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High-Performance Optical Gating in Junction Device based on Vanadium Dioxide Thin Film Grown by Sol-Gel Method

  • Lee, Yong-Wook;Kim, Eung-Soo;Shin, Bo-Sung;Lee, Sang-Mae
    • Journal of Electrical Engineering and Technology
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    • v.7 no.5
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    • pp.784-788
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    • 2012
  • In this paper, a high-performance optical gating in a junction device based on a vanadium dioxide dioxide ($VO_2$) thin film grown by a sol-gel method was experimentally demonstrated by directly illuminating the $VO_2$ film of the device with an infrared light at ~1554.6 nm. The threshold voltage of the fabricated device could be tuned by ~76.8 % at an illumination power of ~39.8 mW resulting in a tuning efficiency of ~1.930 %/mW, which was ~4.9 times as large as that obtained in the previous device fabricated using the $VO_2$ thin film deposited by a pulsed laser deposition method. The rising and falling times of the optical gating operation were measured as ~50 ms and ~200 ms, respectively, which were ~20 times as rapid as those obtained in the previous device.

Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells (연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구)

  • Shin, Seungho;Kim, Ah-Reum;Jung, Hye-Mi;Um, Sukkee
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.10
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    • pp.955-965
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    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

The Effects of Partially Premixed Pilot Injection Timing on the Combustion and Emission Characteristics in a Common Rail Diesel Engine (커먼레일식 디젤기관의 부분 예혼합 분사시기가 연소 및 배기특성에 미치는 영향)

  • Yoon, Sam-Ki;Choi, Nag-Jung
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.18-24
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    • 2013
  • An experimental study was performed to investigate the characteristics of combustion pressure and exhaust emissions when the pilot injection timing and EGR rate were changed in a CRDI 4-cylinder diesel engine. The pilot injection timing and EGR rate have a significant impact on the combustion and emission characteristics of diesel engine. In this study, the pilot injection timing and EGR rate variation were conducted to 2000rpm of engine speed with torque 50Nm. Combustion pressure and heat release rate were decreased under high EGR rate conditions but increased under the pilot injection timing $20^{\circ}$(BTDC). IMEP and the maximum pressure in cylinder(Pmax) were decreased under the same injection timing with the increase of EGR rate. The NOx emission was decreased with increasing the EGR rate. On the other hand, in the same injection timing conditions, CO, HC, $CO_2$ emissions were increased with increasing the EGR rate.

Ga doped ZnO Thin Films for Gas Sensor Application (Ga이 첨가된 ZnO 박막의 가스센서로의 응용 연구)

  • Hwang, Hyun-Suk;Yeo, Dong-Hun;Kim, Jong-Hee;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.499-502
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    • 2008
  • In this work, Ga-doped ZnO (GZO) thin films for gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin film with thickness of 50 nm is analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The film shows good adhesion to the substrate. The GZO gas sensors are tested by gas measurement system and show fast response and recovery characteristics to $NO_x$ gas that is 27.2 and 27.9 sec, recpectively.

The AC Insulation Breakdown Properties of Epoxy/Multi-Alumina Composites for Adding Surface Modified Nano Alumina (표면처리된 나노알루미나가 첨가된 에폭시/멀티-알루미나 콤포지트의 교류절연파괴 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1511-1517
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    • 2016
  • The aim of this study is to improve of properties for electrical AC insulation breakdown strength using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40,50,60wt%)+surface modified nano alumina(1_phr) composites. 14 kinds specimen were prepared with containing epoxy resins, epoxy micro composites and epoxy nano-micro alumina mixture composites. Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The electrical AC insulation breakdown strength was evaluated by sphere to sphere electrode system and raising velocity 1kV/s. The AC breakdown strength decreased insulation properties of multi-composites according to increasing micro alumina and GDE addition contents.

Manufacturing and Characterization of $CuInS_2$ Nanopowder for Compound Thin Film Solar Cell (화합물 박막 태양전지 적용을 위한 $CuInS_2$ 나노분말의 제조 및 특성 평가)

  • Lee, Dae-Girl;Lee, Nam-Hee;Oh, Hyo-Jin;Yun, Yeong-Ung;Hwang, Jong-Sun;Kim, Sun-Jae
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.2113_2114
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    • 2009
  • Chalcopyrite based sollar cells have received much attention because of their tunable electronic and optical properties. As a typical ternary chalcopyrite material, $CuInS_2$ has been considered as one of the most popular and promising candidates as absorber materials for photovoltaic applications because of its high absorption coefficient and environmental consideration. In this study, $CuInS_2$ powders have been synthesized using polyol process of a mixture of copper nitrate, indium nitrate, and thiourea with various stoichiometric molar ratios in ethylene glycol at $196^{\circ}C$. As boiling time goes by, the color of metal ion mixed solutions were changed transparent green to dark green and finally turned to black by reduction of OH- radicals. The prepared powders were fully characterized using SEM, XRD. The particle shape of black colored powders showed sphere with about 50 nm in particle size compared to those with dark green colored powders showed irregular shape with about $1{\mu}m$ in particle size. The XRD results showed highly crystallized $CuInS_2$.

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Formation of Silicon Particles Using $SiH_4$ pyrolysis at atmospheric pressure (상압에서 열분해법을 이용한 실리콘 입자 제조)

  • Woo, Dae-Kwang;Nam, Kyung-Tag;Kim, Young-Gil;Kim, Kwang-Su;Kang, Yun-Ho;Kim, Tae-Sung
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.126-129
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    • 2007
  • The particle formation using pyrolysis has many advantages over other particle manufacturing techniques. The particles by pyrolysis have relatively uniform size and chemical composition. Also, we can easily produce high purity particles. Thus, we studied the formation of silicon particles by pyrolysis of 50% $SiH_4$ gas diluted in Ar gas. A pyrolysis furnace was used for the thermal decomposition of $SiH_4$ gas at $800^{\circ}C$ and atmospheric pressure. The aerosol flow from furnace is separated into two ways. The one is to the Scanning Mobility Particle Sizer (SMPS) for particle size distribution measurement and the other is to the particle deposition system. The produced silicon particles are deposited on the wafer in the deposition chamber. SEM measurement was used to compare the particle size distribution results from the SMPS. Depending on the experimental conditions, particles of high concentration in the $30\sim80$ nm size range were generated.

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Quantitative Analysis of Chrysin and Pinocembrin in Korean Propolis (국산 프로폴리스 내 Chrysin과 Pinocembrin의 정량분석)

  • Kim, Se Gun;Hong, In Pyo;Woo, Soon Ok;Jang, Hye Ri;Han, Sang Mi
    • Korean Journal of Pharmacognosy
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    • v.48 no.1
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    • pp.88-92
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    • 2017
  • In the present study, we carried out quantitative analysis of chrysin and pinocembrin in Korean propolis by ultra performance liquid chromatography (UPLC) equipped with diode array detector. The separation was done using BEH C18 ($2.1{\times}50mm$, $1.7{\mu}m$) column with a mobile phase consisting of MeCN and 0.1% $H_3PO_4$ at 280 nm. The chromatographic method was validated for specificity, limit of detection, limit of quantification, linearity, precision, and accuracy. A quantitative analysis exhibited that the contents of the two compounds in Korean propolis collected from 8 inland areas except Jeju-do ranged from 3.1-46.0 mg/g. These results will be valuable as basic data for standardization of Korean propolis.

Acid Gas Removal Characteristics for Syngas using Fe Oxidization Process (철 산화법을 이용한 합성가스내 산성가스 제거 특성)

  • Lee, Seung-Jong;Hwang, Sang-Yeon;Yoo, Young-Don;Yun, Yong-Seung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.804-807
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    • 2007
  • The acid gas removal (AGR) system was designed and installed to remove $H_2S$ in coal syngas in the pilot-scale coal gasification system for producing chemicals like Dimethyl Ether(DME). The syngas from the coal gasification at the rate of $100{\sim120$ $Nm^3$/hr included pollutants such as fly ash. $H_2S$, COS, $NH_3$, etc. The designed temperature and pressure of the AGR system are below 50oC and 8 kg/$cm^2$. Fe-chelate was used as an absorbent. $H_2S$ was stably removed below 0.5 ppm in the AGR system when the concentration of $H_2S$ was $150{\sim}450$ ppm. The pH of Fe-chelate solution was also stably maintained between $8{\sim}9$. FeMgO absorbent was also tested to remove $H_2S$ in the lab-scale AGR system and $H_2S$ was also removed below 0.5 ppm in the initial operation.

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Control the Length of Carbon Nanotube Array by Using Oxygen Plasma Etching Process (산소플라즈마 에칭공정을 응용한 탄소나노튜브 Array 길이 제어 연구)

  • Song, Yoo-Jin;Kang, Seong-Jun
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.488-493
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    • 2009
  • We developed a simple method to control the length of carbon nanotube array by using oxygen plasma etching. In this way, we could obtain a carbon nanotube with a uniform length (20, 30, 50, $70\;{\mu}m$), that was parallel to the substrate. Moreover, our growing method of carbon nanotube array gives a uniform diameter ~3.5nm, which is consistent with our previous results. Using the same etching method, we demonstrated the carbon nanotube radio frequency identification (RFID) antenna. The results could be useful for carbon nanotube applications such as flexible and transparent conductive films.