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Fabrication of Visible-Light Sensitized ZnTe/ZnSe (Core/Shell) Type-II Quantum Dots

  • Kim, Misung;Bang, Jiwon
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.510-514
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    • 2018
  • Colloidal semiconductor quantum dots (QDs), because of the novel optical and electrical properties that stem from their three-dimensional confinement, have attracted great interest for their potential applications in such fields as bio-imaging, display, and opto-electronics. However, many semiconductors that can be exploited for QD applications contain toxic elements. Herein, we synthesized non-toxic ZnTe/ZnSe (core/shell) type-II QDs by pyrolysis method. Because of the unique type-II character of these QDs, their emission can range over an extended wavelength regime, showing photoluminescence (PL) from 450 nm to 580 nm. By optimizing the ZnSe shell growth condition, resulting ZnTe/ZnSe type-II QDs shows PL quantum yield up to ~ 25% with 35 nm PL bandwidth. Using a simple two step cation exchange reaction, we also fabricated ZnTe/ZnSe type-II QDs with absorption extended over the whole visible region. The visible-light sensitized heavy metal free ZnTe/ZnSe type-II QDs can be relevant for opto-electronic applications such as displays, light emitting diodes, and bio-imaging probes.

Luminescent Properties of BaSi2O5:Eu2+ Phosphor Film Fabricated by Spin-Coating of Ba-Eu Precursor on SiO2 Glass

  • Park, Je Hong;Kim, Jong Su;Kim, Jong Tae
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.45-49
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    • 2014
  • Well-crystallized $BaSi_2O_5:Eu^{2+}$ phosphor films were synthesized by heat treatment of spin-coated BaO:Eu on $SiO_2$ glass. We investigated luminescence-structure properties of these phosphor films as a function of heat-treatment temperature. From x-ray diffraction patterns, our $BaSi_2O_5:Eu^{2+}$ phosphor films revealed that (111)- and (204)-crystal planes of $BaSi_2O_5$ crystal were dominantly increased with an increase of heat-treatment temperature. Photoluminescence intensities of $BaSi_2O_5:Eu^{2+}$ phosphor films were increased with amount of these crystal planes. It can be explained that $Eu^{2+}$ ions were stably occupied at specific crystal orientation of $BaSi_2O_5$ crystal, enhancing the luminescent intensities of $BaSi_2O_5:Eu^{2+}$ phosphor films. In addition, our $BaSi_2O_5:Eu^{2+}$ phosphor films had transmittance of 70% at 510 nm,.due to the dense morphology and specific crystallinity of $BaSi_2O_5:Eu^{2+}$ phosphor films.

Risk Factors for Surgical Site Infections According to Electronic Medical Records Data (전자의무기록(EMR) 자료를 활용한 수술부위감염 관련요인)

  • Kim, Young Hee;Yom, Young-Hee
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.21 no.2
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    • pp.151-161
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    • 2014
  • Purpose: The purpose of this study was to identify the risk factors that influence surgical site infections after surgery. Methods: This study was a retrospective research utilizing Electronic Medical Records. Data collection targeted 4,510 adult patients who had 8 different kinds of surgery (gastric surgery, colon surgery, laparoscopic cholecystectomy, hip & knee replacement, hysterectomy, cesarean section, cardiac surgery) in 4 medical care departments, at one general hospital between January 2006 and December 2011. Multivariate logistic regression analyses were used to identify the risk factors affecting surgical site infections after surgery. Results: Risk factors for increased surgical site infection following surgery were confirmed to be age (OR=1.59, p<.001), BMI (Body Mass Index)(OR=1.25, p=.034), year of operation (OR=2.45, p<.001), length of operation (OR=3.06, p<.001), ASA (American Society of Anesthesiology) score (OR=1.36, p=.025), classification of antibiotic used (OR=2.77, p<.001), duration of the prophylactic antibiotics use (OR=1.85, p<.001), and interaction between classification of antibiotic used and duration of the prophylactic antibiotics use (OR=1.90, p=.016). Conclusions: Results suggest that risk factors affecting surgical site infections should be monitored before surgery. The results of this study should contribute to establishing effective infection management measures and implementing surveillance systems for patients who have actual risk factors.

An Evaluation of Blast Resistance of Partially Reinforced CFT Columns using Computational Analysis (전산해석을 이용한 부분 보강된 CFT 기둥의 폭발저항성능 평가)

  • Kim, Han-Soo;Wee, Hae-Hwan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.28 no.5
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    • pp.503-510
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    • 2015
  • In this paper, the blast resisting performance of partially reinforced CFT columns was compared with the normal CFT columns to evaluate the effect of reinforcing with steel plates. Autodyn which is a specialized hydro-code for analysis of explosion and impact was used to simulate the structural behavior of the CFT columns under the blast loadings. The interaction between concrete and surrounding steel plates was modeled with friction and join option to represent the realistic damage of columns. According to the analysis, the partially reinforced CFT column showed enhanced blast resisting performance than the normal CFT columns. Also the improvement of blast resisting performance was depended on the height of reinforcing steel plates.

Developing a Blockchain based Accounting and Tax Information in the 4th Industrial Revolution (4차 산업혁명시대에 맞는 회계 및 세무 정보의 블록체인 구축 방안)

  • Hong, Sunghyuck;Seo, Cho-Rong
    • Journal of the Korea Convergence Society
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    • v.9 no.3
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    • pp.45-51
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    • 2018
  • According to the report, the World Economic Forum predicted that by 2020, more than 5.3 million jobs will be lost. Among them are accountants and tax accountants as well. Accountancy is a professional practice, accounting for management consulting, accounting audit, and management consultancy, and tax accountant duties are a professional profession that carries out duties such as tax returns and tax laws. Therefore, this study proposes a method to build transparent and safe tax and accounting information by increasing the efficiency of tax and accounting work by building a block chaining accounting and tax information suitable for the fourth industrial revolution era.

Bayesian Algorithm for Indoor Semantic Location Determination (의미 공간에서의 실내 측위를 위한 베이지안 알고리즘)

  • Kim, Hee-Kyum;Tak, Sung-Woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.10a
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    • pp.507-510
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    • 2011
  • As the amount of the wireless mobile products like a 'Smart phone' used increases, the studies about the Location Based Service (LBS) is highly increasing. Outdoor location determination can use the GPS which is built-in in the wireless mobile products. However, it is not possible to use GPS inside the huge cruise bigger than a normal building, it is regarded to consider Indoor location determination which is appropriate at the inside environment. Wi-Fi (Wireless Fidelity) does not need an extra installation process because it is already installed here and there inside the building. In this respect, Wi-Fi has low price competitiveness compared to other wireless sensor products. In this paper, I will introduce 'Bayesian Algorithm' which can recognize useful space with Wi-Fi signal.

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Minimum Autoignition Temperature Behavior(MAITB) of the Flammable Binary Systems (가연성 이성분계의 최소자연발화온도 거동(MAITB))

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.70-75
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    • 2008
  • The values of the AIT(Autoignition temperature) for fire and explosion protection are normally the lowest reported. The minimum autoignition temperature behavior(MAITB) of flammable liquid mixtures is exhibited when the AIT of mixture is below the AIT of the individual components. The MAITB is an interesting experimental features, which can be significant from the perspective of industrial safety. In this study, the AITs of m-xylene+n-butyric acid and ethylbenzene+n-butanol systems were measured using ASTM E659-78 apparatus. The AITs of m-xylene, n-butyric acid, ethylbenzene and n-butanol which constituted two binary systems were $587^{\circ}C$, $510^{\circ}C$, $475^{\circ}C$ and $340^{\circ}C$ respectively. The m-xylene+n-butyric acid system is exhibited MAITB at 0.3 mole fraction of m-xylene, and its minimum autoignition temperature was $460^{\circ}C$.

THE DEVELOPMENT OF KACD(KOREAN ACADEMY OF CONSERVATIVE DENTISTRY) ONLINE ARTICLE CONTRIBUTION MANAGEMENT SYSTEM BASED ON KISTI-ACOMS (KISTI-ACOMS를 기반으로 한 대한치과보존학회 온라인논문투고관리시스템 개발)

  • Park, Jae-Won;Kang, Mu-Yeong
    • Restorative Dentistry and Endodontics
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    • v.28 no.6
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    • pp.504-510
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    • 2003
  • Societies are important sources of new information for users. However. most of these societies still rely on traditional. or rather ancient methods for gathering and servicing the information. Furthermore. most of the societies are trying to electrify processes such as managing members and paper submission as well as the process managing the information for service but are limited due to financial and technical reasons. Therefore. KISTI(Korea Institute of Science and Technology Information) has developed the $\mathbb{\ulcorner}$ KISTI-ACOMS(KISTI-Article COntribution Management System)$\mathbb{\lrcorner}$ as part of the national project for automating the process of processing academic information by societies. in order to convert journals published by academic societies in Korea into an electronic form and make them accessible on the Internet. This system has been developed in the year 2001 and has since been distributed to societies free of charge. The number of societies requesting the service has risen recently. which prompted us to take more recommendations of the societies that adopt this system into account in expanding and standardizing the area of service being provided by the system.

Preferred Orientation and SAW Characteristics of AIN Films Deposited by Reactive RF Magnetron Sputtering (반응성 RF 마그네트론 스퍼터링 법으로 증착된 AIN박막의 우선 배향성 및 표면 탄성파 특성에 관한 연구)

  • Seo, Ju-Won;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.7 no.6
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    • pp.510-516
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    • 1997
  • 반응성RF 마그네트론 스퍼터링 법으로 상온에서 c-축으로 우선 배향된 AIN 박막을 여러 기판 위에 증착하였다. SiO$_{2}$/Si, Si$_{3}$N $_{4}$Si, Si(100), Si(111)그리고 $\alpha$-AI$_{2}$O$_{3}$(0001) 기판에서 AIN(0002)로킹커브 피크의 표준편차는 각각 2.6˚, 3.1˚2.6˚, 2.5˚ 그리고 2.1˚ 의 값을 나타내었다. $\alpha$-AI$_{2}$O$_{3}$(0001) 기판에 증착된 AIN박막은 epitaxial 성장을 나타내었다. Si기판에 증착된 AIN박막에서 측정된 비저항과 1MHz 주파수에서 측정된 유전상수의 값은 각각 $10^{11}$Ωcm와 9.5였다. IDT/AIN/$\alpha$-AI$_{2}$O$_{3}$(0001)구저를 갖는 지연선 소자의 표면 탄성과 특성을 측정하였다. 상 속도, 전기기계 결합계수 그리고 전파손실은 H/λ가 0.17-0.5 범위에서 각각 5448-5640m/s, 0.13-0.17% 그리고 0.41-0.64dB/λ의 값을 나타내었다.다.

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Immiscibility, nucleation and mechanical properties in the lithia-baria-silica system

  • Ertug, Burcu
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.394-400
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    • 2018
  • The current work investigates the effects of nucleation heat treatments, on the microstructure and mechanical properties of a novel silicate glass in $Li_2O-BaO-SiO_2$ system with 1 mol% $P_2O_5$ as nucleating agent. As-cast glass was exposed to nucleation heat treatments at $490-550^{\circ}C$ for 1-3 h. The microstructural examination was performed by SEM/EDS. The highest Vickers microhardness was determined to be 650 Hv for the sample heat treated at $550^{\circ}C$ for 1 h. The increase in the nucleation time also affected Vickers microhardness and the highest one was determined to be 600 Hv after nucleation for 3 h. The fracture toughness, $K_{IC}$ reached $2.51MPa.m^{1/2}$ after nucleation at $550^{\circ}C$ for 1 h. The nucleation temperatures had a more pronounced effect on the fracture toughnesses in comparison to nucleation times. The indentation toughness data was used to determine Weibull parameters from Ln ln [1/(1-P)]-$lnK_{IC}$ plots. Weibull modulus, m of the samples nucleated at 500, 510, 530, $550^{\circ}C$ for 1h. and $540^{\circ}C$ for 2 h. were determined similarly to be 3.8, 3.5, 4.7 and 3.9, respectively. The rest of the samples indicated higher Weibull moduli, which may be attributed to the formations of microcracks due to the mismatch in between newly formed crystals and remaining glassy matrix.