• Title/Summary/Keyword: 4M method

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Separation and Recovery for the Analysis of Radioiodine in RI Wastes (RI 폐기물 내 방사성요오드 분석을 위한 분리 및 회수)

  • Kang, Sang-Hoon;Han, Sun-Ho;Lee, Heung-N.;Jee, Kwang-Yong;Lee, In-Koo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.4
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    • pp.267-272
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    • 2007
  • Various kinds of RI wastes are discharged from licensed organizations of radioisotopes les such as hospitals and clinic organizations, educational organizations, research institutions, and public organizations. Radioiodines such as $^{125}I\;and\;^{131}I$ are radioisotopes mainly used in nuclear medicine and industry. A method for the determination of radioiodines in RI wastes has been applied to measure low level activity using acid decomposition method and HPGe gamma ray spectrometer. Prior to analysis of real samples, $^{131}I$ reference solution and 10 g of yellow tissue paper was added to flask in mantle and was heated in 100 mL of 0.4 N $K_2Cr_2O_7$ and 100 mL of 9 M $H_2SO_4$, and then distilled after adding 10 mL of 30% $H_2PO_3$ and 1 mL of 30% $H_2O_2$. The condensed iodine by circulator was extracted into $CCl_4$, then back-extracted into the aqueous phase with 10 mL of 5% $K_2SO_2$ solution. Finally, $^{131}I$ was measured at 364.48 keV using HPGe gamma ray spectrometer after precipitation and filtration. Chemical yield of three steps such as acid decomposition process, chemical separation process, and precipitation and filtration process was more han 94% respectively, MDA(Minimum Detectable Activity) of $^{131}I$ at this analytical condition was 0.6 Bq/g.

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Improved HPLC-UV method for determination of five synthetic dyes in Typha orientalis

  • Ko, Kyung Yuk;Choi, Eun Young;Jeong, Se Hee;Paek, Ock jin;Lee, Chan;Heo, Huijin;Oh, She-Wook;Lee, Chulhyun;Kang, Juhye;Cho, Sooyeul
    • Analytical Science and Technology
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    • v.34 no.4
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    • pp.160-171
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    • 2021
  • Synthetic azo dyes are used extensively in herbal medicines to render the medicines more visually attractive to consumers. This study developed and validated a rapid high-performance liquid chromatography (HPLC) method to determine whether synthetic colorants such as Tartrazine, Auramine O, Metanil yellow, Sunset yellow, and Orange II are used extensively in Typha orientalis. To increase the recovery of the synthetic dyes, this method employed containing 50 mM ammonium acetate in 70 % methanol at first extraction and 100 mM HCl in 70 % methanol at second extraction. Five synthetic pigments in Typha orientalis were separated by gradient elution with a mobile phase consisting of acetonitrile and 50 mM ammonium acetate in distilled water at ultra-violet (UV) detection 428 nm or 500 nm. Additionally, this study established the liquid chromatography tandem mass spectrometry (LC-MS/MS) method to confirm positive samples suspected by HPLC results. The HPLC-UV method had good linearity, indicating r2> 0.999. The recoveries of the samples spiked with three different concentration ranged from 73.8~91.5 %, and relative standard deviation values indicated 0.2~5.2 %. The established LC-MS/MS could successfully identify the synthetic pigments in herbal medicine samples. The study demonstrates that Typha orientalis adulterated by yellowish synthetic dyes can be successfully distinguished when using the HPLC-UV method.

A Numerical Study on Safety According to the Excavation Step for Large Cross Section Tunnel (대단면 터널굴착에 있어서 굴착순서에 따른 수치해석적 안정성 검토)

  • Jung, Hee-sun;Yoon, Ji-sun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.7 no.4
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    • pp.335-341
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    • 2005
  • In construction of a large cross section NATM tunnel, to keep the tunnel face stability by the ground itself bench cut method is commonly used. In order to necessity of partial face excavation method, we have to look for more enhanced method that can maintain better stress intensity. This paper presents a stress distribution of the Center Diaphragm Method from the partial face excavation methods, with the numerical analysis, and induced the optimal face distance, which is minimizing stress concentration and the optimal excavation step. Commerical 3 dimensional continuum analyzing FLAC-3D Ver. 2.1 program is used for the analysis. Analyses were performed to investigate ground behavior for tunnels with variable bench-length varying from 2m to 40m.

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Blasting Standardization works for NATM on the Seoul Subway Construction by Dr, Ginn Huh (서울 지하철공사 발파공법의 표준화)

  • Heo, Jin
    • Journal of the Korean Professional Engineers Association
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    • v.16 no.3
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    • pp.5-23
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    • 1983
  • On the Seoul Metropolitan Subway Construction of No. 3, 4 Line, the total length is 57 Km and it is now undergoing almost 55% progress. The working method is classified into Open Cut of 70% and the rest of 30% tunnelling method in the 48 job site. Above tunnelling method is execute by American Steel Support System and the rest of 10 job site carried out by New Austria Tunnelling Method. This paper describes Blasting Standardizations works on the above Tunnelling ' Open Cut Method under big slogan, first safety, second execution. As a superintendent, I strived standardization of works with Better powder, Better Drills ' Better Pattern. Geological structure of Seoul area is composed by Jurassic Granite and also the above rockgroup are over burden by Alluviums as a Unconformity. First of all, I carried out the standard amount of powder and burden through experimental standard blasting by each powder as following Blasting works in the subway construction is surrounding shop Building, under pass the city river and also under pass highest building basement floor. I made allowable Blasting Vibration Value by West-Germany Vornorm DIN 4150, Teil 3 and should measure each blasting works as fellows all of powder is used basically Low-Gravity and Low Velocity such as Slurry, Ammonium Nitrate ' Finex I, II. for Smooth Blasting Instead of Gelatin Dynamite. Electric Detonation Cap is used basically M/S Delay Cup instead of Electric delay ' Simultaneous cap. I applied following formula V=KW3/4 $D^{-2}$ V=Particle Velocity (Cm/sec) K=Ginh Huh's Value W=Delay Charge (Kg) D=Distance(m) In the Open Cut, within 1m distance from H-pile I made to use the Concrete breaker, as following V=7W/$^{0.5}$V/$^{-1.75}$ On the Concentrate Building area, I advise to use Light class drill ø36m Bit and advance 1.1m per round blasting the three boom jumbo drill over ø45mm used only suburb of city.e Light class drill ø36m Bit and advance 1.1m per round blasting the three boom jumbo drill over ø45mm used only suburb of city.

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A Novel Nicotinamide Adenine Dinucleotide Correction Method for Mitochondrial Ca2+ Measurement with FURA-2-FF in Single Permeabilized Ventricular Myocytes of Rat

  • Lee, Jeong Hoon;Ha, Jeong Mi;Leem, Chae Hun
    • The Korean Journal of Physiology and Pharmacology
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    • v.19 no.4
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    • pp.373-382
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    • 2015
  • Fura-2 analogs are ratiometric fluoroprobes that are widely used for the quantitative measurement of [$Ca^{2+}$]. However, the dye usage is intrinsically limited, as the dyes require ultraviolet (UV) excitation, which can also generate great interference, mainly from nicotinamide adenine dinucleotide (NADH) autofluorescence. Specifically, this limitation causes serious problems for the quantitative measurement of mitochondrial [$Ca^{2+}$], as no available ratiometric dyes are excited in the visible range. Thus, NADH interference cannot be avoided during quantitative measurement of [$Ca^{2+}$] because the majority of NADH is located in the mitochondria. The emission intensity ratio of two different excitation wavelengths must be constant when the fluorescent dye concentration is the same. In accordance with this principle, we developed a novel online method that corrected NADH and Fura-2-FF interference. We simultaneously measured multiple parameters, including NADH, [$Ca^{2+}$], and pH/mitochondrial membrane potential; Fura-2-FF for mitochondrial [$Ca^{2+}$] and TMRE for ${\Psi}_m$ or carboxy-SNARF-1 for pH were used. With this novel method, we found that the resting mitochondrial [$Ca^{2+}$] concentration was $1.03{\mu}M$. This $1{\mu}M$ cytosolic $Ca^{2+}$ could theoretically increase to more than 100 mM in mitochondria. However, the mitochondrial [$Ca^{2+}$] increase was limited to ${\sim}30{\mu}M$ in the presence of $1{\mu}M$ cytosolic $Ca^{2+}$. Our method solved the problem of NADH signal contamination during the use of Fura-2 analogs, and therefore the method may be useful when NADH interference is expected.

An Empirical Study on the Improvement of In Situ Soil Remediation Using Plasma Blasting, Pneumatic Fracturing and Vacuum Suction (플라즈마 블라스팅, 공압파쇄, 진공추출이 활용된 지중 토양정화공법의 정화 개선 효과에 대한 실증연구)

  • Jae-Yong Song;Geun-Chun Lee;Cha-Won Kang;Eun-Sup Kim;Hyun-Shic Jang;Bo-An Jang;Yu-Chul Park
    • The Journal of Engineering Geology
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    • v.33 no.1
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    • pp.85-103
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    • 2023
  • The in-situ remediation of a solidified stratum containing a large amount of fine-texture material like clay or organic matter in contaminated soil faces limitations such as increased remediation cost resulting from decreased purification efficiency. Even if the soil conditions are good, remediation generally requires a long time to complete because of non-uniform soil properties and low permeability. This study assessed the remediation effect and evaluated the field applicability of a methodology that combines pneumatic fracturing, vacuum extraction, and plasma blasting (the PPV method) to improve the limitations facing existing underground remediation methods. For comparison, underground remediation was performed over 80 days using the experimental PPV method and chemical oxidation (the control method). The control group showed no decrease in the degree of contamination due to the poor delivery of the soil remediation agent, whereas the PPV method clearly reduced the degree of contamination during the remediation period. Remediation effect, as assessed by the reduction of the highest TPH (Total Petroleum Hydrocarbons) concentration by distance from the injection well, was uncleared in the control group, whereas the PPV method showed a remediation effect of 62.6% within a 1 m radius of the injection well radius, 90.1% within 1.1~2.0 m, and 92.1% within 2.1~3.0 m. When evaluating the remediation efficiency by considering the average rate of TPH concentration reduction by distance from the injection well, the control group was not clear; in contrast, the PPV method showed 53.6% remediation effect within 1 m of the injection well, 82.4% within 1.1~2.0 m, and 68.7% within 2.1~3.0 m. Both ways of considering purification efficiency (based on changes in TPH maximum and average contamination concentration) found the PPV method to increase the remediation effect by 149.0~184.8% compared with the control group; its average increase in remediation effect was ~167%. The time taken to reduce contamination by 80% of the initial concentration was evaluated by deriving a correlation equation through analysis of the TPH concentration: the PPV method could reduce the purification time by 184.4% compared with chemical oxidation. However, the present evaluation of a single site cannot be equally applied to all strata, so additional research is necessary to explore more clearly the proposed method's effect.

The Shear Wave Velocity Analysis using Passive Method MASW in the Center of the Metropolis, Gyeongsan (Passive Method MASW 방법을 이용한 경산시 도심구간에서의 전단파 속도 분석)

  • Lee, Hong-Gyu;Kim, Woo-Hyuk;Jang, Seung-Ik;Lee, Seog-Kyu
    • The Journal of Engineering Geology
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    • v.17 no.4
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    • pp.511-516
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    • 2007
  • Active method MASW(Multi channel Analysis of Surface Waves), which is one of the surface wave exploration methods, has the difficulties to supply enough shear wave velocity log, caused by short spread length and lack of low frequency energy. To make up this defect, the passive method MASW survey is taked and analysised in Daeku subway construction site, Jungpyung-dong Gyeongsan city. The passive method MASW using the microtremor, improve the quality of the overtone record by applying the azimuth correction caused offline sources. And combing with active overtone record which is acquired by same geometry has the benefits of improve shallow depth resolution and extend possible investigation depth. To take the optimized acquisition parameters, the 2m, 4m, and 6m geophone spacing is tested. And 2m spacing overtone image could make the reliable shear wave velocity log.

Consolidation Behavior of Soft Ground by Prefabricated Vertical Drains (연직드레인 공법에 의한 연약지반의 압밀거동)

  • 이달원;강예묵
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1998.10a
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    • pp.376-381
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    • 1998
  • The large scaled field test by prefabricated vertical drains was performed to evaluate the superiority of vertical discharge capacity for drain materials through compare and analyze the time-settlement behavior with drain spacing and the compression index and consolidation coefficient obtained by laboratory experiments and field monitoring system 1. The relation of measurement settlement( $S_{m}$) versus design settlement( $S_{t}$) and measurement consolidation ratio( $U_{m}$) versus design consolidation ratio( $U_{t}$) were shown $S_{m}$=(1.0~l.1) $S_{t}$, $U_{m}$=(1.13~l.17) $U_{t}$, at 1.0m drain spacing and $S_{m}$=(0.7~0.8) $S_{t}$, $U_{m}$=(0.92~0.99) $U_{t}$ at 1.5m drain spacing, respectively. 2. The relation of field compression index( $C_{cfield}$) and virgin compression index( $V_{cclab}$) was shown $C_{cfield}$=(1.0~1.2) $V_{cclab}$, But it was nearly same value when considered the error with determination method of virgin compression index and prediction method of total settlement. 3. field consolidation coefficient was larger than laboratory consolidation coefficient, and the consolidation coefficient ratio( $C_{h}$/ $C_{v}$) were $C_{h}$=(2.4 ~ 3.0) $C_{v}$. $C_{h}$=(3.5 ~ 4.3) $C_{v}$ at 1.0m and 1.5m drain spacing and increased with increasing of drain spacingngasing of drain spacingng spacingng

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A Design of Variable Rate Clock and Data Recovery Circuit for Biomedical Silicon Bead (생체 의학 정보 수집이 가능한 실리콘 비드용 가변적인 속도 클록 데이터 복원 회로 설계)

  • Cho, Sung-Hun;Lee, Dong-Soo;Park, Hyung-Gu;Lee, Kang-Yoon
    • Journal of Korea Society of Industrial Information Systems
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    • v.20 no.4
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    • pp.39-45
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    • 2015
  • In this paper, variable rate CDR(Clock and Data Recovery) circuit adopting blind oversampling architecture is presented. The clock recovery circuit is implemented by using wide range voltage controlled oscillator and band selection method and the data recovery circuit is designed to digital circuit used majority voting method in order to low power and small area. The designed low power variable clock and data recovery is implemented by wide range voltage controlled oscillator and digital data recovery circuit. The designed variable rate CDR is operated from 10 bps to 2 Mbps. The total power consumption is about 4.4mW at 1MHz clock. The supply voltage is 1.2V. The designed die area is $120{\mu}m{\times}75{\mu}m$ and this circuit is fabricated in $0.13{\mu}m$ CMOS process.

Development of Production Resources (4M1E) Integration in Real Time and Middleware for Autonomous Configuration (생산자원(4M1E) 실시간 융합과 자율재구성용 미들웨어 개발)

  • Cha, Suk Keun;Yoon, Jai Young;Lee, Sung Keun;Heo, Young Sook
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.4
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    • pp.303-309
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    • 2014
  • This paper contains how to integrate production resources of 4M1E (Man, Machine, Material, Method and Energy), analyze and collect various type of management information which emphasize the need of a common platform's 4M1E Middleware and Autonomous Configuration. Management efficiency improved by the functionality of integrated management information and digitizing information with standardized data.