• 분석과학
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• 제7권4호
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• pp.505-515
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• 1994

DMSO(dimethylsuloxide-$d_6$) 용액 속에 존재하는 CN/CN 리간드의 hemin 착물과 CN/DMSO의 hemin 착물이 $^1H$ NMR로 기록되어지고 분석되어졌다. Hemin으로의 CN 착물화 과정은 온도에 따라 변화함을 NMR 스펙트럼이 보여 주며, 한 개의 CN 리간드에서 두 개의 CN 리간드착물로 바뀌는 과정의 열역학함수는 ${\Delta}H^{\circ}=736.6cal/mol$ 및 ${\Delta}S^{\circ}=16.4eu$인 흡열과정을 나타낸다. CN/DMSO의 hemin 착물은 Curie behavior로부터의 벗어남은 high-spin 성격의 존재를 나태내고, 이는 Fe-DMSO 결합이 순간적으로 깨짐을 의미하며, 이러한 CN/DMSO hemin 착물이 한 개의 axial ligand가 약한 heme 단백질의 전자 및 분자구조의 model complex로 작용할 수 있음을 보여 준다.

• 천문학논총
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• 제12권1호
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• pp.99-109
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• 1997

We obtained the CN($\Delta_V=0$) and $C_2(\Delta_V=0,\;\pm1$) spectra of comet Hale-Bopp(C/1995 O1) at the Kyunghee Observatory and Bohyunsan Astronomical Observatory between March 7 and May 12, 1997 The fluxes for each molecular band were measured and then the production rates and column densities of CN and $C_2$ were calculated using a simple model. The resultantproduction rates of CN and $C_2$ are logQ(CN)=27.4 at r=0.94 AU(preperihelion) and $logQ(C_2)=27.3$ at r=0.94 AU(postperihelion), respectively.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제7권2호
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• pp.184-201
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• 2013

In this paper, we study the problem of designing the power and number of cooperative node (CN) in the cooperation phase to maximize the average throughput for secondary user (SU), under the constraint of the total cooperation and transmission power. We first investigate the scheme of cooperative spectrum sensing without a separated control channel. Then, we prove that there indeed exist an optimal CN power when the number of CNs is fixed and an optimal CN number when CN power is fixed. The case without the constraints of the power and number of CN is also studied. Finally, numerical results demonstrate the characteristics and existences of optimal CN power and number. Meanwhile, Monte Carlo simulation results match to the theoretical results well.

• 한국수자원학회논문집
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• 제30권4호
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• pp.379-387
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• 1997

논에서의 수문 특성을 현장 조사 및 측정하고, 강우-유출 자료로부터 논의 최대 잠재저류장의 확률적 특성을 분석하여, 선행강우조건에 따른 CN을 추정하였다. 추정된 CN은 AMC II의 경우 78이었으며, AMC-I, III의 경우에는 각각 63, 88이었다. 논의 강우-유출자료에 의한 CN은 년 홍수량 자료의 적용여부가 불확실하므로 이를 보완하고, 물고높이나 초기담수심의 영향을 구체적으로 규명하기 위하여 논의 물수지 모형을 구성하였다. 논의 유출량은 선행 강우뿐 아니라 초기담수심에 따라 변화하므로 최대 잠재저류량을 이용하여 CN을 결정하기에는 어려움이 따른다. 따라서, 최대 잠재저류량의 경우와 같이 담수심의 확룰분포함수를 이용하여 CN을 추정하였다. 물수지모형을 이용하여 확률담수심, 물고높이 및 기상자료로부터 논의 유출량을 추정하였다. 추정된 유출량으로부터 CN을 계산하고, 확률 담수심에 해당하는 CN-I, CN-II, CN-III을 결정하였으며, 그 값은 각각 70, 79, 89이었다.

• 센서학회지
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• 제15권1호
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• pp.53-57
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• 2006

This paper describes a novel processing technique for fabrication of polymer-derived SiCN (silicone carbonitride) microstructures for super-temperature MEMS applications. PDMS (polydimethylsiloxane) mold is fabricated on SU-8 photoresist using standard UV photolithographic process. Liquid precursor is injected into the PDMS mold. Finally, solid polymer structure is cross-linked using HIP (hot isostatic pressure) at $400^{\circ}C$, 205 bar. Optimum pyrolysis and annealing conditions are determined to form a ceramic microstructure capable of withstanding over $1400^{\circ}C$. The fabricated SiCN ceramic microstructure has excellent characteristics, such as shear strength (15.2 N), insulation resistance ($2.163{\times}10^{14}{\Omega}$) and BDV (min. 1.2 kV) under optimum process condition. These fabricated SiCN ceramic microstructures have greater electric and physical characteristics than bulk Si wafer. The fabricated SiCN microstructures would be applied for supertemperature MEMS applications such as heat exchanger and combustion chamber.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.2955-2959
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• 2011

Second-order rate constants for nucleophilic substitution reactions of 2,4-dinitrophenyl benzenesulfonate 1a with a series of alicyclic secondary amines in MeCN have been measured spectrophotometrically and compared with those reported previously for the corresponding reactions performed in aqueous medium to investigate the effect of medium on reactivity and reaction mechanism. The amines employed in this study are found to be more reactive in the aprotic solvent than in $H_2O$. The reactions of 1a in MeCN result in a linear Br${\o}$nsted-type plot with ${\beta}_{nuc}$ = 0.58, which contrasts to the curved Br${\o}$nsted-type plot reported previously for the corresponding reactions performed in the aqueous medium (i.e., ${\beta}_2$ = 0.86 and ${\beta}_1$ = 0.38). Accordingly, it has been concluded that the reaction mechanism changes from a stepwise mechanism to a concerted pathway upon changing the medium from $H_2O$ to MeCN. Reactions of Y-substituted phenyl benzenesulfonates 1a-c with piperidine in MeCN result in a linear Br${\o}$nsted-type plot with ${\beta}_{lg}$ = -1.31, indicating that expulsion of the leaving group is significantly more advanced than bond formation in the transition state. The trigonal bipyramidal intermediate ($TBPy^{\pm}$) proposed previously for the reactions in $H_2O$ would be highly unstable in MeCN due to strong repulsion between the negative charge in $TBPy^{\pm}$ and the negative dipole end of MeCN. Thus, destabilization of $TBPy^{\pm}$ in MeCN has been concluded to change the reaction mechanism from a stepwise mechanism to a concerted pathway.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.392-393
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• 2006

This paper describes the fabrication of SiCN microstructures for super-high temperature MEMS using photopolymerization of pre-ceramic polymer. In this work. polysilazane liquide as a precursor was deposited on Si wafers by spin coating. microstructured and solidificated by UV lithography. and removed from the substrate. The resulting solid polymer microstructures were cross-linked under HIP process and pyrolyzed to form a ceramic of withstanding over $1400^{\circ}C$. Finally, the fabricated SiCN microstructures were annealed at $1400^{\circ}C$ in a nitrogen atmosphere. Mechanical characteristics of the SiCN microstructure with different fabrication process conditions were evaluated. The elastic modules. hardness and tensile strength of the SiC microstructure implemented under optimum process conditions are 94.5 GPa, 10.5 GPa and 11.7 N/min, respectively. Consequently, the SiCN microstructure proposed in this work is very suitable for super-high temperature MEMS application due to very simple fabrication process and the potential possiblity of sophisticated multlayer or 3D microstructures as well as its good mechanical properties.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
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• pp.125-128
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• 2004

In this paper, a novel processing technique for fabrication of high-temperature MEMS based on polymer-derived SiCN microstructures is described. PDMS molds are fabricated on SU-8 photoresist using standard UV-photolithographic processes. Liquid precursors are injected into the PDMS mold. And then, the resulting solid polymer structures are crosslinked under isostatic pressure, and pyrolyzed to form a ceramic capable of withstanding over $1500^{\circ}C$. These fabricated SiCN structures would be applied for high-temperature applications, such as heat exchanger and combustion chamber.

• 한국광학회:학술대회논문집
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• 한국광학회 1990년도 광학 및 양자전자학 워크샵
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• pp.94-100
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• 1990

The rapid quenching dynamics of the F-center excitation by CN- defects in CsCl crystals were investigated by monitoring the ground state bleach recovery kinetics of F-centers, using a picosecond streak camera absorption spectrometer. The F-centers in CN- doped quenched samples show two bleach recovery components. Optical aggregation converts the slow component to the fast component. The slow one is due to the normal relaxation of the F*-centers as found in CN_ free crystals. The fast one is due to the energy transfer of the F-center electronic excitation to the vibrational energy levels of CN_ molecualr defects. The energy transfer occurs only in the F-center-CN_ defect pairs, FH(CN_)-centers.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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• pp.376-379
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• 2003

In this paper, a novel processing technique for fabrication of high-temperature MEMS based on polymer-derived SiCN microstructures is described. PDMS molds are fabricated on SU-8 photoresist using standard UV-photolithographic processes. Liquid precursors are injected into the PDMS mold. And then, the resulting solid polymer structures are crosslinked under isostatic pressure, and pyrolyzed to form a ceramic capable of withstanding over $1500^{\circ}C$. These fabricated SiCN structures would be applied for high-temperature applications, such as heat exchanger and combustion chamber.