• Title/Summary/Keyword: 4F Process

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A Facile Process for Surface Modification with Lithium Ion Conducting Material of Li2TiF6 for LiMn2O4 in Lithium Ion Batteries

  • Kim, Min-Kun;Kim, Jin;Yu, Seung-Ho;Mun, Junyoung;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.223-230
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    • 2019
  • A facile method for surface coating with $Li_2TiF_6$ which has a high lithium-ion conductivity, on $LiMn_2O_4$ spinel cathode material for high performance lithium ion batteries. The surface coating is performed by using a co-precipitation method with $Li_2CO_3$ powder and $H_2TiF_6$ solution under room temperature and atmospheric pressure without special equipment. Total coating amount of $Li_2TiF_6$ is carefully controlled from 0 to 10 wt.% based on the active material of $LiMn_2O_4$. They are evaluated by a systematic combination of analyses comprising with XRD, SEM, TEM and ICP. It is found that the surface modification of $Li_2TiF_6$ is very beneficial to high cycle life and excellent rate capability by reducing surface failure and supporting lithium ions transportation on the surface. The best coating condition is found to have a high cycle life of $103mAh\;g^{-1}$ at the 100th cycle and a rate capability of $102.9mAh\;g^{-1}$ under 20 C. The detail electrochemical behaviors are investigated by AC impedance and galvanostatic charge and discharge test.

Design and Fabrication of a Low-cost Wafer-level Packaging for RF Devices

  • Lim, Jae-Hwan;Ryu, Jee-Youl;Choi, Hyun-Jin;Choi, Woo-Chang
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.91-95
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    • 2014
  • This paper presents the structure and process technology of simple and low-cost wafer-level packaging (WLP) for thin film radio frequency (RF) devices. Low-cost practical micromachining processes were proposed as an alternative to high-cost processes, such as silicon deep reactive ion etching (DRIE) or electro-plating, in order to reduce the fabrication cost. Gold (Au)/Tin (Sn) alloy was utilized as the solder material for bonding and hermetic sealing. The small size fabricated WLP of $1.04{\times}1.04{\times}0.4mm^3$ had an average shear strength of 10.425 $kg/mm^2$, and the leakage rate of all chips was lower than $1.2{\times}10^{-5}$ atm.cc/sec. These results met Military Standards 883F (MIL-STD-883F). As the newly proposed WLP structure is simple, and its process technology is inexpensive, the fabricated WLP is a good candidate for thin film type RF devices.

A study on the thickness change according to the necking ratio of aluminum tube(A3003, A6061) (알루미늄 튜브(A3003, A6061)의 축관률에 따른 두께 변화에 관한 연구)

  • Oh, Jong-Seong;Min, Kyung-Ho;Lee, Chun-Kyu
    • Design & Manufacturing
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    • v.15 no.4
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    • pp.37-42
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    • 2021
  • The tube necking process increases the thickness of the material, and some of the tube necking products require cutting on the inside of the formed product as a post-process. In order to prevent over-cutting or un-cutting due to increased thickness during cutting, it is necessary to know in advance the increase in thickness after forming. Therefore, in this study, the thickness change according to the tube necking was observed. Aluminum 3003-F and 6061-O were used for the materials used in the experiment, and necking was carried out up to 50% of the outer diameter of the tube through five processes. The two materials were formed under the same conditions, and the thickness of three points was observed in each process. In addition, the thickness increase of the two materials was compared, and the trend of thickness increase according to the cumulative necking ratio was observed. As a result of the experiment, both materials had the smallest thickness at the end of the formed product. In addition, as a result of comparing the thickness measurement values of the two materials, the maximum difference was 0.1mm, indicating that there was no difference in thickness between the two materials.

Mechanical Properties of Cf/SiC Composite Using a Combined Process of Chemical Vapor Infiltration and Precursor Infiltration Pyrolysis

  • Kim, Kyung-Mi;Hahn, Yoonsoo;Lee, Sung-Min;Choi, Kyoon;Lee, Jong-Heun
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.392-399
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    • 2018
  • $C_f/SiC$ composites were prepared via a process combining chemical vapor infiltration (CVI) and precursor infiltration pyrolysis (PIP), wherein silicon carbide matrices were infiltrated into 2.5D carbon preforms. The obtained composites exhibited porosities of 20 vol % and achieved strengths of 244 MPa in air at room temperature and 423 MPa at $1300^{\circ}C$ under an Ar atmosphere. Carbon fiber pull-out was rarely observed in the fractured surfaces, although intermediate layers of pyrolytic carbon of 150 nm thickness were deposited between the fiber and matrix. Fatigue fracture was observed after 1380 cycles under 45 MPa stress at $1000^{\circ}C$. The fractured samples were analyzed by transmission electron microscopy to observe the distributed phases.

Evaluation of Thermal Processes for Canned Marine Products (2) Canned Smoked Oyster in Oil and Canned Boiled Oyster in Brine (수산물통조림의 살균조건에 관한 연구(2) 굴 훈제 기름담금 통조림 및 굴 보일드 통조림)

  • PARK Young-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.3
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    • pp.165-169
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    • 1984
  • In succession to the previous paper, the present studies were directed to determine the sterilizing valves ($F_0$) of the thermal processes for the canned smoked oyster in oil and the canned boiled oyster in brine. The heat penetration tests were carried out under the condition of industrial scale at the tannery of the Taiyang Silup Company, Pusan, Korea. The test cans were placed in the middle layer of the crate in which the same canned products were loaded with, and the test cans were arranged to the front, the middle and the rear in the retort. The heat penetration was tested three times with three cans at a time for each canned product. The heat penetration curve of the canned smoked oyster in oil shelved a simple logarimicth heating curve while that of the canned boiled oyster in brine showed a broken logarithmic heating curve. The calculated $F_0$ value for canned smoked oyster in oil packed into No. 3B square can was 14.58 and the canned boiled oyster in brine packed into No.7 fruit can was 14. 78. On the basis of the heat penetration data obtained. the nomographs representing the relationship between $F_0$ values and B values (process time including $42\%$ of come-up time) for the canned oyster products were constructed.

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Characteristics of Electrical Resistance in System Mn-Co-Ni-Fe oxide for Thermistor with various Compositions (서미스터용 Mn-Co-Ni-Fe계 산화물의 조성에 따른 전기저항특성)

  • Kim, Yeong-Min;Im, Jae-Seok;Im, Goeng
    • The Journal of Engineering Research
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    • v.5 no.1
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    • pp.63-72
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    • 2004
  • The properties of electrical resistance of Mn-Co-Ni-Fe oxide-based thermistor with various Fe contents in sintering process at $1200^{\circ}$ to $1400^{\circ}C$ for 4 hours in air atmosphere for fabricating thermistor materials were investigated. The results were as follows: all samples showed single cubic spinel crystal structures in all region. The electrical conductivity is the highest thermistor sintered at $1300^{\circ}C$ for 4 hours. In general when the Fe content is increased except F-2, the resistivity increases and relatively the conductivity decreases. Particularly F-2 composition exhibited the highest electrical conductivity (1.4${\times}$$10^-3$${\textohm}cm) and relatively low B constant(2906K)

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The Electron Trap Analysis in Thermoluminescent LiF Crystal

  • Park, Dae-Yoon;Ko, Chung-Duck;Lee, Sang-Soo
    • Nuclear Engineering and Technology
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    • v.4 no.3
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    • pp.214-222
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    • 1972
  • In the optic,11 grade LiF crystal, the electron traps corresponding to the thermoluminescence(abbreviated to TL) glow peak develop as irradiation dose is increased. Originally the electron trap of the crystal has two levels but as the dose reaches to the order of 10$^4$rontgen, it attains five levels as observed in the TL glow curves. The five trap depths are determined from the glow peak temperatures for two different heating rates, $\theta$=6.6$^{\circ}C$/sec and 3.4$^{\circ}C$/sec. The electron trap depths have the following values E$_1$=0.79 eV, E$_2$=0.93 eV, E$_3$=1.02 eV, E$_4$=1.35 eV, E$_{5}$=1.69eV. The special feature of thermoluminescence of optical grade LiF is that the traps, except E$_1$and E$_2$corresponding to 12$0^{\circ}C$ glow peak and 15$0^{\circ}C$ glow peak for $\theta$=6.6$^{\circ}C$/sec, have severe thermal instability, namely E$_3$, E$_4$and E$_{5}$ levels disappear during bleaching process. These defects in the optical grade LiF crystal seem annealed out during the course of TL measurement. The fresh or long time unused LiF(Mg) crystal shows only two glow peaks at 17$0^{\circ}C$ and 23$0^{\circ}C$ for $\theta$=6.6$^{\circ}C$/sec, but upon sensitization with r-ray irradiation, it converts to the six glow peak state. The four electron traps, E$_1$, E$_2$, E$_3$, and E$_{6}$ created by r-ray irradiation and corresponding to the glow peaks at T=10$0^{\circ}C$ 13$0^{\circ}C$, 15$0^{\circ}C$ and 29$0^{\circ}C$ are stable and not easily annealed out thermally, The sensitization essentially required to LiF(Mg) dosimeter is to give the crystal the stable six levels in the electron trap. In optical grade LiF, the plot between logarithm of total TL output versus logarithm of r-ray dose gives more supra-linear feature than that of LiF(Mg). However, if one takes the height of 12$0^{\circ}C$ glow peak(S=6.6$^{\circ}C$/sec), instead of the total TL output, the curve becomes close to that of LiF(Mg).

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Optimum design analysis of ICP(Inductively Coupled Plasma) torch for high enthalpy thermal plasma flow (고엔탈피 열유동 발생용 고주파 유도결합 플라즈마 토치의 최적 설계변수 해석)

  • Seo, Jun-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.4
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    • pp.316-329
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    • 2012
  • In this paper, optimum design process of ICP (Inductively Coupled Plasma) torch, which has been used widely in aerospace application, such as supersonic plasma wind tunnel, is presented. For this purpose, the behaviors of equivalent circuit parameters (equivalent resistance and inductance, coupling efficiency) were investigated according to the variations of torch design parameters (frequency, $f$, confinement tube radius, $R$ and coil turn numbers, $N$) in the basis of analytical and numerical MHD (Magneto Hydro-Dynamics) models combined with electrical circuit theory. From the results, it is found that equivalent resistance is increased with the increase of $f$ values but vice versa for equivalent inductance. For elevated values of $R$ and $N$, however, both parameters tend to increase. Based on these observations, ICP torch with a power level of 10 kW can be optimized at the design ranges of $f$=4~6 MHz, $R$=17~25 mm and $N$=3~4 to maximize the electrical coupling efficiency, which is the ratio of equivalent resistance to equivalent inductance.

Research of Sea Food Wastewater Treatment using Membrane Filter (Membrane Filter를 이용한 수산물 가공폐수처리에 대한 연구)

  • Han, Dong-Joon
    • Journal of environmental and Sanitary engineering
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    • v.22 no.4
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    • pp.119-130
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    • 2007
  • Sea food wastewater including high concentration of organics and nutrients is hard to treat stably by established traditional activated sludge process. This research is aimed to obey more and more of strengthened the law and to secure stable effluents by using advanced treatment process applied membrane filter in aeration tank for treatment of wastewater from marine products. It must maintain pH of influent over 6.0 to keep up stably biological sludge of advanced treatment process. At 38hr of HRT, removal rates of TBOD and TCOD were 99.9% and 99.4% respectively and TSS also removed with high efficiency. Most organics in the effluent was constituted with soluble type materials, it caused that membrane filter installed aeration tank should remove minute suspended particles. The reactor was operated well to get stable treatment results for operation period, in spite of high loading of organics like that $0.67{\sim}1.67\;kgTBOD/m^3/day$ of organics loading and $0.10{\sim}0.21\;kgBOD_5/kgMLSS/day$ of F/M ratio. At $36{\sim}48hr$ of HRT, removal rates of T-N and T-P were $89.7{\sim}90.7%\;and\;91.5{\sim}96.0%$ respectively. It means this treatment process also work to remove nutrients of high concentration. Upon investigation of advanced treatment's operation factors, optimum SRT was about 30days and average SNR that showed tendency to increase according to increase water temperature was calculated 0.014 gN/g MLVSS/d. SDNR was risen in conformity to increase F/M ratio of Non-aeration tank and investigated as $0.038{\sim}0.051\;gN/gMLVSS/d$.

Development of an evaluation tool for the quality of nursing care in abdominal surgery patients (복부수술 환자간호의 질평가 도구 개발)

  • Lee, Byoung-Sook
    • Journal of Korean Academy of Nursing Administration
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    • v.4 no.1
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    • pp.107-127
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    • 1998
  • The purpose of this study was to develop an evaluation tool for the quality of nursing care in abdominal surgery patient. The target subjects of the tool were adult patients having abdominal surgery under general anesthesia. Process-outcome framework was selected for the development of the tool in this study. The results were as follows. 1. Nine standards. 40 criteria and 88 indicators were developed. A standard was summary statement of the ideal level of excellencein a dimension of quality of nursing care. which could be evaluated by criteria. Several criteria indicated a specific standard and each criterion could be measured by observable and measurable indicators. 2. The standards were divided into two dimensions. One was process dimension which contained four standards(23 criteria), the other was outcome dimension which contatined five standards(17 criteria). 3. Average CVI was .985 at 9 standards. .947 at 40 criteria. and .987 at 88 indicators. 4. The evaluation tool for the quality of nursing care in abdminal surgery patients was a criterion-referenced tool. And data collection methods of the tool were investigation of patient's record and interview( or questionnaire) with the patients. 5. Interrater reliabilities of the tool were ; r= .7572 (agreement between two raters), and pI=.8487 (intraclass correlation between five raters who rated the 84 patients). 6. Internal consistency reliability ${\alpha}$ was .6194, which was obtained from 32 criteria. Eight criteria were missed in the analyzing process because of data omission. 7. Scores of the process and the outcome dimensions showed significant. but low correlation(r= .3759, p < .001). 8. There were significant differences in total scores between the hospitals and the departments of surgery(F = 15.233. p .0001). There was also significant interaction effect between hospitals and departments to total score(F = 8.396. p = .0001). Construct validity of the toool was verified by the known-group method. these kinds of difference were expected by the nursing experts participated in the study. From these results, more specific patient classification is suggested for the development of evaluation tool of the quallity of nursing care. And indicators to be used for objective measurement for the quality of nursing care must be developed.

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