnel. This paper present the results of the study about interference mechanism, AC corrosion, limitation of safety voltage and analysis of indiction voltage.

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A Study on Fatigue Crack Behavior of Metal Matrix Composites for Automobile Engine (자동차엔진용 금속기 복합재료의 피로균열거동에 관한 연구)

  • 박원조;허선철;정재욱;이해우;부명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.140-146
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    • 2003
  • Metal matrix composites had generated a lot of interest in recent time because of their high specific strength and stiffness in specific properties. It was also highlighted as the material of frontier industry because strength, heat-resistance, corrosion-resistance and wear-resistance were superiored. In this study, the strength properties of $Al_{18}B_{4}O_{33}$/AC4CH composites were represented mixing the binder of $SiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_{4}O_{33}$/AC4CH was fabricated at the melt temperature of $760^{\circ}C$, the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa. Consequently, fatigue life was observed roughly in the order of AC4CH> nobiner> $SiO_2$, independently on crack propagation direction and stress ratio.

Module-Type Switching Rectifier for Cathodic Protection of Underground and Maritime Metallic Constructions (지하매설 및 해양 금속구조물 음극방식용 모듈 타입 스위칭 정류기)

  • 문상호;김보경;김인동;노의철;권영원;정성우;임헌호
    • The Transactions of the Korean Institute of Power Electronics
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    • v.7 no.6
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    • pp.570-578
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    • 2002
  • Cathodic protection is widely used to prevent corrosion of steel materials buried in the underground and sea. As a rectifier for cathodic protection, the conventional phase-controlled rectifiers have been used so far in spite of such shortcomings as large volume, heavy weight and floor power factor. In order to overcome such disadvantages, this paper proposes a new module-type switching rectifier for cathodic protection, which is composed of two parts, namely, AC/DC converter and module- type DC/DC converter. The AC/DC converter is a single-phase IGBT PWM rectifier, thus resulting in almost unity power factor and controlled DC output voltage. The module-type DC/DC converter operates under ZVS/ZCS switching condition to permit high frequency switching operation. It enables to use high-frequency transformer for electrical isolation, thus reducing volume and weight of overall system and improving system efficiency. It should be anticipated that the proposed rectifier techniques apply to the similar technical areas.

EIS monitoring on corroded reinforcing steel in cement mortar after calcium electro-deposition treatment (칼슘 전착처리 후, 시멘트 모르타르 속 철근의 부식속도에 대한 EIS 모니터링)

  • Kim, Je-Kyoung;Kee, Seong-Hoon;Yee, Jurng-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.1-8
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    • 2019
  • The primary purposes of this study are to understand a fundamental effects of electro-deposition on reinforcing steel in saturated Ca(OH)2 electrolyte, and evaluate the corrosion rates of rebars under cyclic 3wt.%NaCl immersion and dry corrosion environment. The three cement mortar specimens with cover thickness 5, 10 and 30mm, were prepared in the experiment. To monitor the corrosion rates of rebars in mortar, the three cement mortar specimens were exposed to 110 wet-drying cycles(8-hour-immersion in 3wt.%NaCl and 16-hour-drying in a room temperature) in the laboratory. During the wet-dry cycles, the polarization resistance, Rp, and solution resistance, Rs, were continuously measured. The instantaneous corrosion rates of rebars on the effect of electro-depositing with sat. Ca(OH)2 electrolyte were estimated from obtained R-1p and degrees of wetness were estimated from Rs values. From the experimental results, the corrosion rates of rebars were greatly accelerated by wet/dry cycles. During the mortars exposed to drying condition, the large increases in the corrosion rates were showed at all rebar surfaces in three mortar specimen, attributed from the accelerated reduction rates of dissolved oxygen in drying process. However, the corrosion rates on rebar surface electrochemically deposited with sat. Ca(OH)2 electrolyte showed the clear decreases, caused by calcium deposits in the porous rust layer.

Application of Fractal Geometry to Interfacial Electrochemistry - II. Impedance Behaviour of Fractal Electrodes

  • Shin Heon-Cheol;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.4 no.1
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    • pp.26-33
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    • 2001
  • This article involves the application of the fractal geometry to interfacial electrochemistry. Especially, we gave our attention to impedance behaviour of the fractal electrode. First, this article briefly explained the constant phase element (CPE) in electrochemical impedance and the do Levie's transmission line model. Second, we introduced the Nyikos and Pajkossy's theoretical works to approach the CPE phenomena using the fractal geometry. Finally this article presented other various fractal models for analysing the ac response of the rough electrodes.

A Study on the ICCP Control and Monitoring System for Ship (선박용 ICCP 제어 감시 시스템에 관한 연구)

  • 이지영;오진석
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.4
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    • pp.667-674
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    • 2004
  • This thesis is about the Impressed Current Cathodic Protection (ICCP) control and monitoring system. which brings protection against the corrosion of the ship's hull in the sea environments. The ICCP system is composed of a power supply. anode. reference electrode and controller. AC sources from the ship's generator are converted to DC sources in terms of power supply, and a protection current is sent to ship's hull though anode. The controller fully senses whether or not the detected potential is within a range of protection of ship's hull and then it is automatically controlled to increase or decrease the amount of protective current to be sent to the anode. The monitoring system with RS 232/485 communication is also studied in order to check the normal state of the system at a long period. because an operator does not always watch over this system and thus the system cannot operate well because of his or her negligent management. Since the vessel always navigates in the sea. an characteristics experiment of the ICCP system is conducted by introducing various corrosive environmental factors such as velocity, resistivity, dissolved oxygen, PH, temperature and contamination degree. These results must be referred to when the ICCP system is set up. In short. the ICCP is a multi-system for use on ships and on land structures because it includes a safety device. It is suggested that this system can accomodate a ship's automation and will be very useful.