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Thermally Robust Highly Crosslinked Poly(methyl methacrylate-co-divinyl benzene) Microspheres by Precipitation Polymerization

  • Shim, Sang-Eun;Sunhye Yang;Hyejeon Jung;Soonja Choe
    • Macromolecular Research
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    • v.12 no.2
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    • pp.233-239
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    • 2004
  • We prepared thermally robust fully crosslinked poly(methyl methacrylate-co-divinyl benzene) [poly(MMA-co-DVB)]microspheres successfully by precipitation polymerization in the absence of a stabilizing agent. The DVB concentration plays a pivotal role not only in the formation of the individually stable microspheres but also in the polymerization characteristics, including the particle size, the uniformity of size, the polymerization yield, and the thermal properties. The number-average diameter of the microspheres increased linearly, from 0.72 to 2.15 $\mu\textrm{m}$, and the particle size distribution became narrower, by elevating the uniformity from 1.35 to 1.12, as the DVB concentration increased from 20 to 75 mol%. In addition, the yield of the polymerization increased, from 73.4 to 98.6%, as the DVB concentration increased. Since the prepared particles possess fully crosslinked microstructures, no glass transition temperatures were observed, but all the samples prepared with DVB concentrations ranging from 20 to 75 mol% possess enhanced thermal properties. Based on the DSC and TGA data, the thermal stability of the mesospheres prepared by the precipitation polymerization is significantly improved as a result of crosslinking with DVB.

Selected Properties of Particleboard Made from Sugar Palm (Arenga pinnata) Dregs

  • Faza AISYADEA;Greitta Kusuma DEWI;Ragil WIDYORINI
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.5
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    • pp.334-344
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    • 2023
  • Dregs from the sugar palm (Arenga pinnata) starch industry are considered a waste product of the agricultural industry and have not yet been optimally utilized. Therefore, this study aimed to manufacture particleboards from dregs using different amounts of adhesive and particle size ratios. Sugar palm dregs, which had been separated into fibers and powder/fine particles, were used as raw material for making particleboards. The fiber had an average length of 6.84 ± 3.23 cm, while the fine particles were of a size that passed through size 10 mesh and remained in size 60 mesh. Three ratios of fiber to fine particles (100:0, 75:25, and 50:50 wt%) with three different amounts of sucrose-citric acid adhesive (10, 15, and 20 wt%) were used in this study. Increasing the amount of fine particles and the resin content can improve the physical properties and the internal bond strength of boards made from sugar palm dregs. The fine particles possibly filled the gap between the fibers in the particleboard, while the fibers exhibited a high bending strength. As a result, a high-performance particleboard can be attained by combining the composition ratio of fiber/fine particles and resin content. In this study, particleboards made from fiber/fine particles (75:25 wt%) and adhesive content of 15 wt% and 20 wt% had the mechanical properties that met the requirements of Japanese Industrial Standard (JIS) A 5908 type 18. Sugar palm dregs have the potential to be used as raw materials to create value-added particleboards.

Effects of Planting Density and Harvesting Time on Production of Small-size Tuberous Roots in Sweet Potato (소형 고구마 생산을 위한 재식거리와 수확시기의 영향)

  • Lee, Na-Ra;Choi, Kyu-Hwan;Lee, Seung-Yeob
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.60 no.4
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    • pp.491-497
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    • 2015
  • Small-sized tuber of sweet potato (Ipomoea batatas Lam.) is more preferred by Korean consumers, because it is convenient to eat with hands, and can easily be steamed or roasted in small pan as a healthy snack for a small family. The present study was aimed to investigate the effect of high-density plantings and harvesting times on production of smallsized tuber (50~200 g). Four varieties ('Annobeny', 'Daeyumi', 'Shinzami', and 'Yeonhwangmi') were planted in 2-row zigzag high-density planting ($75{\times}30cm$, A; $75{\times}25cm$, B) and 1-row planting ($75{\times}25cm$, control) covered with black vinyl film on May 23th, 2014. Marketable yields and small-sized tuber yields were compared between 120- and 150-day harvesting. Vine length and fresh weight per plant were significantly decreased in 2-row planting A and B plots compared to the control at 120 days after planting. Weight of tuber per plant, mean weight of tuber and number of tuber per plant were significantly decreased in 120-day harvesting of A and B plots than in the control. Marketable yields per 10a were increased by 17% ($2.4ton{\cdot}10a^{-1}$) and 8% ($2.6ton{\cdot}10a^{-1}$) in 120-day harvesting of A and B plots compared to the control ($2.4ton{\cdot}10a^{-1}$), and those were largely increased by 29% ($4.0ton{\cdot}10a^{-1}$) and 26% ($3.9ton{\cdot}10a^{-1}$) in 150-day harvesting than in the control ($3.1ton{\cdot}10a^{-1}$). Proportions of small size tuber (50~200 g) were increased by about 65% in 150-day harvesting of A and B plots compared to the control (55.3%). Small-size tuber yield and marketable yield were highly increased in 150-day harvesting of 2-row zigzag high-density planting A ($75{\times}30cm$).

A Study on Smoke Movement by Using Large Eddy Simulation II. Smoke Control Systems and Opening Size (대와류모사를 이용한 연기이동의 연구 II. 제연방식과 개구부의 크기)

  • 박외철
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.34-38
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    • 2003
  • The large eddy simulation based Fire Dynamics Simulator was utilized to investigate the effects of the size of an opening on smoke removal performance for the three smoke control systems-ventilation purge, and extraction. Three different opening sizes, $r_A$=1, 2, and 3 were investigated while the flow rate remained 0.75 $m^3/s$ at the inlet or outlet depending on the systems. Increase of the opening size did not give a significant difference in the smoke removal rate for the three smoke control systems, though the increasing opening size slightly improved smoke removal. The extraction system was shown the best smoke control system, and the purge system yielded low performance compared to the other two systems for all the different opening sizes.

A production rescheduling system for a large size parallel machine flow shop (대규모 병렬기계 흐름생산의 재일정계획)

  • Chung, Nam-Kee;Yoo, Chul-Soo;Kim, Jong-Min;Choi, Jeong-Gil
    • IE interfaces
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    • v.9 no.2
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    • pp.75-82
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    • 1996
  • A scheduling system is developed for a parallel machine flow shop which reflects the situations of the manufacturing processes in the tire industry. The schedule is generated via simulation using heuristic rules to get satisfaction on such constraints as due dates, demands, work-in-process, process capacity, set-up times and scheduling speed. This system, constructed with relational DB, SQL and C language, consumes less than 10 minutes of PC simulation to handle real size problems.

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Optimum Chilling Terms for Germination of the Dehisced Ginseng(Panax ginseng C. A. Meyer) Seed (개갑 인삼종자의 발아 적정 저온감응기간)

  • 권우생;이장호;이명구
    • Journal of Ginseng Research
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    • v.25 no.4
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    • pp.167-170
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    • 2001
  • Experiments were conducted to study the optimum chilling period for breaking physiological dormancy of dehisced ginseng(Panax ginseng C. A. Meyer) seed. Embryo of ginseng seed is too small to be noticed with naked eyed on harvesting time. Embryo grew to half size of endosperm after seeds were stratified for 3 months. It takes 6 months for this embryo to reach the size enough for germination. And it grew faster indoors than outdoors. Dehisced ginseng seed with full-size embryo did not germinate at room temperature and required chilling treatment for 75days in outdoors and 90 days in cold chamber. While seed receiving sufficient chilling treatment were left to be in room temperature, the chilling effect decreased remarkably.

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Synthesis of TiO2 nanoparticles induced by electron beam irradiation and their electrochemical performance as anode materials for Li-ion batteries

  • Ahn, Ja-Hwa;Eom, Ji-Yong;Kim, Jong-Huy;Kim, Hye Won;Lee, Byung Cheol;Kim, Sung-Soo
    • Journal of Electrochemical Science and Technology
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    • v.6 no.3
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    • pp.75-80
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    • 2015
  • We introduce a new synthesis method to prepare small TiO2 nanoparticles with a narrow particle size distribution, which is achieved by electron beam (E-beam) irradiation. The effects of E-beam irradiation on the synthesis of TiO2 nanoparticles and the electrochemical performance of TiO2 nanoparticles as alternative anode materials for Li-ion batteries are investigated. The TiO2 nanoparticles induced by E-beam irradiation present better cycling performance and rate capability than the TiO2 nanoparticles synthesized by normal hydrolysis reaction. The better electrochemical performance is attributed to small particle size and narrow particle size distribution, resulting in the large surface area that provides innumerable reaction sites and short diffusion length for Li+ through TiO2 nanoparticles.

Morphological Features of Pollen Grains in Portulaca

  • Kim, InSun
    • Applied Microscopy
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    • v.43 no.2
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    • pp.75-80
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    • 2013
  • The morphological features of pollen grains collected from the broad-leaved and cylindrical-leaved Portulaca species of the Hawaiian Islands were investigated. The variation in size and surface pattern were examined using scanning electron microscopy and statistical analysis. Pollens of the Portulaca were apolar grains of monads exhibiting apertures, colpi, and relatively thin echini. Of particular interest was the differing size of pollen grains among the species studied. Pollens of the broad-leaved Portulaca were considerable in size with a length of about $73{\sim}86{\mu}m$, while the cylindrical-leaved Portulaca tended to have smaller pollen grains ranging from 50~65 in diameter. The smallest pollens were found in cultivar 2 having an average of $43{\mu}m$. The pollen was intectate, and the exine surface appeared granulous, having sculptured elements of spinules and puncta. Two types of puncta were discerned; one forming an operculum, and the other, a simple perforation. Numerous spinules and small puncta were found throughout the cylindrical-leaved Portulaca. In the present study, morphological features of pollen grains from ten Hawaiian Portulaca species, including endemic and unknown taxa, revealed the aforementioned pattern of variation. This paper aim to provide morphological information that could be of phylogenetic value within the Hawaiian Portulaca.

The Effect of Space Size and Dialogue Topic on Metaverse UX (대화 공간의 크기와 대화 주제가 메타버스 경험에 주는 영향)

  • Song, Stephen W.;Chung, Hanna;Chung, Donghun
    • Journal of Korea Game Society
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    • v.22 no.1
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    • pp.65-76
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    • 2022
  • What difference does the metaverse experience have from the real world? This study investigated the effect of space size and dialogue topic on metaverse user experience. The results from a 3(space size: reality vs. metaverse in an open room vs. metaverse in a closed room) x 2(dialogue topic: positive vs. negative) mixed factorial design experiment (N = 75) revealed statistically significant effects of space on responsiveness, and dialogue topic on closeness. This result implies that designing metaverse for non-immersive devices should include careful considerations regarding the characteristics of the user's real space.

Analysis of Broken Rice Separation Efficiency of a Laboratory Indented Cylinder Separator

  • Kim, Myoung Ho;Park, Seung Je
    • Journal of Biosystems Engineering
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    • v.38 no.2
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    • pp.95-102
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    • 2013
  • Purpose: Using a laboratory indented cylinder separator, broken rice separation experiments were conducted and the characteristics of the separation process were studied to provide information for developing a prototype indented cylinder broken rice separator. Methods: Rice (Ilmi variety) milled in a local RPC was used for the experiment. Rice kernels were classified into four groups according to their length l; whole kernels (I > 3.75 mm), semi-whole kernels (2.5 < I < 3.75 mm), broken kernels (1.75 < I < 2.5 mm), and foreign matters (I < 1.75 mm). A laboratory grain cleaner, Labofix '90 (Schmidt AG, Germany) was used for the experiments. Experiments were designed as a $4{\times}4$ factorial arrangement in randomized blocks with three replications. Cylinder rotational speeds (17, 34, 51, 68 rpm) and trough angles (15, 37.5, 60, $82.5^{\circ}$) were the two factors and feed rates (25, 50 kg/h), indent shapes (Us, $S_1$ type), and indent sizes (2.5, 3.75 mm) were treated as the blocks. Two 125 g samples and one 125 g sample were taken at the cylinder outlet and from the trough, respectively. The whole, semi-whole, and broken kernel weight ratio of the samples and feed was determined by a rice sizing device. From these weight ratios, purities, degrees of extraction and coefficient of separation efficiency were calculated. Results: Trough angle, cylinder speed, and their interaction on the coefficient of separation efficiency were statistically significant. Cylinder speed of 17, 34, and 51 rpm made the most effective separation when the trough angle was $15^{\circ}$ or $37.5^{\circ}$, $60^{\circ}$, and $82.5^{\circ}$, respectively. Maximum values of coefficient of separation efficiency were in the range of 60 to 70% except when the indent size was 2.5 mm and were recorded for the combinations of low cylinder speed (17 rpm) with medium trough angle ($37.5^{\circ}$ or $60^{\circ}$). Indent shape did not appear to make any noticeable difference in separation efficiency. Conclusions: Due to the interaction effect, the trough angle needs to be increased appropriately when an increase in cylinder speed is made if a rapid drop of effectiveness of separation should be avoided. In commercial applications, $S_1$ type indents are preferred because of their better manufacturability and easier maintenance. For successful separation of broken kernels, the indent size should be set slightly bigger than the actual sizes of broken kernels: an indent size of 3.0 mm for separating broken kernels shorter than 2.5 mm.