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Spectroscopy of acetylene (13C2H2) using a tunable erbium-doped fiber ring laser (파장가변 광섬유 링 레이저를 이용한 아세틸렌(13C2H2) 분광)

  • 유한영;오정미;이동한;문한섭;이원규;박갑동;서호성
    • Korean Journal of Optics and Photonics
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    • v.14 no.6
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    • pp.674-679
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    • 2003
  • We fabricated erbium-doped fiber ring laser with a new structure that can operate in C- & L-band wavelength region. The wave-length of the laser can be tuned continuously over 102 nm between 1510.4-1612.6 nm by insertion of the fiber Fabry-Perot tunable filter (FFP-TF) in the ring cavity. By use of the wavelength tunable characteristics of our fiber laser, we measured absorption spectra of more than fifty transition lines of the acetylene ($^{13}$ C$_2$H$_2$) molecule with high signal to noise ratio (SNR).

Efficient excitation and amplification of the surface plasmons

  • Iqbal, Tahir
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1381-1387
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    • 2018
  • One dimensional (1D) grating has been fabricated (using focused ion beam) on 50 nm gold (Au) film deposited on higher refractive index Gallium phosphate (GaP) substrate. The sub-wavelength periodic metal nano structuring enable to couple photon to couple with the surface plasmons (SPs) excited by them. These grating devices provide the efficient control on the SPs which propagate on the interface of noble metal and dielectric whose frequency is dependent on the bulk electron plasma frequency of the metal. For a fixed periodicity (${\Lambda}=700 nm$) and slit width (w = 100 nm) in the grating device, the efficiency of SPP excitation is about 40% compared to the transmission in the near-field. Efficient coupling of SPs with photon in dielectric provide field localisation on sub-wavelength scale which is needed in Heat Assisted Magnetic recording (HAMR) systems. The GaP is also used to emulate Vertical Cavity Surface emitting laser (VCSEL) in order to provide cheaper alternative of light source being used in HAMR technology. In order to understand the underlying physics, far-and near-field results has been compared with the modelling results which are obtained using COMSOL RF module. Apart from this, grating devices of smaller periodicity (${\Lambda}=280nm$) and slit width (w = 22 nm) has been fabricated on GaP substrate which is photoluminescence material to observe amplified spontaneous emission of the SPs at wavelength of 805 nm when the grating device was excited with 532 nm laser light. This observation is unique and can have direct application in light emitting diodes (LEDs).

Diffusion Length Measurement of the Triplet Exciton in PHOLEDs by using Double Quantum Well Structure

  • Park, Won-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.225-225
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    • 2016
  • PHOLED devices which have the structure of ITO/HAT-CN(5nm)/NPB(50nm)/EML(47nm)/TPBi(10nm)/Alq3(20nm)/LiF(0.8nm)/Al(100nm) are fabricated to investigate the diffusion length of the triplet exciton by using double-quantum-well(DQE) EML structure. To fabricate DQW structures, Ir(ppy)3(2% wt) and Ir(btp)2(8% wt) are used as green and red emission zones, respectively. In DQW structured EML, as shown in Fig. 1, 1nm thick layers of green and red emission zones are located middle of the EML, and the distance between these wells(x) is changed from 0nm to 10nm. As shown in Fig. 2, the emission spectra from DQW PHOLED devices are changed with different x. The intensity of the green emission(520nm) is decreased when x is decreased, and it goes to near zero when x=0nm. This behavior can be identified as the diffusion of the triplet excitons from Ir(ppy)3 to Ir(btp)2 by the Dexter energy transfer(DET). From the external quantum efficiency(EQE) of the red emission, as shown in Fig. 3, the diffusion length of the triplet excitons can be determined by the equation of DET rate, R=A Exp(-2RDA/L), where RDA is donor-acceptor distance and L is the sum of the van der Wals radii. As a result, the measured data of the red EQEs with different x are identified to theoretical result from the equation of DET rate(Fig. 4). From this results, we could confirm that the diffusion length of the triplet excitons can be determined by using DQW structure and this method is very useful to investigate the behavior of the excitons in PHOLEDs.

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Emission Properties of White Organic Light-Emitting Diodes with Blue Emitting Layer (청색 발광층에 의한 백색 OLED의 발광 특성)

  • Chun, Hyun-Dong;Na, Hyunseok;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.451-456
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    • 2013
  • To study emission properties of white phosphorescent organic light emitting devices (PHOLEDs), we fabricated white PHOLEDs of ITO(150 nm) / NPB(30 nm) / TcTa(10 nm) / mCP(7.5 nm) / light-emitting layer(25 nm) / UGH3(5 nm) / Bphen(50 nm) / LiF(0.5 nm) / Al(200 nm) structure. The total thickness of light-emitting layer with co-doping and blue-doping/co-doping using a host-dopant system was 25 nm and the dopant of blue and red was FIrpic and $Bt_2Ir$(acac) in UGH3 as host, respectively. The OLED characteristics were changed with position and thickness of blue doping layer and co-doping layer as light-emitting layer and the best performance seemed in structure of blue-doping(5 nm)/co-doping(20 nm) layer. The white PHOLEDs showed the maximum current density of $34.5mA/cm^2$, maximum brightness of $5,731cd/m^2$, maximum current efficiency of 34.8 cd/A, maximum power efficiency of 21.6 lm/W, maximum quantum efficiency of 15.6%, and a Commission International de L'Eclairage (CIE) coordinate of (0.367, 0.436) at $1,000cd/m^2$.

The optical properties of GZO and ZnO thin films deposited by RF magnetron sputtering (RF magnetron sputtering 법으로 증착된 GZO와 ZnO 박막의 광학적 특성)

  • HwangBoe, S.J.;Jeon, H.H.;Kim, G.C.;Lee, J.S.;Kim, D.H.;Choi, W.B.;Jeon, M.H.
    • Journal of the Korean Vacuum Society
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    • v.16 no.6
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    • pp.453-457
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    • 2007
  • Zinc oxide (ZnO) and Ga doped zinc oxide (GZO) with different thickness in range of 10nm to 100nm are prepared on glass substrate by RF magnetron sputtering at room temperature. The structural and optical properties of the thin films is evaluated. The structural properties of ZnO and GZO are investigated by Tunneling Electron Microscopy (TEM) and scanning electron microscopy (SEM). Optical properties are also investigated by UV-VIS-NIR spectrophotometer (200$\sim$1400nm). The much larger grain size of ZnO compared to GZO decreased the light scattering at the grain boundary and improved the transmittance. The transmittance of ZnO is higher than that of GZO through all of the ranges of wavelengths. In case of over 50nm, we found that the transmittance of ZnO is 20% higher than that of GZO.

Design and Growth of InAs Multi-Quantum Dots and InGaAs Multi-Quantum Wells for Tandem Solar Cell (텐덤형 태양전지를 위한 InAs 다중 양자점과 InGaAs 다중 양자우물에 관한 연구)

  • Cho, Joong-Seok;Kim, Sang-Hyo;HwangBoe, Sue-Jeong;Janng, Jae-Ho;Choi, Hyon-Kwang;Jeon, Min-Hyon
    • Journal of the Korean Vacuum Society
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    • v.18 no.5
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    • pp.352-357
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    • 2009
  • The InAs multi-quantum dots (MQDs) solar cell and InGaAs multi-quantum wells (MQWs) solar cell to cover 1.1 eV and 1.3 eV were designed by 1D poisson, respectively. The MQDs and MQWs of 5, 10, 15 layers were grown by molecular beam epitaxy. The photo luminescence results showed that the 5 period stacked MQDs have the highest intensity at around 1.1 eV with 57.6 meV full width at half maximum (FWHM). Also we can observe 10 period stacked MQWs peak position which has highest intensity at 1.31 eV with 12.37 meV FWHM. The density and size of QDs were observed by reflection high energy electron diffraction pattern and atomic force microscope. Futhermore, AlGaAs/GaAs sandwiched tunnel junctions were modified according to the width of GaAs layer on p-type GaAs substrates. The structures with GaAs width of 30 nm and 50 nm have backward diode characteristics. In contrast, tunnel diode characteristics were observed in the 20 nm of that of sample.

Beyond-CMOS: Impact of Side-Recess Spacing on the Logic Performance of 50 nm $In_{0.7}Ga_{0.3}As$ HEMTs

  • Kim, Dae-Hyun;del Alamo, Jesus A.;Lee, Jae-Hak;Seo, Kwang-Seok
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.146-153
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    • 2006
  • We have been investigating InGaAs HEMTs as a future high-speed and low-power logic technology for beyond CMOS applications. In this work, we have experimentally studied the role of the side-recess spacing $(L_{side})$ on the logic performance of 50 nm $In_{0.7}Ga_{0.3}As$ As HEMTs. We have found that $L_{side}$ has a large influence on the electrostatic integrity (or short channel effects), gate leakage current, gate-drain capacitance, and source and drain resistance of the device. For our device design, an optimum value of $L_{side}$ of 150 nm is found. 50 nm $In_{0.7}Ga_{0.3}As$ HEMTs with this value of $L_{side}$ exhibit $I_{ON}/I_{OFF}$ ratios in excess of $10^4$, subthreshold slopes smaller than 90 mV/dec, and logic gate delays of about 1.3 ps at a $V_{CC}$ of 0.5 V. In spite of the fact that these devices are not optimized for logic, these values are comparable to state-of-the-art MOSFETs with similar gate lengths. Our work confirms that in the landscape of alternatives for beyond CMOS technologies, InAs-rich InGaAs FETs hold considerable promise.

Studies on Electrochemical Behavior of Some Light Lanthanide Ions in Nonaqueous Solution, Flow Injection Determination and Photochemical Characterization of Heavy Metal Ion Chelate Eight Coordinated Complexes. (Part 2) (비수용액에서 가벼운 란탄족 이온의 전기화학적 거동, 흐름 주입법에 의한 정량 및 중금속 이온의 킬레이트형 8-배위 착물의 광화학적 특성 연구 (제 2 보) : 계면활성제 존재하에서 Chromeazurol S를 사용하여 몇 가지 란탄이온의 흐름주입법에 의한 정량)

  • Gang, Sam U;Jang, Ju Hwan;Kim, Il Gwang;Han, Hong Seok;Jo, Gwang Hui
    • Journal of the Korean Chemical Society
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    • v.38 no.1
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    • pp.50-54
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    • 1994
  • Spectrophotometric determination of some light lanthanide ions by flow injection method is described. Chromeazurol S forms water soluble complex with lanthanide ions in the presence of DTAB. The absorption maximum of the complexes are from 650 nm to 655 nm and the molar absorptivities were ca. $1.8{\times}10^5\;L mol^{-1}cm^{-1}$ on Tris buffer (pH 10.5). The calibration curves for Nd(III), Eu(III) and Sm(III) obtained by FIA are over the range of 0.1 to 0.6 ppm and the correlation coefficient were ca. 0.9993. The detection limits (S/N) were from 10 ppb for Nd(III) and Eu(III) to 20 ppb for Sm(III). The relative standard deviations was ${\pm}$.2% for 0.4 ppm sample. The samples throughput was ca. $50\;cm^{-1}$.

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Preparation of Nano-Sized Tin Oxide Powder by Spray Pyrolysis Process (분무열분해(噴霧熱分解) 공정(工程)에 의한 주석(朱錫) 산화물(酸化物) 나노 분말(粉末) 제조(製造))

  • Yu, Jae-Keun;Cha, Kwang-Yong;Kim, Myung-Choun;Han, Joung-Su;Jang, Jae-Bum;Lee, Yong-Hwa;Kim, Dong-Hee
    • Resources Recycling
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    • v.17 no.6
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    • pp.79-88
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    • 2008
  • This study is the previous stage for the mass production technology development of the nano-sized tin oxide powder by the recycling of the wasted tin metal, and nano-sized tin oxide powder with the average particle size below 50 nm is prepared from the tin chloride solution by the spray pyrolysis process. As the reaction temperature increases from 800 to 850, the average particle size of the generated powder increases from 20 to 30 nm. As the reaction temperature increases to 900, the droplet type is composed of the particles with the average size of the 30 nm. while the average size of the independent particles increases up to $80{\sim}100$ nm and the surface microstructure becomes more solid. Until $900^{\circ}C$, as the reaction temperature increases, the XRD peak intensity increases, while the specific surface area decreases. When the reaction temperature increases to 950, most of the powder appears with the independent type and the average particle size decrease down to 70 nm. The XRD peak intensity greatly decreases and the specific surface area increases almost twice.

Floating Gate Organic Memory Device with Plasma Polymerized Styrene Thin Film as the Memory Layer (플라즈마 중합된 Styrene 박막을 터널링층으로 활용한 부동게이트형 유기메모리 소자)

  • Kim, Heesung;Lee, Boongjoo;Lee, Sunwoo;Shin, Paikkyun
    • Journal of the Korean Vacuum Society
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    • v.22 no.3
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    • pp.131-137
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    • 2013
  • The thin insulator films for organic memory device were made by the plasma polymerization method using the styrene monomer which was not the wet process but the dry process. For the formation of stable plasma, we make an effort for controlling the monomer with bubbler and circulator system. The thickness of plasma polymerized styrene insulator layer was 430 nm, the thickness of the Au memory layer was 7 nm thickness of plasma polymerized styrene tunneling layer was 30, 60 nm, the thickness of pentacene active layer was 40 nm, the thickness of source and drain electrodes were 50 nm. The I-V characteristics of fabricated memory device got the hysteresis voltage of 45 V at 40/-40 V double sweep measuring conditions. If it compared with the results of previous paper which was the organic memory with the plasma polymerized MMA insulation thin film, this result was greater than 18 V, the improving ratio is 60%. From the paper, styrene indicated a good charge trapping characteristics better than MMA. In the future, we expect to make the organic memory device with plasma polymerized styrene as the memory thin film.